公开(公告)号：AU598929B2

公开(公告)日：1990-07-05

申请号：AU1564588

申请日：1988-05-05

Applicant: MITSUI TOATSU CHEMICALS

Inventor： YAMAGUCHI AKIHIRO ,  OHTA MASAHIRO ,  YAMAYA NORIMASA

IPC: C08G73/10 ,  C08J5/16 ,  C08K3/04 ,  C08K3/30 ,  C08K3/38 ,  F16C33/20 ,  F16J9/28 ,  C08L79/08

Abstract: A thermosetting resin composition formed of a polyaminobismaleimide resin, which is composed of a bismaleimide compound and a diamine compound, and a solid lubricant. The composition has low coefficient of friction and excellent wear resistance, and can be utilized for self-lubricating parts.

公开(公告)号：AU4563089A

公开(公告)日：1990-06-14

申请号：AU4563089

申请日：1989-11-28

Applicant: MITSUI TOATSU CHEMICALS

Inventor： YAMAYA NORIMASA ,  YAMAGUCHI AKIHIRO ,  OHTA MASAHIRO

IPC: C08F212/34 ,  C08F12/00 ,  C08F20/10 ,  C08F22/36 ,  C08F222/40 ,  C08G73/12 ,  C08G73/00 ,  C08F299/02

Abstract: This invention provides thermosetting-resin-forming compositions which are formed of (a) a bismaleimide compound represented by the following formula: wherein R represents a divalent group of or X being a direct bond or a group selected from divalent hydrocarbon groups having 1-10 carbon atoms, hexa-fluorinated isopropylidene, carbonyl, thio, sulfinyl, sulfonyl and oxo, and (b) a specific diallylbisphenol compound. These compositions can provide thermosetting resins having high cracking resistance due to improved impact resistance and toughness and low water absorption.

公开(公告)号：CA2003664A1

公开(公告)日：1990-05-28

申请号：CA2003664

申请日：1989-11-23

Applicant: MITSUI TOATSU CHEMICALS

Inventor： YAMAYA NORIMASA ,  OHTA MASAHIRO ,  YAMAGUCHI AKIHIRO

IPC: C08F212/34 ,  C08F12/00 ,  C08F20/10 ,  C08F22/36 ,  C08F222/40 ,  C08G73/12 ,  C08G73/10

Abstract: This invention provides thermosetting-resin-forming compositions which are formed of (a) a bismaleimide compound represented by the following formula: wherein R represents a divalent group of or , X being a direct bond or a group selected from the group consisting of divalent hydrocarbon groups having 1-10 carbon atoms, hexa-fluorinated isopropylidene, carbonyl, thio, sulfinyl, sulfonyl and oxo, and (b) a specific diallylbisphenol compound. These compositions can provide thermosetting resins having high cracking resistance due to improved impact resistance and toughness and low water absorption.

公开(公告)号：AU589785B2

公开(公告)日：1989-10-19

申请号：AU7497187

申请日：1987-06-30

Applicant: MITSUI TOATSU CHEMICALS

Inventor： BABA KENICHI ,  KOGA NOBUHITO ,  YAMAYA NORIMASA

IPC: C08L27/12 ,  C08L79/08 ,  C08L87/00

Abstract: This invention is a polyimide resin composition containing 100 parts by weight of polyimide having recurring units of the following formula : (where Y is a bond, divalent hydrocarbon radical having from 1 to 10 carbons, hexafluorinated isopropylidene radical, carbonyl radical, thio radical, sulfinyl radical, sulfonyl radical or oxide, and R is a tetra-valent radical of aliphatic radical having at least 2 carbons, alicyclic radical, monoaromatic radical, condensed polyaromatic radical, or non-condensed polyaromatic radical wherein aromatic radicals are mutually connected with a bond or a crosslinking function) and from 5 to 100 parts by weight of fluororesin. The resin composition can provide molded products which are excellent in high-temperature stability, dimensional stability and mechanical strength and moreover have a low friction coefficient and good wear resistance. Therefore, the composition is useful as the material for electric and electronic devices, precision instrument parts etc. Polyimide of this invention can be prepared from aromatic diamines and tetracarboxylic acid dianhydrides. Suitable aromatic diamines are 4,4'-bis(3-aminophenoxy)biphenyl, 2,2-bis[4-(3-aminophenoxy)phenyl]propane, bis[4-(3-aminophenoxy)phenyl] sulfide etc. Suitable tetracarboxylic acid dianhydrides are pyromellitic dianhydride and 3,3', 4,4'-benzophenonetetracarboxylic dianhydride. Representative fluororesin which can be used in this invention is polytetrafluoroethylene.

公开(公告)号：AU1500388A

公开(公告)日：1988-10-27

申请号：AU1500388

申请日：1988-04-20

Applicant: MITSUI TOATSU CHEMICALS

Inventor： YAMAYA NORIMASA ,  OHTA MASAHIRO ,  YAMAGUCHI AKIHIRO

IPC: C08G73/12 ,  C08K7/08 ,  C08L79/02 ,  C08L79/04 ,  C08K7/02 ,  C08K7/06 ,  C08K7/14

Abstract: A thermosetting resin composition formed of a polyaminobismaleimide resin, which is composed of a bismaleimide compound I and a diamine compound II, and a fibrous reinforcing material selected from potassium titante fibres and aromatic polyamide fibres, the fibres having an aspect ratio of from 5 to 600. The composition has excellent impact resistance and toughness while retaining conventional high heat resistance.

公开(公告)号：AU7235687A

公开(公告)日：1987-11-09

申请号：AU7235687

申请日：1987-04-08

Applicant: MITSUI TOATSU CHEMICALS

Inventor： YAMAYA NORIMASA ,  KOGA NOBUHITO ,  BABA KENICHI

IPC: C08K7/02 ,  C08L79/08 ,  H01B3/30

Abstract: New polyimide resin compsn. is composed of 100 pts. by wt. of a polyimide having repeat units represented by general formula (I) and 5 to 100 pts. by wt. of fibrous reinforcing material, where Y represents a direct bond, a divalent 1-10C hydrocarbyl gp., a hexafluoroisopropylidene gp., a carbonyl gp., or a oxido gp. R represents a tetravalent 2 or more C aliphatic gp., an alicyclic gp., a monocyclic aromatic gp., a fused polycyclic aromatic gp., or a non-fused cyclic aromatic gp. in which aromatic gps. are linked direct to each other or via a linking member. The polyimide can have an isopropylidene gp. for Y in general formula (1), it can have a direct bond for Y and (II) for R, it can have an isopropylidene gp. for Y and (III) for R, etc. The fibrous reinforcing material can be glass fibres, carbon fibres, potassium titanate fibres or aromatic polyamide fibres.

公开(公告)号：EP0267289A4

公开(公告)日：1988-07-25

申请号：EP87902709

申请日：1987-04-08

Applicant: MITSUI TOATSU CHEMICALS

Inventor： YAMAYA NORIMASA ,  KOGA NOBUHITO ,  BABA KENICHI

IPC: C08K7/02 ,  C08L79/08 ,  H01B3/30

CPC classification number: H01B3/306 ,  C08K7/02 ,  C08L79/08

Abstract: A polyimide resin composition, which comprises 100 parts by weight of a polyimide having repeating units represented by general formula (I), (wherein Y represents a direct bond, a divalent hydrocarbyl group having 1 to 10 carbon atoms, a hexafluoroisopropylidene group, a carbonyl group, a thio group, a sulfinyl group, a sulfonyl group or an oxido group, and R represents a tetravalent aliphatic group having 2 or more carbon atoms, alicyclic group, monocylic aromatic group, fused polycyclic aromatic group or non-fused cyclic aromatic group wherein aromatic groups are linked to each other directly or via a linking member) and 5 to 100 parts by weight of fibrous reinforcing material such as glass fibers, carbon fibers, potassium titanate fibers, aromatic polymide fibers, etc. This resin composition has excellent heat resistance, dimensional stability, and mechanical strength and is a useful material for manufacturing electric or electronic components, precision machine parts, etc. The polyimide to be used can be prepared from an aromatic ether diamine and a tetracarboxylic acid dianhydride, using 4,4'-bis(3-aminophenoxy)biphenyl, 2,2'-bis(4-(3-aminophenoxy)phenyl)propane, bis(4-(3-aminophenoxy)phenyl) sulfide, etc. as the ether diamine and pyromellitic dianhydride, 3,3',4,4'-benzophenonetetracarboxylic acid dianhydride, etc. as the tetracarboxylic acid dianhydride.

公开(公告)号：JPS6426668A

公开(公告)日：1989-01-27

申请号：JP9016888

申请日：1988-04-14

Applicant: MITSUI TOATSU CHEMICALS

Inventor： YAMAYA NORIMASA ,  OHTA MASAHIRO ,  YAMAGUCHI AKIHIRO

IPC: C08L79/00 ,  C08K7/06

Abstract: PURPOSE:To obtain the titled composition, having excellent impact resistance and toughness without deteriorating heat resistance, by blending a polyaminobismaleimide polymer consisting of a specific bismaleimide compound and diamine compound with a specific amount of a fibrous reinforcing agent. CONSTITUTION:A thermoplastic polymer composition obtained by blending (A) 100pts.wt. polyaminobismaleimide polymer consisting of (A1) 1mol. bismaleimide compound expressed by formula I [R is formula II or III (X is direct bond, 1-10C bifunctional hydrocarbon, etc.) [e.g. 1,3-bis(3- maleimidophenoxy)benzene] and (A2) 0.1-1.2mol. diamine compound expressed by formula IV [e.g. 1,3-bis(3-aminophenoxy)benzene] with (B) 10-400pts.wt., preferably 20-350pts.wt. fibrous reinforcing agent (e.g. glass fiber, carbon fiber or potassium titanate fiber).