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    Indoanilines in keratinic fiber dye compositions
    51.
    发明授权
    Indoanilines in keratinic fiber dye compositions 失效
    角质纤维染料组合物中的印花尼牌

    公开(公告)号：US3929404A

    公开(公告)日：1975-12-30

    申请号：US48252374

    申请日：1974-06-24

    Applicant: OREAL

    Inventor： KALOPISSIS GREGOIRE ,  BUGAUT ANDREE ,  ESTRADIER FRANCOISE

    IPC: A61K8/41 ,  A61Q5/10 ,  C07C275/26 ,  C07D295/13 ,  C07D295/135 ,  C09B53/02 ,  D06P3/14 ,  A61K7/13

    CPC classification number: C07D295/13 ,  A61K8/413 ,  A61Q5/10 ,  C07C275/26 ,  C07D295/135 ,  Y10S424/01

    Abstract: WHEREIN R1 represents hydrogen, halogen, alkyl or alkoxy; R2 represents alkyl, hydroxyalkyl, carbamylalkyl, piperidinoalkyl, morpholinalkyl, sulfoalkyl, dialkylaminoalkyl, acylaminoalkyl, (preferably acetylaminoalkyl or benzoylaminoalkyl) and mesylaminoalkyl; R3 represents hydroxyalkyl, carbamylalkyl, piperidinoalkyl, morpholinoalkyl, sulfoalkyl, dialkylaminoalkyl, acylaminoalkyl, (preferably acetylaminoalkyl or benzoylaminoalkyl), mesylaminoalkyl; or R2 and R3 together form with the nitrogen atom to which they are attached a heterocycle selected from piperidino or morpholino; R4, R5 and R6 each independently represents hydrogen, halogen, alkyl, alkoxy, acylamino, ureido or carbalkoxyamino, and R5 can also represent amino, alkylamino, hydroxyalkylamino or carbamylalkylamino. The alkyl and alkoxy groups above can contain from 1 to 6 carbon atoms and the acyl group can contain from 2 to 7 carbon atoms. The present invention also relates to a process for the preparation of the above indoanilines and to dye compositions for keratinic fibers, and in particular living human hair, containing said indoanilines.

    Indoaniline of the formula

    Abstract translation: 式AD的吲哚苯胺，其中R1表示氢，卤素，烷基或烷氧基; R 2表示烷基，羟基烷基，氨基甲酰基烷基，哌啶子基烷基，吗啉基烷基，磺基烷基，二烷基氨基烷基，酰基氨基烷基（优选乙酰氨基烷基或苯甲酰基氨基烷基）和甲磺酰氨基烷基; R 3表示羟烷基，氨基甲酰基烷基，哌啶子基烷基，吗啉代烷基，磺基烷基，二烷基氨基烷基，酰氨基烷基（优选乙酰氨基烷基或苯甲酰氨基烷基），甲磺酰氨基烷基; 或者R 2和R 3与它们所连接的氮原子一起形成选自哌啶子基或吗啉代的杂环; R 4，R 5和R 6各自独立地表示氢，卤素，烷基，烷氧基，酰氨基，脲基或烷氧基氨基，R 5也可以表示氨基，烷基氨基，羟基烷基氨基或氨基甲酰基烷基氨基。 上述烷基和烷氧基可含有1至6个碳原子，酰基可含有2至7个碳原子。 本发明还涉及制备上述吲哚苯胺的方法和用于角蛋白纤维的染色组合物，特别是包含所述吲哚苯胺的活人的头发。

    2-nitro-4-benzenesulfonamido chlorobenzenes
    52.
    发明授权
    2-nitro-4-benzenesulfonamido chlorobenzenes 失效
    2-硝基-4-苯并呋喃氨基氯仿

    公开(公告)号：US3920710A

    公开(公告)日：1975-11-18

    申请号：US35299473

    申请日：1973-04-20

    Applicant: OREAL

    Inventor： KALOPISSIS GREGOIRE ,  BUGAUT ANDREE ,  ZORAYAN VAHAN

    IPC: A61K8/41 ,  A61Q5/06 ,  C07C311/37 ,  C09B51/00 ,  D06P3/08 ,  C07C143/80

    CPC classification number: A61K8/418 ,  A61Q5/065 ,  C09B51/00 ,  D06P3/08

    Abstract: A keratin fiber dye composition which comprises a solvent and a dyeing amount of a dye compound having the formula:

    in which n is a whole number between 2 and 6 inclusive, and R2 and R3, which may be identical or different, are selected from the group consisting of hydrogen, lower alkyl, lower hydroxyalkyl, and with the nitrogen atom adjacent R2 and R3 may form morpholino and piperidino, each R1, R2, R3 having 1-6 carbon atoms on their alkyl portion, AND THE PROCESS OF DYEING KERATIN FIBERS.

    IN WHICH R'' is selected from the group consisting of methyl and NO2, and R'''' is selected from the group consisting of hydrogen and lower alkyl, having 1-6 carbon atoms, AND R1 is selected from the group consisting of lower alkyl, lower hydroxyalkyl, lower alkoxyalkyl, and

    D R A W I N G
    IN WHICH R is selected from the group consisting of lower alkyl, hydroxy alkyl, carboxyalkyl, carbethoxyalkyl, carbamylalkyl, haloalkyl, aminoalkyl, aminodialkyl, alkylaminodialkyl, alkyl morpholino, alkyl piperidino, having 1-6 carbon atoms on each mentioned alkyl portion, Z is selected from the group consisting of

    Dye composition for keratinic fibers containing an oxidation base and a meta-aminophenol coupler
    53.
    发明授权
    Dye composition for keratinic fibers containing an oxidation base and a meta-aminophenol coupler 失效
    含有氧化碱和间氨基苯偶姻的角质纤维的染料组合物

    公开(公告)号：US3918896A

    公开(公告)日：1975-11-11

    申请号：US48255874

    申请日：1974-06-24

    Applicant: OREAL

    Inventor： KALOPISSIS GREGOIRE ,  BUGAUT ANDREE

    IPC: A61K8/41 ,  A61Q5/10 ,  C07C215/76 ,  C07C233/12 ,  C07C233/16 ,  C09B57/00 ,  C09B67/00 ,  D06P3/14 ,  A61K7/13

    CPC classification number: A61K8/415 ,  A61K8/411 ,  A61K8/413 ,  A61Q5/10

    Abstract: A dye composition for keratinic fibers comprising in combination A. AT LEAST ONE OXIDATION BASE SELECTED FROM THE GROUP CONSISTING OF AN AROMATIC OR HETEROCYCLIC COMPOUND CARRYING EITHER TWO AMINO GROUPS OR ONE AMINO GROUP AND ONE HYDROXY GROUP, FIXED IN PARA POSITION RELATIVE TO EACH OTHER ON THE AROMATIC OR HETEROCYCLIC NUCLEUS OF SAID COMPOUND, SAID OXIDATION BASE BEING IN THE FORM OF A FREE BASE OR IN THE FORM OF AN ACID ADDITION SALT THEREOF AND B. AT LEAST ONE COUPLER OF THE FORMULA:

    WHEREIN X represents a member selected from the group consisting of F, Cl or Br; or the acid addition salt of the compound of formula (I).

    Abstract translation: 用于角质形成纤维的染料组合物，其组合为A.从由包含两个氨基团或一个氨基和一个羟基的芳族或杂环化合物组成的组中选出的至少一个氧化基团，其相对于任何另一个固定在PARA位置 所述化合物的芳香或杂环核，以氧自由基形式或以其酸加成盐形式存在氧化基，B为最小配方的一个偶联物：

    Non-ionic surface active agents as cosmetic emulsifiers
    54.
    发明授权
    Non-ionic surface active agents as cosmetic emulsifiers 失效
    非离子表面活性剂作为化妆品乳化剂

    公开(公告)号：US3914407A

    公开(公告)日：1975-10-21

    申请号：US48067174

    申请日：1974-06-17

    Applicant: OREAL

    Inventor： KALOPISSIS GREGOIRE ,  VANLERBERGHE GUY

    IPC: A61K8/06 ,  A61K8/39 ,  A61K8/90 ,  A61Q5/10 ,  A61Q19/00 ,  B01F17/00 ,  C07C43/11 ,  A61K7/021 ,  A61K7/035 ,  A61K9/10

    CPC classification number: C07C43/11 ,  A61K8/06 ,  A61K8/39 ,  A61K8/90 ,  A61K2800/43 ,  A61Q5/10 ,  A61Q19/00 ,  B01F17/0021 ,  Y10S514/941 ,  Y10S516/01

    Abstract: An emulsifying and peptizing agent having the formula ROC2H3O(R''))m (C2H3O(X))nH wherein R is a lipophilic hydrocarbon residue of a member selected from the group consisting of alcohols, sterols and their mixtures derived from a member selected from the group consisting of (a) hydrogenated lanolin, and (b) cyclic fatty acids, R'' is selected from the group consisting of methyl and ethyl, X is selected from the group consisting of -CH2O-C2H3O(CH2OH))p CH2-CHOH-CH2OH, m has a statistical average value between 1-10 inclusive, N HAS A STATISTICAL AVERAGE VALUE BETWEEN 1-5 INCLUSIVE, P IS AN INTEGER BETWEEN 0-10 INCLUSIVE AND THE PRODUCT N(P+2) LIES BETWEEN 2-12 INCLUSIVE.

    Abstract translation: 具有式RO-C 2 H 3 O（R'）] m [C 2 H 3 O（X）] nH的乳化和胶溶剂，其中R是选自醇，甾醇及其衍生自成员的混合物的成员的脂族烃残基 选自（a）氢化羊毛脂和（b）环状脂肪酸，R'选自甲基和乙基，X选自-CH 2 O-C 2 H 3 O（CH 2 OH）] p CH2-CHOH-CH2OH，m具有介于1-10之间的统计平均值，N HAS在1-5包含之间的统计平均值，P是0-10包含之间的整数和产品N（P + 2）之间的比例 2-12包含。

    Method and composition containing nitroparaphenylene dyes for dyeing keratinic fibers
    60.
    发明授权
    Method and composition containing nitroparaphenylene dyes for dyeing keratinic fibers 失效
    含有硝基苯乙烯染料的方法和组合物，用于染色卡介苗

    公开(公告)号：US3694140A

    公开(公告)日：1972-09-26

    申请号：US3694140D

    申请日：1968-05-16

    Applicant: OREAL

    Inventor： KALOPISSIS GREGOIRE ,  BUGAUT ANDREE ,  ZORAYAN VAHAN

    IPC: D06P1/32 ,  A61K7/12 ,  D06P3/02

    CPC classification number: D06P1/32 ,  Y10S8/917

    Abstract: COMPOSITION CONTAINING NITROPARAPHENYLENE DIAMINE DERIVATIVES FOR DYEING KERATINIC FIBERS AND METHOD OF APPLYING SAID COMPOSITION TO THE HAIR, WHEREIN SAID DIAMINE DERIVATIVES HAVE THE FORMULA:

    1-(R-NH-),2-(O2N-),4-(R-N(-Z)-)BENZENE

    IN WHICH:

    R REPRESENTS H OR A LOWER ALKYL; Z REPRESENTS H, AN

    1-R'',4-(SO2-)BENZENE

    RADICAL IN WHICH R'' REPRESENTS H, METHYL, OR NO2, OR AN OC-R" RADICAL IN WHICH R" REPRESENTS A LOWER ALKYL; AND AT LEAST ONE OF R AND Z IS H; R1 REPRESENTS A LOWER ALKYL, LOWER HYDROXYALKYL, LOWER ALKOXYALKYL OR

    -(CH2)N-N(-R2)-R3

    IN WHICH N IS A WHOLE NUMBER BETWEEN TWO AND SIX INCLUSIVE, WHILE R2 AND R3 REPRESENT H, A LOWER ALKYL, OR A LOWER HYDROXY ALKYL, AND THE ALKYL PORTION OF R, R", R1, R2 AND R4 HAVING 1 TO 6 CARBON ATOMS.

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