公开(公告)号：FI751394A

公开(公告)日：1975-05-13

申请号：FI751394

申请日：1975-05-13

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT KARL ,  MILLER ARTHUR FRANCIS ,  SHAW WILFRID GARSIDE

IPC: C07C20060101 ,  C07C

公开(公告)号：DE2258821A1

公开(公告)日：1973-07-05

申请号：DE2258821

申请日：1972-12-01

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID GARSIDE ,  GRASSELLI ROBERT KARL

IPC: B01J21/00 ,  B01J23/887 ,  B01J27/192 ,  C07B61/00 ,  C07C1/00 ,  C07C5/333 ,  C07C5/48 ,  C07C11/167 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  C07C121/32

公开(公告)号：ES2095406T3

公开(公告)日：1997-02-16

申请号：ES92305436

申请日：1992-06-12

Applicant: STANDARD OIL CO OHIO

Inventor： PAPARIZOS CHRISTOS ,  SHAW WILFRID GARSIDE

IPC: B01J23/88 ,  B01J23/887 ,  B01J27/192 ,  B01J27/199 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08

公开(公告)号：DE69216390D1

公开(公告)日：1997-02-13

申请号：DE69216390

申请日：1992-06-12

Applicant: STANDARD OIL CO OHIO

Inventor： PAPARIZOS CHRISTOS ,  SHAW WILFRID GARSIDE

IPC: B01J23/88 ,  B01J23/887 ,  B01J27/192 ,  B01J27/199 ,  C07C253/24 ,  C07C253/26 ,  C07C255/08

公开(公告)号：NO141830C

公开(公告)日：1980-05-21

申请号：NO743150

申请日：1974-09-03

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT KARL ,  MILLER ARTHUR FRANCIS ,  SHAW WILFRID GARSIDE

IPC: C07C27/14 ,  B01J23/88 ,  B01J23/882 ,  B01J23/883 ,  B01J23/887 ,  B01J23/888 ,  B01J23/89 ,  B01J27/192 ,  B01J27/198 ,  B01J27/199 ,  C07B35/04 ,  C07B61/00 ,  C07C5/333 ,  C07C5/48 ,  C07C27/00 ,  C07C27/12 ,  C07C45/00 ,  C07C45/34 ,  C07C45/35 ,  C07C47/20 ,  C07C47/22 ,  C07C51/25 ,  C07C57/05 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  B01J23/84 ,  C07C121/32 ,  C07C57/04

Abstract: Catalysts containing at least nickel or cobalt, chromium, bismuth and molybdenum have been found to be especially useful for the ammoxidation of olefins, the oxidation of olefins and the oxidative dehydrogenation of olefins.

公开(公告)号：ATA709477A

公开(公告)日：1980-03-15

申请号：AT709477

申请日：1977-10-05

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES FERGUSON ,  SHAW WILFRID GARSIDE

IPC: C07C57/04 ,  B01J27/00 ,  B01J27/19 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  B01J27/18

Abstract: Coated catalysts having an inert support material with an outer surface and a coating of active catalyst containing molybdenum, phosphorus, arsenic, copper and oxygen have been found to be especially effective catalysts for the production of unsaturated acids from the corresponding unsaturated aldehydes, for example, methacrolein is oxidized to methacrylic acid using these catalysts. The catalysts give a very low exotherm, very high single pass yields of the desired acid and reduce the undesirable byproducts.

公开(公告)号：ATA893676A

公开(公告)日：1980-01-15

申请号：AT893676

申请日：1976-12-02

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID GARSIDE ,  TERRILL DAVID BYERLY

IPC: B01J23/88 ,  B01J23/00 ,  B01J23/18 ,  B01J23/22 ,  B01J23/28 ,  B01J23/887 ,  B01J37/02 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  B01J23/84

Abstract: A process for obtaining acrylic acid or methacrylic acid from acrolein or methacrolein, respectively, comprising the steps of mixing the aldehyde, molecular oxygen and water vapor in a molar ratio within the range of 1/0.5-5/0-20, respectively; contacting said mixture with a catalyst at a temperature of about 200º to 500º c, said catalyst having a composition represented by the empirical formula ** (formula) ** wherein x is a metal selected from the group consisting of antimony and germanium, or both, and where a is a number from 6 to about 18, b, c and d are, individually, from about 0.1 to about 6, and e is the number of oxygen atoms required to meet the valence requirements of the other metals present; and recover the unsaturated acid. (Machine-translation by Google Translate, not legally binding)

公开(公告)号：AT350513B

公开(公告)日：1979-06-11

申请号：AT760374

申请日：1974-09-20

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT KARL ,  MILLER ARTHUR FRANCIS ,  SHAW WILFRID GARSIDE

IPC: B01J23/88 ,  B01J23/887 ,  B01J23/888

公开(公告)号：PT67140B

公开(公告)日：1979-03-19

申请号：PT6714077

申请日：1977-10-11

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES FERQUSON ,  SHAW WILFRID GARSIDE

IPC: C07C57/04 ,  B01J27/00 ,  B01J27/19 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00

Abstract: Coated catalysts having an inert support material with an outer surface and a coating of active catalyst containing molybdenum, phosphorus, arsenic, copper and oxygen have been found to be especially effective catalysts for the production of unsaturated acids from the corresponding unsaturated aldehydes, for example, methacrolein is oxidized to methacrylic acid using these catalysts. The catalysts give a very low exotherm, very high single pass yields of the desired acid and reduce the undesirable byproducts.

公开(公告)号：NO783834L

公开(公告)日：1978-04-20

申请号：NO783834

申请日：1978-11-15

Applicant: STANDARD OIL CO OHIO

Inventor： WHITE JAMES FERGUSON ,  SHAW WILFRID GARSIDE ,  APPLEQUIST MICHAEL DUANE

IPC: B01J23/28 ,  B01J23/54 ,  B01J23/88 ,  B01J23/887 ,  B01J23/89 ,  B01J27/19 ,  B01J27/198 ,  B01J27/199 ,  B01J27/24 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/05 ,  C07C57/055 ,  C07C67/00 ,  B01J