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公开(公告)号：CA2801397A1
公开(公告)日：2011-12-08
申请号：CA2801397
申请日：2011-06-03
Applicant: STORA ENSO OYJ
Inventor： HARLIN ALI , RASANEN JARI , PENTTINEN TAPANI
IPC: C10G65/12 , C07C4/06 , C07C15/08 , C07C51/265 , C07C63/26 , C08G63/183 , C08G63/78
Abstract: The present invention relates to a method of manufacturing aromatic hydrocarbons, which are suitable for the production of terephthalic acid, from tall oil-based raw material. According to the invention, the raw material that contains tall oil or its fraction is catalytically deoxygenated with hydrogen, and one or more aromatic hydrocarbons (A) that can be converted into terephthalic acid are separated from the deoxygenated reaction yield (10). The deoxygenation catalyst is preferably a NiMo catalyst and, in addition, a cracking catalyst can be used, such as an acidic zeolite catalyst. The separated hydrocarbon is preferably p-xylene, o-xylene or p-cymene. According to the invention, these can be converted by oxidation and, when needed, by a re-arrangement reaction into terephthalic acid that is suitable for the source material of the manufacture of bio-based polyethylene terephthalate.
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公开(公告)号：CA2801394A1
公开(公告)日：2011-12-08
申请号：CA2801394
申请日：2011-06-03
Applicant: STORA ENSO OYJ
Inventor： RASANEN JARI , PENTTINEN TAPANI , HARLIN ALI , KAILA REETTA
Abstract: Herein disclosed is biobased p-cymene, which can further be converted to terephtalate. Further, here is described a method for converting crude sulphate turpentine recovered from chemical wood pulping into p-cymene and eventually to terephtalic acid of biological origin, and and products thereof respectively. In said method, both conversion and desulphurisation is realised in one reaction step. Present disclosure is also related to use of zeolite catalysts in said method.
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公开(公告)号：FI121626B
公开(公告)日：2011-02-15
申请号：FI20095079
申请日：2009-01-29
Applicant: STORA ENSO OYJ
Inventor： HARLIN ALI , PENTTINEN TAPANI , RAESAENEN JARI , AALTONEN OLLI
Abstract: The invention relates to a method of producing olefinic monomers for the production of a polymer. The invention particularly relates to the production of tall oil-based biopolymers, such as polyolefins. In the stages of the method bio oil, with a content of over 50% of fatty acids of tall oil and no more than 25% of resin acids of tall oil, and hydrogen gas are fed into a catalyst bed (7); the oil is catalytically deoxygenated in the bed by hydrogen; the flow exiting the bed is cooled down and divided into a hydrocarbon-bearing liquid phase (10) and a gas phase; and the hydrocarbon-bearing liquid (13) is subjected to steam cracking (4) to provide a product containing polymerizing olefins. The deoxygenation in the bed can be followed by a catalytic cracking or, with a suitable catalyst, the deoxygenation and cracking can be simultaneous. The separated hydrogen-bearing gas phase can be circulated in the process.
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公开(公告)号：CA2767290A1
公开(公告)日：2011-01-13
申请号：CA2767290
申请日：2010-07-02
Applicant: STORA ENSO OYJ
Inventor： VEHVILAEINEN MARIANNA , KAMPPURI TAINA , PELTOLA MAARIT , HARLIN ALI , NOUSIAINEN PERTTI
Abstract: The invention relates to a process for treating cellulosic fibres which process comprises mechanically pre-treating the fibres followed by treating the fibres with an enzyme and thereafter mixing the fibres with a solution comprising an alkali metal hydroxide followed by mechanically treating the fibres to form microfibrillated cellulose. In this way it is possible to produce MFC in an improved and energy efficient way.
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公开(公告)号：FI20105630A0
公开(公告)日：2010-06-03
申请号：FI20105630
申请日：2010-06-03
Applicant: STORA ENSO OYJ
Inventor： RAESAENEN JARI , PENTTINEN TAPANI , HARLIN ALI , KAILA REETTA
IPC: C07C20100101
Abstract: Biobased p-cymene and methods of producing same, which can further be converted to terephtalate. Further, a method is described for converting crude sulfate turpentine recovered from chemical wood pulping into p-cymene and eventually to terephtalic acid of biological origin, and products thereof respectively. In said method, both conversion and desulfurization is realized in one reaction step. The disclosure is also related to use of zeolite catalysts in said method.
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Patent Agency Ranking
公开(公告)号：FI125589B2
公开(公告)日：2022-03-31
申请号：FI20135342
申请日：2013-04-08
Applicant: STORA ENSO OYJ
Inventor： HARLIN ALI , RÄSÄNEN JARI , LINNEKOSKI JUHA , AALTONEN OLLI , ANTHONYKUTTY JINTO
IPC: C10G3/00 , C07C11/02 , C07C15/08 , C07C51/265 , C07C63/26 , C08F110/00 , C08F110/02 , C08F110/04 , C08G63/183 , C10G49/04 , C10G49/08 , C10G65/12
Abstract: The present invention relates to a method of deoxygenating tall oil pitch, yielding aliphatic and aromatic hydrocarbons. The invention even comprises turning the aliphates into polymerizable olefins by steam cracking, and turning the aromates into polymerizable terephthalic acid by oxygenation and, as necessary, rearrangement. The monomers can be used for the production of polymers of partially or completely biologic origin. According to the invention, tall oil pitch is first heated to turn it into liquid, which is then fed into a catalyst bed and catalytically deoxygenated with hydrogen. The deoxygenation catalyst is preferably a Ni-Mo catalyst and, in addition, a cracking catalyst can be used, such as an acidic zeolite catalyst. The deoxygenated product stream is cooled down so as to obtain a liquid, which is distilled for separation of the aliphatic and aromatic hydrocarbons for use in the production of the respective monomers and finally polymers.
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公开(公告)号：BR112012030782A8
公开(公告)日：2021-07-06
申请号：BR112012030782
申请日：2011-06-03
Applicant: STORA ENSO OYJ
Inventor： HARLIN ALI , KAILA REETA , PENTTINEN TAPANI , RÄSÄNEN JARI
Abstract: refino catalítico de terpenos de origem de polpa. a presente invenção está correlacionada a um composto de p-cimeno de origem biológica, que pode ser ainda convertido em tereftalato. além disso, é descrito um método para conversão de sulfato de bruto de terebentina (aguarrás), recuperado de polpação química de madeira, em p-cimeno e, eventualmente, em ácido tereftálico de origem biológica e derivados do mesmo, respectivamente. no dito método, as etapas de conversão e dessulfurização são realizadas em uma única etapa reacional. a presente divulgação é tambem correlacionada ao uso de catalisadores de zeólito no referido método.
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公开(公告)号：SE543676C2
公开(公告)日：2021-05-25
申请号：SE1950835
申请日：2019-07-03
Applicant: STORA ENSO OYJ
Inventor： HARLIN ALI , LAINE CHRISTIANE , KOSKELA HANNA , SETÄLÄ HARRI , KAMMIOVIRTA KARI , KETOJA JUKKA , HJELT TUOMO
IPC: D21H11/20 , B29C51/08 , B31B50/59 , B65B43/08 , C08B1/08 , C08L1/02 , D21H11/02 , D21H11/16 , D21H15/04
Abstract: The present invention relates to a method for manufacturing modified cellulose fibers for a moldable cellulose fiber based material, said method comprising: a) providing a chemical or semi-chemical wood pulp comprising cellulose fibers, and optionally subjecting the pulp to alkaline extraction to obtain an alkaline extracted pulp; and b) subjecting the pulp or the alkaline extracted pulp of step a) to a chemical treatment with an alkaline solution and/or an organic solvent to obtain a treated pulp or treated alkaline extracted pulp comprising modified cellulose fibers for a moldable cellulose fiber based material. The invention further relates to a moldable cellulose fiber based material comprising at least 70% by dry weight of modified cellulose fibers obtainable by the method.
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公开(公告)号：FI126458B
公开(公告)日：2016-12-15
申请号：FI20095291
申请日：2009-03-20
Applicant: STORA ENSO OYJ
Inventor： RÄSÄNEN JARI , PENTTINEN TAPANI , HARLIN ALI , HILTUNEN JAAKKO , WIKBERG HANNE , TAMMELIN TEKLA
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公开(公告)号：CA2907844A1
公开(公告)日：2014-10-16
申请号：CA2907844
申请日：2014-04-08
Applicant: STORA ENSO OYJ
Inventor： RASANEN JARI , HARLIN ALI , AALTONEN OLLI , LINNEKOSKI JUHA , ANTHONYKUTTY JINTO
IPC: C10G3/00 , C07C1/207 , C07C4/06 , C07C11/02 , C07C15/08 , C07C51/265 , C10G45/02 , C10G49/04 , C10G65/12
Abstract: The present invention relates to a method of deoxygenating tall oil pitch, yielding aliphatic and aromatic hydrocarbons. The invention even comprises turning the aliphates into polymerizable olefins by steam cracking, and turning the aromates into polymerizable terephthalic acid by oxygenation and, as necessary, rearrangement. The monomers can be used for the production of polymers of partially or completely biologic origin. According to the invention, tall oil pitch is first heated to turn it into liquid, which is then fed into a catalyst bed and catalytically deoxygenated with hydrogen. The deoxygenation catalyst is preferably a NiMo catalyst and, in addition, a cracking catalyst can be used, such as an acidic zeolite catalyst. The deoxygenated product stream is cooled down so as to obtain a liquid, which is distilled for separation of the aliphatic and aromatic hydrocarbons for use in the production of the respective monomers and finally polymers.
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