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公开(公告)号:JPH07329235A
公开(公告)日:1995-12-19
申请号:JP12628094
申请日:1994-06-08
Applicant: TORAY INDUSTRIES
Inventor: NAGAI ITSUO , TANAKA YOSHIO , ASAKURA MASAYOSHI
Abstract: PURPOSE:To provide a metal oxide laminated polypropylene composite film excellent in oxygen barrier properties and steam barrier properties. CONSTITUTION:A metal oxide laminated polypropylene composite film is obtained by providing a resin layer of syndiotactic polypropylene or a mixed resin layer of syndiotactic polypropylene and isotactic polypropylene on at least the single surface of a base layer based on polypropylene and laminating a metal oxide layer to the surface of the resin layer.
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公开(公告)号:JPH07216537A
公开(公告)日:1995-08-15
申请号:JP1098894
申请日:1994-02-02
Applicant: TORAY INDUSTRIES
Inventor: TANAKA SHIGERU , ASAKURA MASAYOSHI , UEHA ISAZUMI
IPC: B32B15/085 , B32B15/08 , C23C14/20
Abstract: PURPOSE:To produce a heat-resistant moistureproof vapor deposition film excellent in heat resistance and moisture proof by vapor depositing a metal on a biaxially oriented polypropylene film having specified thermal fusing temp. and crystallization degree to obtain specified thermal shrinkage and permeability for water vapor. CONSTITUTION:At least one surface of a biaxially oriented polypropylene film having >=165 deg.C peak temp. of thermal fusing temp. and >=50% crystallization degree is treated with corona discharge or plasma to deposit a metal (such as Al, Zn, Si) by vapor deposition. Thus, a film having .24hr/20mum permeability of water vapor is obtd. The film has excellent heat resistance and moisture proof and good dimensional stability.
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公开(公告)号:JPH07188431A
公开(公告)日:1995-07-25
申请号:JP33513293
申请日:1993-12-28
Applicant: TORAY INDUSTRIES
Inventor: ASAKURA MASAYOSHI , HASHIMOTO KOKICHI
Abstract: PURPOSE:To obtain a film excellent in pliability, transparency, heat resistance, low-temp. impact resistance, and elastic recovery from elongation. CONSTITUTION:This film comprises a polypropylene copolymer and 10-60wt.% hydrogenated copolymer comprising at least one polymer block formed mainly from a vinylaromatic compound and at least one polymer block formed mainly from a hydrogenated conjugated diene compound. It preferably has recesses on at least one side which have a depth of 5mum or larger and the density of which along at least a line extending in one direction on the surface is 1-200.
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公开(公告)号:JPH07157573A
公开(公告)日:1995-06-20
申请号:JP30402893
申请日:1993-12-03
Applicant: TORAY INDUSTRIES
Inventor: TANAKA SHIGERU , ASAKURA MASAYOSHI , UEHA KATSUZUMI
Abstract: PURPOSE:To obtain a film excellent in heat and organic solvent resistances and moistureproofness and further fabricabilit} such as printing, vacuum deposition and coating. CONSTITUTION:This heat-resistant and moistureproof film is a film prepared by mixing 70-95wt.% crystalline polypropylene having half the isothermal crystallization time at 125 deg.C of =98.5% isotactic pentad fraction with 5-30wt.% one or more of petroleum resins and terpenic resins. In any of the resins, no polar group is substantially contained. The film has .24hr/0.1mm) moisture permeability.
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公开(公告)号:JPH07133363A
公开(公告)日:1995-05-23
申请号:JP28140993
申请日:1993-11-10
Applicant: TORAY INDUSTRIES
Inventor: TANAKA SHIGERU , ASAKURA MASAYOSHI , FUKADA KUNITADA
Abstract: PURPOSE:To obtain a film having a high optical density and excellent hiding power, impact resistance and steam-barrier, properties. CONSTITUTION:The title film is made from 55-93wt.% crystalline polypropylene, 5-30wt.% hydrogenated ring-opening dicyclopentadiene polymer having a glass transition point of 80 deg.C or above, and 2-15wt.% polyolefin resin of a melting temperature of 150 deg.C or below, and the cross section of the film exhibits a structure which has a void layer in which the dicyclopentadiene polymer forms cores.
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公开(公告)号:JPH06126914A
公开(公告)日:1994-05-10
申请号:JP27878392
申请日:1992-10-16
Applicant: TORAY INDUSTRIES , TORAY GOSEI FILM KK
Inventor: ASAKURA MASAYOSHI , ICHIMURA TADAO , TSUCHIYA KATSUHIRO
Abstract: PURPOSE:To provide a composite polyolefin film for print laminate which is excellent in heat laminate aptitude for print laminate printing paper. CONSTITUTION:In a composite film wherein a polyolefin thermofusible resin (layer B) is laminated on one side of a cast film (layer A) having polypropylene as a main component, a surface glossiness of the layer A is 110% or higher and its mean refractive index is within a range of 1.500-1.5080. Therefore, transfer resistance of a flaw of a metallic roll in print laminate can be improved, and print laminate printing paper having a high quality surface can be obtained.
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公开(公告)号:JPH05295146A
公开(公告)日:1993-11-09
申请号:JP12665892
申请日:1992-04-21
Applicant: TORAY INDUSTRIES
Inventor: TANAKA SHIGERU , ASAKURA MASAYOSHI , TAKEUCHI MASANORI
IPC: B29C55/12 , B29K23/00 , B29K105/04 , B29L7/00 , B29L9/00 , B32B5/18 , B32B7/02 , B32B27/32 , C08J5/18 , C08J9/00 , C08L23/12 , C08L101/00
Abstract: PURPOSE:To obtain the objective film having a high optical density and excellent hiding power, impact resistance and steam barrier properties, comprising a resin of a specified composition and having a specified cross-section and a specified optical density. CONSTITUTION:The film is made from a resin having a composition of 65-93wt.% crystalline PP, 5-20wt.% amorphous resin (e.g. polycarbonate resin) of a heat distortion temperature of 120 deg.C or above, and 2-15wt.% polyolefin resin of a melting temperature of 140 deg.C or below (e.g. ethylene/methyl methacrylic acid copolymer). The cross section of the film has a three-layer structure composed of an intermediate layer made of an unfoamed layer and the upper and lower layers each made of a foamed layer. The average ratio of the thickness of the intermediate layer to the entire thickness of the film cross section is 5-60%, and the optical density in a film thickness of 30mum is 0.40 or above.
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公开(公告)号:JPH04453B2
公开(公告)日:1992-01-07
申请号:JP3257984
申请日:1984-02-24
Applicant: TORAY INDUSTRIES
Inventor: ASAKURA MASAYOSHI , TANAKA KAZUHIRO , OKAMURA JUJI
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公开(公告)号:JPH02286216A
公开(公告)日:1990-11-26
申请号:JP10851289
申请日:1989-04-27
Applicant: TORAY INDUSTRIES
Inventor: ASAKURA MASAYOSHI , YAMAUCHI HIDEYUKI , TSUNASHIMA KENJI
Abstract: PURPOSE:To produce a polyester film which is excellent in adhesive properties in printing ink and a metallic vapor-deposited film and resistance to moisture by melting oxyketone metallic complex compd. and mixing this complex compd. with polyester in vacuum and extruding this mixture. CONSTITUTION:The content of oxyketone metallic complex compd. is regulated to 0.01 - 3 wt.% for polyester resin. In the case less than this range, the adhesive properties to a metallic vapor-deposited layer expecially at high humidity and curing are not made remarkable. Further the case exceeding the above-mentioned range is made unpreferable because degree of polymerization is lowered at a time for heating and melting polyester or coloring is easily casued. In the case of mixing oxyketone metallic complex compd. with polyester, such a method is shown that for example, these are supplied to a vacuum vent-type biaxial extruder, heated and melted in vacuum and mixed with each other. At this time, degree of vacuum is preferably regulated to a range within 0.1 - 10 mmHg and heating temp. is preferably regulated to m.p. or more of polyester resin. Further oxyketone metallic complex compd. is melted on at least single side of a film made of polyethylene terephthalate and mixed therewith. A composite film can be formed by laminating a film made of this obtained polyester.
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公开(公告)号:JPH02266937A
公开(公告)日:1990-10-31
申请号:JP8879489
申请日:1989-04-07
Applicant: TORAY INDUSTRIES
Inventor: HIRATA JUN , ASAKURA MASAYOSHI , TSUNASHIMA KENJI
IPC: B32B27/32
Abstract: PURPOSE:To enhance pinhole resistance, the adhesion strength of a deposited film and soldering resistance by forming a polyester film from 1,4- polycyclohexylene dimethylene terephthalate and specifying the thickness of a polyolefin support film. CONSTITUTION:A laminated film is constituted by laminating a polyester film having a thickness of 0.2-1.5mum to the single surface or both surfaces of a polyolefin support film and the polyester film is composed of 1, 4- polycyclohexylene dimethylene terephthalate and the thickness of the polyethylene support film is set to a range of 5-100 times that of the polyester film. Further, the polyolefin film is a non-oriented, uniaxially oriented or biaxially oriented film composed of a polymer or copolymer of olefin and, as polyolefin, a propylene copolymer having an m.p. of 100-150 deg.C is especially pref. This laminated film can be used in a dielectric for a condenser or a thermal transfer ribbon.
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