公开(公告)号：US438739A

公开(公告)日：1890-10-21

申请号：US438739D

CPC classification number: B05D1/206 ,  B05C3/02

公开(公告)号：JPS60196934A

公开(公告)日：1985-10-05

申请号：JP5207884

申请日：1984-03-21

Applicant: Canon Inc

Inventor： NISHIMURA YUKIO ,  MUNAKATA HIROHIDE ,  MATSUDA HIROSHI ,  MIYAZAKI TOSHIHIKO

IPC: H01L49/02 ,  B01J19/00 ,  B05D1/20 ,  C23C26/00 ,  H01L21/312 ,  H01L21/368

CPC classification number: B82Y30/00 ,  B05D1/206 ,  B82Y40/00

Abstract: PURPOSE:To prevent film forming molecular groups from joining together while making it feasible to form uniform molecular film or monomolecular laminated films by a method wherein forming molecular groups spread on a liquid surface are oscillated. CONSTITUTION:Liquid 9' spreading a molecular film thereon is contained in a square water vessel 1. A monomolecular film spread on the liquid surface 9 maintains the solid film status pertinent to the film forming process provided with specified surface tension by a float 3. A flat substrate is attachably and detachably fixed to a carrier supporting jig 15 provided on a carrier lifting arm 11 with a lifting mechanism so that the carrier lifting arm 11 may shift almost perpendicularly traversing the spread liquid surface 9 of monomolecular film. A carrier 10 can shift the monomolecular film spread on the liquid surface 9 to itself by means of transfer to form the monomolecular film or monomolecular laminated films with desired lamination. Through these procedures, even and non-defective monomolecular film or monomolecular laminated films free of defect may be formed improving dynamic characteristics, conductivity and breakdown voltage etc.

Abstract translation: 目的：为了防止成膜分子基团连接在一起，同时通过其中形成分布在液面上的分子基团的方法形成均匀的分子膜或单分子层叠膜是可行的。 构成：在平方水容器1中包含在其上铺展分子膜的液体9'。在液面9上扩散的单分子膜保持与通过浮子3提供具有特定表面张力的成膜工艺相关的固体膜状态。 平面基板通过提升机构可拆卸地固定在设置在载体提升臂11上的托架支撑夹具15上，使得托架提升臂11可以几乎垂直地移动穿过单分子膜的展开液面9。 载体10可以通过转移将液面9上扩散的单分子膜转移到其自身以形成具有期望层压的单分子膜或单分子层叠膜。 通过这些方法，可以形成改善动态特性，导电性和击穿电压等的无缺陷单分子膜或单分子层叠膜。

公开(公告)号：JPS60193328A

公开(公告)日：1985-10-01

申请号：JP4811184

申请日：1984-03-15

Applicant: Canon Inc

Inventor： MIYAZAKI TOSHIHIKO ,  HIRAI YUTAKA

IPC: H01L49/02 ,  B01J19/00 ,  B05D1/20 ,  C23C26/00 ,  H01L21/312 ,  H01L21/368

CPC classification number: B82Y30/00 ,  B05D1/206 ,  B82Y40/00

Abstract: PURPOSE:To improve a yield of continuous cumulation of molecules for film forming, by providing with liquid-flow generating means in the liquid bath for expanding the film forming molecules, and by controlling a surface density of the film forming molecules by changing the liquid-flow when a desired monomolecular cumulated film is formed. CONSTITUTION:On forming a thin film bearing optical functions which a logical device, a memory device and a photoelectric converting device, etc. have, the thin film consisting of organic molecules is formed with a monomolecular cumulation method. Water from a water flow generating means 7 is flowed into a water bath 3, the water surface is dammed by a barrier 8 being placed on the water bath 3 so as to overflow the excess water, and organic solution is dripped onto the water surface being dammed to form a film. That is to say, the solution of 0.1ml in which stearic acid is being melted in a solvent of chloroform at a rate of 1X10 M/l is dripped onto the water surface. The width of the water bath 3 at the surface pressure producing area 11 including the dripping area 9 is made narrow, for example 2cm, and the width of the cumulating area 10 is made wide, for example 20cm, to allow flow rates of these areas to change into about 2cm/sec from 20cm/sec. In this way, the cumulation yield can be improved to 50-100%.

Abstract translation: 目的：为了提高用于成膜的分子的连续累积的产率，通过在用于膨胀成膜分子的液槽中提供液体流产生装置，并且通过改变成膜分子来控制成膜分子的表面密度， 当形成所需的单分子累积膜时流动。 构成：在形成具有逻辑器件，存储器件和光电转换器件等的薄膜承载光学功能的情况下，由单分子累积方法形成由有机分子组成的薄膜。 来自水流产生装置7的水流入水浴3中，水面被放置在水浴3上的屏障8阻挡，以溢出多余的水，有机溶液滴在水面上 阻止了形成一部电影。 也就是说，将0.1ml其中硬脂酸以1×10 -3 M / l的速率在氯仿溶剂中熔融的溶液滴在水面上。 包括滴水区域9的表面压力产生区域11处的水浴3的宽度变窄，例如2cm，并且使累积区域10的宽度变宽，例如20cm，以允许这些区域的流速 从20cm / sec变为约2cm / sec。 以这种方式，累积产量可以提高到50-100％。

公开(公告)号：JPS60189929A

公开(公告)日：1985-09-27

申请号：JP4567984

申请日：1984-03-12

Applicant: Canon Inc

Inventor： TOMITA YOSHINORI ,  MUNAKATA HIROHIDE ,  HARUTA MASAHIRO ,  HIRAI YUTAKA ,  MIYAZAKI TOSHIHIKO

IPC: H01L49/02 ,  B01J19/00 ,  B05D1/20 ,  C23C26/00 ,  H01L21/312 ,  H01L21/368

CPC classification number: B82Y30/00 ,  B05D1/206 ,  B82Y40/00

Abstract: PURPOSE:To enable the improvement in the rate of cumulation by reducting the rotation of molecules at the tine of removing monomolecular films from the liquid surface by a method wherein a carrier to be formed into films is rotated and moved up and down on the liquid surface where a monomolecular film is being developed. CONSTITUTION:The circular cylinder 3 is rotated by rotating a gear 5 by transmission of motor rotation to a motor shaft 7, and thus by driving a chain 9 stretched between a gear 4 fixed to a cylinder rotary shaft 6. The cylinder 3 is moved up and down by varying the length of a music wire 10 fixed between the rotary shaft 6 and the motor shaft 7 by means of a music-wire wind-up 11. After a monomolecular film is developed over the liquid surface by dripping a desired group of molecules for film formation down on the liquid 2, the cylinder 3 is rotated with this cylinder 3 kept at a desired level above the liquid surface, when a monomolecular film or a monomolecular cumulative film of desired cumulative frequency is formed on the cylinder 3.

Abstract translation: 目的：为了使通过在液面上除去单分子膜的分子的旋转减少的方式提高累积率，通过这样一种方法，其中待成膜的载体在液面上上下移动 正在开发单分子膜。 构成：通过将电动机旋转传递到电动机轴7，从而通过驱动在固定于气缸旋转轴6的齿轮4之间拉伸的链条9来使圆筒3旋转。气缸3向上移动 并且通过借助于音乐线缠绕11来改变固定在旋转轴6和电动机轴7之间的音乐线10的长度来降低。通过滴落所需组的单分子膜在液面上显影， 用于在液体2上成膜的分子，当在气缸3上形成单分子膜或所需累积频率的单分子累积膜时，气缸3旋转，使气缸3保持在液面以上所需的水平。

公开(公告)号：JPS61142746A

公开(公告)日：1986-06-30

申请号：JP25296885

申请日：1985-11-13

Applicant: Vickers Plc

Inventor： UIRIAMU ANDORIYUU BAAROO ,  GURAHAMU MEERINTON

IPC: H01L51/05 ,  B05C3/02 ,  B05C3/10 ,  B05C11/00 ,  B05C11/11 ,  B05D1/20 ,  C23C26/00 ,  H01L49/02 ,  H01L51/40

CPC classification number: B82Y30/00 ,  B05C3/02 ,  B05C11/00 ,  B05C11/11 ,  B05D1/206 ,  B82Y40/00

公开(公告)号：JPS6135515A

公开(公告)日：1986-02-20

申请号：JP15684185

申请日：1985-07-15

Applicant: Nima Technol Ltd

Inventor： FURANKU AMIN GURANFUERUDO

IPC: H01L51/05 ,  B05C3/02 ,  B05C3/05 ,  B05D1/20 ,  H01L21/205 ,  H01L49/02 ,  H01L51/40

CPC classification number: B82Y30/00 ,  B05C3/02 ,  B05C3/05 ,  B05D1/206 ,  B82Y40/00

公开(公告)号：JPS60193325A

公开(公告)日：1985-10-01

申请号：JP4810884

申请日：1984-03-15

Applicant: Canon Inc

Inventor： MIYAZAKI TOSHIHIKO ,  HIRAI YUTAKA

IPC: B05C3/18 ,  B01J19/00 ,  B05D1/20 ,  C23C26/00 ,  H01L21/312 ,  H01L21/368 ,  H01L49/02 ,  H01L51/05 ,  H01L51/40

CPC classification number: B82Y30/00 ,  B05D1/206 ,  B82Y40/00

Abstract: PURPOSE:To cumulate easily and continuously a monomolecular film and to improve a pH condition, by controlling surface pressure of the monomolecular film so as to attain a desired surface density, and by providing with a pH controller in a liquid-circulating system. CONSTITUTION:A water-circulating closed circuit is constituted by a water circulating path 12, a reservoir 13, pumps 14, 15 and a water bath 3. With a barrier 8 contacted onto the water bath 3, solution of 0.1ml in which stearic acid is being melted in chloroform being a solvent at a rate of 1X10 M/l, is flowed in at the upstream dripping area 9 at a rate of 20cm/sec. Next, a monomolecular film 2 is cumulated on the cumulating area 10 near the barrier 8. An output of a pH sensor 21 which is being immersed in the water bath immediately before the area 9 is converter into an analogue signal by employing a vacuum-tube voltmeter 22. The analogue signal is delivered into a micro-computer 17 which contains a micro-processor 18 and a memory 19 and an interface circuit 20, via an A/D converter 23. The output of the micro-computer 17 then can operate a cylinder 26a containing sodium hydroxide 25a and a cylinder 26b containing hydrochloric acid 26b to control pH of the water.

Abstract translation: 目的：通过控制单分子膜的表面压力以达到所需的表面密度，并且通过在液体循环系统中设置pH控制器，能够容易且连续地累积单分子膜并改善pH条件。 构成：水循环闭路由水循环路径12，储存器13，泵14,15和水浴3构成。将屏障8接触到水浴3上，将0.1ml的溶液加入硬脂酸 在溶剂中以1×10 -3 M / l的速率在氯仿中熔融，以20cm / sec的速率在上游滴落区域9流动。 接着，在隔壁8附近的累积区域10上累积单分子膜2.通过使用真空管将浸渍在区域9之前的水浴中的pH传感器21的输出转换为模拟信号 电压表22.模拟信号通过A / D转换器23传送到包含微处理器18和存储器19以及接口电路20的微型计算机17中。然后，微计算机17的输出可以操作 包含氢氧化钠25a的气缸26a和含有盐酸26b以控制水的pH的气缸26b。

公开(公告)号：US20240299975A1

公开(公告)日：2024-09-12

申请号：US18599941

申请日：2024-03-08

Applicant: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA

Inventor： Luat Thanh Vuoug ,  Sophie Weiss ,  Frank Rodriquez ,  Ji Feng

IPC: B05D1/20 ,  C09D5/02 ,  C09D7/20 ,  C09D7/40 ,  C09D7/61 ,  C09D125/06

CPC classification number: B05D1/204 ,  B05D1/206 ,  C09D5/02 ,  C09D7/20 ,  C09D7/61 ,  C09D7/67 ,  C09D7/68 ,  C09D7/70 ,  C09D125/06

Abstract: A method is disclosed of three-dimensional (3D) free-form printing for coating free-form objects, the method including: arranging a free-form object in a Langmuir-Blodgett (LB) trough filed with a liquid, the LB trough designed based on a shape of the free-form object; arranging an LB film comprising a plurality of colloidal nanospheres on a surface of the liquid within the LB trough; and draining the liquid from the LB trough to form a self-assemble film of the colloidal nanoparticles on a surface of the free-form object.

公开(公告)号：US20100029001A1

公开(公告)日：2010-02-04

申请号：US12515609

申请日：2007-11-21

Applicant: Xiaodon Chen ,  Lifeng Chi ,  Harald Fuchs ,  Michael Hirtz

Inventor： Xiaodon Chen ,  Lifeng Chi ,  Harald Fuchs ,  Michael Hirtz

IPC: B05C3/10 ,  B32B9/04 ,  B32B17/06 ,  B32B15/04 ,  B05D3/02 ,  C12N5/00

CPC classification number: B05D1/206 ,  B82Y30/00 ,  B82Y40/00 ,  Y10T428/31504 ,  Y10T428/31678

Abstract: A rotating transfer device for transfer of a film to a substrate at a gas-liquid interface, the rotating transfer device comprising a substrate holder holding the substrate, and a rotational positioning unit for rotating the substrate holder, the rotational positioning unit having a pivot to which the substrate holder is attached, whereby the pivot is angled between 0° and 60° to the plane of the interface surface. As a result, LB patterns with different dimensions and orientations that depend on the transfer velocity can be generated simultaneously.

Abstract translation: 一种旋转传送装置，用于在气 - 液界面处将胶片转印到基片上，旋转传送装置包括保持基片的基片支架和用于旋转基片支架的旋转定位单元，该转动定位单元具有枢轴 其中衬底保持器被附接，由此枢轴与接口表面的平面成0°到60°的角度。 结果，可以同时产生具有取决于传送速度的不同尺寸和取向的LB图案。

公开(公告)号：US5908666A

公开(公告)日：1999-06-01

申请号：US933937

申请日：1997-09-19

Applicant: Naoki Nakamura

Inventor： Naoki Nakamura

IPC: B05D1/20 ,  B01J19/00 ,  B05C3/02 ,  B05D1/36 ,  B05D7/00

CPC classification number: B05D1/202 ,  B05D1/206 ,  B82Y30/00 ,  B82Y40/00

Abstract: A process for producing a Langmuir-Blodgett (LB) film, comprising the steps of: developing a monomolecular film of a film forming molecule on the surface of water and transferring the monomolecular film on a substrate, wherein a film forming solution containing the film forming molecule is dropped on the surface of water while allowing a water stream directed to the substrate to act on the surface of water or allowing an air stream directed to the substrate to act on a position in the vicinity of the surface of water; a condensed film of the film forming molecule is rapidly formed upon dropping of the film forming solution by taking advantage of the action of the water stream or air stream; and, after or simultaneously with the formation of the condensed film, the condensed film is transferred onto the substrate. This process can prevent the inclusion of impurities, enabling an LB film to be produced using a small apparatus without using any large developing trough. Further, a hybrid LB film can be formed by changing the film forming molecule dropped on the surface of water in the course of the formation of the LB film.

Abstract translation: 一种制备Langmuir-Blodgett（LB）膜的方法，包括以下步骤：在水表面上形成成膜分子的单分子膜，并将单分子膜转移到基材上，其中含有成膜 分子被滴在水面上，同时允许指向基底的水流作用在水表面上，或允许指向基底的空气流作用在水表面附近的位置; 通过利用水流或空气流的作用，在成膜溶液滴下时快速形成成膜分子的冷凝膜; 并且在形成冷凝膜之后或同时形成冷凝膜，将冷凝的膜转移到基板上。 该方法可以防止杂质的包含，从而能够在不使用任何大的显影槽的情况下使用小型装置制造LB膜。 此外，可以通过在形成LB膜的过程中改变落在水面上的成膜分子来形成混合LB膜。