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    METHOD FOR MAKING POLYOLEFIN NANOCOMPOSITES
    61.
    发明申请
    METHOD FOR MAKING POLYOLEFIN NANOCOMPOSITES 审中-公开
    制备聚烯烃纳米复合材料的方法

    公开(公告)号：WO2003106549A2

    公开(公告)日：2003-12-24

    申请号：PCT/IB2003/002688

    申请日：2003-06-11

    Applicant: BASELL POLIOLEFINE ITALIA S.p.A.

    Inventor： ROSENTHAL, Jay, S. ,  WOLKOWICZ, Michael, D.

    IPC: C08K3/34

    CPC classification number: C08K5/20 ,  C08K3/346 ,  C08K5/10 ,  C08K9/04 ,  C08L23/12 ,  C08L51/06 ,  C08L23/10 ,  C08L2666/24

    Abstract: A polyolefin nanocomposite is prepared by melt blending (a) a polyolefin and (b) a smectite clay in the presence of at least one intercalating agent that is a solid at room temperature and is selected from the group consisting of (a) hydroxy-substituted carboxylic acid esters, (b) amides, (c) hydroxy-substituted amides, and (d) oxidized polyolefins, wherein the ratio of the intercalating agent to the clay is at least 1:3, based on the ash content of the clay.

    Abstract translation: 聚烯烃纳米复合材料通过在至少一种在室温下为固体的嵌入剂存在下熔融共混（a）聚烯烃和（b）蒙脱石粘土而制备，并且选自（a）羟基取代的 羧酸酯，（b）酰胺，（c）羟基取代的酰胺和（d）氧化的聚烯烃，其中基于粘土的灰分含量，插层剂与粘土的比例至少为1:3。

    POLYOLEFIN COMPOSITIONS HAVING HIGH TENACITY
    63.
    发明申请
    POLYOLEFIN COMPOSITIONS HAVING HIGH TENACITY 审中-公开
    具有高温度的聚烯烃组合物

    公开(公告)号：WO2003076509A1

    公开(公告)日：2003-09-18

    申请号：PCT/IB2003/000835

    申请日：2003-03-06

    Applicant: BASELL POLIOLEFINE ITALIA S.P.A.

    Inventor： GLOGOVSKY, Todd ,  BUTALA, Robert, G. ,  HAN, Choong, Y. ,  ENNIS, Gerald, John ,  GOBERTI, Paolo

    IPC: C08L23/10

    CPC classification number: C08L23/16 ,  C08L23/10 ,  C08L23/142 ,  C08L2308/00 ,  C08L2666/06

    Abstract: A polyolefin composition suitable for preparing single ply roofing membranes, comprising: (A) from about 15 to 40% by weight of a crystalline copolymer of propylene with at least one alpha-olefin of formula H 2 C=CHR 1 , where R 1 is H or a C 2-8 linear or branched alkyl, containing at least about 90% by weight of propylene, having solubility in xylene at room temperature lower than about 15% by weight; (B) from about 60 to about 85% by weight of an elastomeric fraction comprising: (1) a copolymer of propylene with ethylene containing about 20 to about 35% by weight ethylene, and having solubility in xylene at room temperature greater than about 70% by weight, the intrinsic viscosity of the xylene soluble fraction being higher than about 3.0dl/g; and (2) a copolymer of ethylene with at least one alpha-olefin of formula H 2 C=CHR 2 , where R 2 is a C 2-8 linear or branched alkyl, containing about 15% to 40% by weight alpha-olefin, and having solubility in xylene at room temperature greater than about 25% by weight, the intrinsic viscosity of the xylene soluble fraction ranging from about 0.5 to about 5.0dl/g; the (1) (2) weight ratio ranging from about 1:5 to about 5:1. The polyolefin composition of the invention, preferably prepared by sequential polymerization in at least three stages, has tensile strength at break ≥ 25 Mpa, elongation at break ≥ 700 Mpa and toughness ≥ 150 Mpa.

    Abstract translation: 一种适于制备单层屋顶膜的聚烯烃组合物，其包含：A约15至40重量％的丙烯与至少一种式IIC = CHR1的α-烯烃的结晶共聚物，其中R 1为H或C 2-8 含有至少约90重量％丙烯的直链或支链烷基，其在室温下在二甲苯中的溶解度低于约15重量％B，约60至约85重量％的弹性体级分包括：1 丙烯与含有约20至约35重量％乙烯的乙烯，并且在室温下在二甲苯中的溶解度大于约70重量％，二甲苯可溶部分的特性粘度高于约3.0dl / g，2共聚物 的乙烯与至少一种式H2C = CHR2的α-烯烃，其中R2是C2-8直链或支链烷基，含有约15％至40％（重量）的α-烯烃，并且在室温下在二甲苯中的溶解度大于 约25％ 重量，二甲苯可溶部分的特性粘度范围为约0.5至约5.0dl / g，重量比为约1:5至约5:1。 本发明的聚烯烃组合物优选通过至少三个阶段的顺序聚合制备，断裂强度> 25Mpa，断裂伸长率> 700Mpa，韧性> 150Mpa。

    COMPONENTS AND CATALYSTS FOR THE POLYMERIZATION OF OLEFINS
    64.
    发明申请
    COMPONENTS AND CATALYSTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的组分和催化剂

    公开(公告)号：WO2003022894A1

    公开(公告)日：2003-03-20

    申请号：PCT/EP2002/010049

    申请日：2002-09-04

    Applicant: BASELL POLIOLEFINE ITALIA S.P.A. ,  MORINI, Giampiero ,  BALBONTIN, Giulio ,  GULEVICH, Yuri, V. ,  VITALE, Gianni

    Inventor： MORINI, Giampiero ,  BALBONTIN, Giulio ,  GULEVICH, Yuri, V. ,  VITALE, Gianni

    IPC: C08F10/00

    CPC classification number: C08F4/651 ,  C08F110/06 ,  C08F2500/15

    Abstract: The present invention relates to a solid catalyst component for the polymerization of olefins CH 2 =CHR in which R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and an electron donor selected from maleates of a particular formula. Said catalyst components when used in the polymerization of olefins, and in particular of propylene, are capable to give polymers in high yields and with high isotactic index expressed in terms of high xylene insolubility.

    Abstract translation: 本发明涉及用于烯烃CH 2 = CHR的聚合的固体催化剂组分，其中R是氢或具有1-12个碳原子的烃基，包括Mg，Ti，卤素和选自马来酸酯的电子给体 。 当用于烯烃聚合，特别是丙烯时，所述催化剂组分能够以高产率和高二甲苯不溶性表现的高全同立构指数得到聚合物。

    POLYPROPYLENE GRAFT COPOLYMER/FLUORINATED POLYOLEFIN BLENDS
    65.
    发明申请
    POLYPROPYLENE GRAFT COPOLYMER/FLUORINATED POLYOLEFIN BLENDS 审中-公开
    聚丙烯共聚物/氟化聚烯烃共混物

    公开(公告)号：WO2003014221A1

    公开(公告)日：2003-02-20

    申请号：PCT/IB2002/003081

    申请日：2002-08-05

    Applicant: BASELL POLIOLEFINE ITALIA S.P.A.

    Inventor： NYOGI, Suhas, G.

    IPC: C08L51/06

    CPC classification number: C08F255/02 ,  C08L51/06 ,  C08F220/00 ,  C08L2666/04

    Abstract: The thermal stability of graft copolymers can be improved by blending (1) a graft copolymer comprising a backbone of a propylene polymer material having graft polymerized thereto a monomer selected from the group consisting of (a) an ester of an acrylic acid substituted at the alpha carbon atom by a 1-3 alkyl group and (b) a combination of (i) an ester of an acrylic acid substituted at the alpha carbon atom by a 1-3 alkyl group and (ii) an ester of an unsubstituted acrylic acid, or an acrylic acid substituted at the alpha carbon atom by a 1-3 carbon alkyl group and (2) about 1 weight % to about 25 weight % of a fluorinated olefin polymer, wherein the ratio of the polymerized monomer to the fluorinated olefin polymer is about 25:1 to about 0.5:1.

    Abstract translation: 接枝共聚物的热稳定性可以通过共混（1）包含具有接枝聚合的丙烯聚合物材料的主链的接枝共聚物来提高，所述接枝共聚物具有选自以下的单体：（a）在α 碳原子1-3个烷基，（b）（i）在α碳原子被1-3个烷基取代的丙烯酸的酯和（ii）未取代的丙烯酸的酯的组合， 或在α碳原子上被1-3个碳烷基取代的丙烯酸和（2）约1重量％至约25重量％的氟化烯烃聚合物，其中聚合单体与氟化烯烃聚合物的比例为 约25:1至约0.5:1。

    CONTROLLING THE MOLECULAR WEIGHT OF GRAFT COPOLYMERS USING POLYMERIZABLE CHAIN TRANSFER AGENTS
    66.
    发明申请
    CONTROLLING THE MOLECULAR WEIGHT OF GRAFT COPOLYMERS USING POLYMERIZABLE CHAIN TRANSFER AGENTS 审中-公开
    使用可聚合链转移剂控制共聚物的分子量

    公开(公告)号：WO2003014175A1

    公开(公告)日：2003-02-20

    申请号：PCT/IB2002/003082

    申请日：2002-08-05

    Applicant: BASELL POLIOLEFINE ITALIA S.P.A.

    Inventor： SONG, Cheng, Q.

    IPC: C08F255/02

    CPC classification number: C08F2/38 ,  C08F255/02

    Abstract: The molecular weight of a graft copolymer is reduced by carrying out the following steps in a non-oxidizing atmosphere: (1) treating a propylene polymer material with an organic compound that is a free radical polymerization initiator, (2) treating the propylene polymer material with about 2 to about 240 parts per hundred parts of the propylene polymer material, of at least one vinyl-substituted grafting monomer in the presence of about 0.5% to about 5% of a polymerizable chain transfer agent that is a derivative of allyl alcohol, and (3) removing any unreacted monomer, decomposing any unreacted initiator, and deactivating any residual free radicals in the material.

    Abstract translation: 通过在非氧化性气氛中进行以下步骤来降低接枝共聚物的分子量：（1）用作为自由基聚合引发剂的有机化合物处理丙烯聚合物材料，（2）处理丙烯聚合物材料 在约0.5％至约5％的作为烯丙醇的衍生物的可聚合链转移剂的存在下，每100份丙烯聚合物材料约2至约240份，至少一种乙烯基取代的接枝单体， 和（3）除去任何未反应的单体，分解任何未反应的引发剂，并使材料中的任何残留的自由基失活。

    PROCESS FOR PREPARING ALKYLIDENE SUBSTITUTED SUCCINIC ACID ESTERS
    67.
    发明申请
    PROCESS FOR PREPARING ALKYLIDENE SUBSTITUTED SUCCINIC ACID ESTERS 审中-公开
    制备烷基取代的酸性酯的方法

    公开(公告)号：WO2002098837A1

    公开(公告)日：2002-12-12

    申请号：PCT/EP2002/006097

    申请日：2002-06-04

    Applicant: BASELL POLIOLEFINE ITALIA S.P.A ,  MORINI, Giampiero ,  GULEVICH, Yuri ,  FACHINI, Marco ,  PRINI, Giansiro ,  CRISTOFORI, Antonio

    Inventor： MORINI, Giampiero ,  GULEVICH, Yuri ,  FACHINI, Marco ,  PRINI, Giansiro ,  CRISTOFORI, Antonio

    IPC: C07C67/343

    CPC classification number: C07C67/343 ,  C07C67/11 ,  C07C69/593

    Abstract: A process for the preparation of alkylidene substituted succinates comprising a step (a) in which is carried out the reaction of a carbonilic compound, a succinic and a base in a reaction medium and a step (b) in which the alkylidene substituted product obtained in (a) is esterified, characterized in that the succinic ester is used in a molar amount substantially equal to, or lower than, the amount of compound carbonilic compound, (ii) the base is used in a molar amount substantially equal to the succinic ester and is selected from metal hydrides and metal and alkoxides, and (iii) the reaction medium comprises an aprotic liquid medium or a protic liquid medium having a Ka, measured in water, lower than that of iPrOH.

    Abstract translation: 一种制备亚烷基取代的琥珀酸盐的方法，包括步骤（a），其中在反应介质中进行碳酸化合物，琥珀酸和碱的反应，和步骤（b），其中获得的亚烷基取代的产物 （a）被酯化，其特征在于所述琥珀酸酯的用量基本上等于或低于化合物碳化合物的量，（ii）碱的用量基本上等于琥珀酸酯 并且选自金属氢化物和金属和醇盐，和（iii）反应介质包含非质子液体介质或具有低于iPrOH的Ka测量的Ka的质子液体介质。

    POLYPROPYLENE RESIN COMPOSITION
    68.
    发明申请
    POLYPROPYLENE RESIN COMPOSITION 审中-公开
    聚丙烯树脂组合物

    公开(公告)号：WO2002096960A2

    公开(公告)日：2002-12-05

    申请号：PCT/EP2002/005603

    申请日：2002-05-21

    Applicant: BASELL POLIOLEFINE ITALIA S.P.A. ,  IWASHITA, Toshiyuki

    Inventor： IWASHITA, Toshiyuki

    IPC: C08F8/00

    CPC classification number: C08K5/057 ,  C08F8/50 ,  C08F2810/10 ,  C08K3/22 ,  C08K3/2279 ,  C08K5/0091 ,  C08K5/14 ,  C08L23/10 ,  C08L2023/42 ,  C08L2205/02 ,  C08L2666/04 ,  C08F110/06

    Abstract: A polypropylene resin composition containing (A) a polypropylene resin treatment product obtained by adding from (0.05) to (5) weight parts of an organic peroxide to (100) weight parts of a polypropylene resin with a melt flow rate of from (0.1) to (50) g/10min and carrying out a melt treatment and (B) from (0.01) to (2) weight parts of an oxide of the group (2) or (12) metal of the periodic table or a metal alkoxide of defined formula to (100) weight parts of a resin content of the above polypropylene resin treatment product.

    Abstract translation: 一种聚丙烯树脂组合物，其含有（A）通过从（0.05）〜（5）重量份的有机过氧化物加入（100）重量份熔体流动速率为（0.1）的聚丙烯树脂得到​​的聚丙烯树脂处理产物， 至（50）g / 10min，进行熔融处理，和（B）（0.01）至（2）重量份的元素周期表第（2）或（12）族金属的氧化物或金属醇盐 （100）重量份上述聚丙烯树脂处理产品的树脂含量。

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