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    COMPOSITION FOR IMPROVED NICKEL-LIGAND SOLUBILITY
    61.
    发明公开
    COMPOSITION FOR IMPROVED NICKEL-LIGAND SOLUBILITY 审中-公开
    ZUSAMMENSETZUNGFÜRVERBESSERTENICKELLIGANDLÖSLICHKEIT

    公开(公告)号：EP2928598A1

    公开(公告)日：2015-10-14

    申请号：EP13812362.5

    申请日：2013-12-06

    Applicant: Invista Technologies S.à.r.l.

    Inventor： VOS, Thomas E.

    IPC: B01J31/18 ,  C07C253/10 ,  C07C53/10

    CPC classification number: B01J31/185 ,  B01J37/00 ,  B01J2231/322 ,  B01J2531/847 ,  B01J2531/90 ,  C07C253/10 ,  C07C255/07 ,  C07C255/04

    Abstract: In the hydrocyanation reaction of butadiene proceeding through pentenenitriles to adiponitrile, catalysis by complexes of zerovalent nickel with bidentate phosphorus-based ligands of the NiL
    2 A type wherein L
    2 is a bidentate ligand and A is an unsaturated compound, can be rate-limited by the solubility of the catalytic complex. The present invention concerns solvent compositions for the nickel-ligand complex comprising mixtures of unsaturated nitriles that provide for increased metal solubility, particularly in the absence of a Lewis acid promoter, resulting in higher hydrocyanation reaction rates in an industrial-scale process for production of important nylon manufacturing intermediates. The mixed nitrile solvent compositions can include mixtures of pentenenitriles and/or methylbutenenitriles. The mixtures of mixed unsaturated nitriles can be, at least in part, from recycle streams from the hydrocyanation reaction for which the nickel-bidentate ligand complexes are used as catalysts.

    Abstract translation: 在通过戊烯腈进行己二腈的丁二烯的氢氰化反应中，通过零价镍的络合物与NiL2A型的二齿磷系配体的催化作用，其中L2是二齿配体，A是不饱和化合物，可以通过溶解度 催化复合物。 本发明涉及镍 - 配体络合物的溶剂组合物，其包含不饱和腈的混合物，其提供增加的金属溶解度，特别是在不存在路易斯酸促进剂的情况下，导致在工业规模生产过程中较高的氢氰化反应速率 尼龙制造中间体。 混合的腈溶剂组合物可以包括戊烯腈和/或甲基丁烯腈的混合物。 混合不饱和腈的混合物可以至少部分地来自使用镍二齿配位体配合物作为催化剂的氢化氰化反应的再循环流。

    PROCESSES TO DYE AND TREAT BCF YARN
    62.
    发明公开
    PROCESSES TO DYE AND TREAT BCF YARN 审中-公开
    染色和处理BCF纱线的过程

    公开(公告)号：EP2898136A1

    公开(公告)日：2015-07-29

    申请号：EP13839626.2

    申请日：2013-09-18

    Applicant: Invista Technologies S.à.r.l.

    Inventor： TUNG, Wae-Hai ,  RITTENHOUSE, Ronnie

    IPC: D06M13/248 ,  D06M13/10 ,  D06P1/36

    CPC classification number: D06P3/24 ,  D06M13/52 ,  D06M15/70 ,  D06M23/02 ,  D06P1/0016 ,  D06P3/241 ,  D06P3/26 ,  D06P3/52 ,  D06P3/521 ,  D06P3/54 ,  D06P3/8214 ,  D06P5/02 ,  D06P5/04 ,  D06P5/08

    Abstract: Disclosed are processes for applying dyes, stain blocker and anti-soil compositions on BCF yarns during cable or air twisting processes, or heat setting processes, prior to weaving, knitting or tufting. Further discloses are process for applying dyes, stain blocker and anti-soil compositions on BCF yarns prior to heat setting. The processes forego the need to dye and otherwise treat carpets and other textiles made from the BCF yarn using current methods. Also disclosed are systems, BCF yarns, and carpets made from the BCF yarn treated by the disclosed process.

    Abstract translation: 公开了在编织，针织或簇绒之前在电缆或空气加捻过程或热定形过程中将BCF纱线上的染料，阻斑剂和防污组合物施加到BCF纱线上的方法。 进一步公开的是在热定型之前在BCF纱线上涂覆染料，防污剂和防污组合物的方法。 这些工艺放弃了使用现有方法染色和以其他方式处理由BCF纱制成的地毯和其他纺织品的需要。 还公开了系统，BCF纱线和由通过所公开的方法处理的BCF纱线制成的地毯。

    PROCESS FOR THE PURIFICATION OF A CYCLOHEXANE AIR OXIDATION PRODUCT STREAM
    64.
    发明公开
    PROCESS FOR THE PURIFICATION OF A CYCLOHEXANE AIR OXIDATION PRODUCT STREAM 审中-公开
    VERFAHREN ZUR REINIGUNG EINES CYCLOHEXAN-LUOXOXIDATIONSPRODUKTSTROMS

    公开(公告)号：EP2874983A1

    公开(公告)日：2015-05-27

    申请号：EP12741206.2

    申请日：2012-07-19

    Applicant: Invista Technologies S.à.r.l.

    Inventor： VALDEZ, David, Lee

    IPC: C07C29/50 ,  C07C29/76 ,  C07C29/86 ,  C07C35/08 ,  C07C45/33 ,  C07C45/78 ,  C07C45/80 ,  C07C45/82 ,  C07C49/403 ,  C07C407/00 ,  C07C409/14

    CPC classification number: C07C29/50 ,  C07C29/76 ,  C07C29/86 ,  C07C45/33 ,  C07C45/783 ,  C07C45/80 ,  C07C407/003 ,  C07C2601/14 ,  C07C35/08 ,  C07C49/403 ,  C07C409/14

    Abstract: A method is disclosed for removing contaminants from a feed stream to a hydrogenation process that begins with providing a product mixture from an air oxidation reaction. A first liquid separation process and cooling procedure is used on the product mixture to form a cooled product mixture and a first vapor stream. The cooled product mixture is then subjected to a water wash to form a washed product mixture and an aqueous exit stream, wherein a majority of the water soluble other oxidation products from the cooled product mixture are present in the aqueous exit stream. Next, the washed product stream undergoes a second liquid separation and water removal to form a treated product mixture and a second vapor stream. Finally, the treated product mixture is recovered and can be fed to a hydrogenation process.

    Abstract translation: 公开了一种从进料流中除去污染物到加氢过程的方法，该方法从提供来自空气氧化反应的产物混合物开始。 在产物混合物上使用第一液体分离方法和冷却程序以形成冷却的产物混合物和第一蒸气流。 然后将冷却的产物混合物进行水洗以形成洗涤的产物混合物和水性出口流，其中来自冷却的产物混合物的大部分水溶性其它氧化产物存在于水性出口流中。 接下来，洗涤的产物流经历第二次分液和除水以形成经处理的产物混合物和第二蒸气流。 最后，回收处理过的产物混合物，并将其加入氢化过程中。

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