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公开(公告)号:NO330870B1
公开(公告)日:2011-08-01
申请号:NO20010041
申请日:2001-01-04
Applicant: BASF AG
Inventor: WISTUBA ECKEHARDT , SCHWARTZ MANFRED , BECHERT BERTOLD , DENU HANS-JUERGEN
Abstract: The use of an aqueous polymer dispersion for modifying cement bonded mineral coatings for concrete mold bodies. The polymer comprises: (A) a polymer P in the form of ethylenic unsaturated polymer particles with a glass transition temperature of -20 - + 80 C; and (B) an emulsifier for stabilizing the polymer particles. (A) comprises: (i) 90 - 99.9 wt. % hydrophobic, monoethylenic unsaturated monomer(s) (M1) from styrene, butadiene, 1 - 4 C alkylester of methacrylic acid and 2 - 12 C alkylester of acrylic acid; and (ii) 0.1 - 10 wt. % hydrophilic, monoethylenic unsaturated monomer (M2) comprising up to 2 wt. %, based on the total amount of monomer of a monoethylenic unsaturated monomer(s) containing an acid group (M2a) and/or up to 10 weight. % thereof different hydrophilic monomer (M2b). (B) comprises: (a) the salt of a sulfuric acid half ester of an alkoxylated alcohol, containing a 4 - 20 C alkyl chain(s) (salt a); and (b) an alkoxylated alcohol containing a 4 - 20 C alkyl chain(s) (compound b). An independent claim is also included for the preparation of a mineral coated concrete roofing slabs, comprising: (i) conventional manufacture of the uncoated roofing slabs blank; (ii) application to the damp blank of a cement bonded mineral mixture comprising the novel aqueous polymer dispersion, inorganic pigment dye, conventional additives, cement and water; and (iii) removal of the roofing product.
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公开(公告)号:DE59912421D1
公开(公告)日:2005-09-22
申请号:DE59912421
申请日:1999-07-27
Applicant: BASF AG
Inventor: SCHWARTZ MANFRED , BECHERT BERTOLD , WIESE HARM , HUEMMER WOLFGANG
IPC: C04B41/48 , C04B41/63 , C08F2/26 , C09D5/00 , C09D7/12 , C09D157/00 , C09K23/00 , C09K23/04 , B01F17/00
Abstract: A method of coating a mineral molding includes applying at least one aqueous preparation to at least one surface of the molding, the aqueous preparation including:(i) as film-forming constituent at least one polymer P which is composed of ethylenically unsaturated monomers M and which is present in dispersed form in the aqueous phase of the aqueous preparation and which has a glass transition temperature TG in the range from -25 to +80° C.;(ii) at least one anionic emulsifier selected from the group consisting of (a), (b), and (c):(a) salts of formula I: whereinAlk is linear or branched, saturated alkyl having from 10 to 18 carbon atoms,Et is 1,2-ethylene,n is an integer from 25 to 40, andM+ is a monovalent cation or a cation equivalent,(b) mixtures of salts of formula I; and(c) mixtures of salts of formula I with other anionic emulsifiers, wherein the salts of formula I make up at least 80% by weight of the anionic emulsifiers; and(iii) at least one nonionic emulsifier.
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公开(公告)号:NO319749B1
公开(公告)日:2005-09-12
申请号:NO985213
申请日:1998-11-09
Applicant: BASF AG
Inventor: SCHWARTZ MANFRED , BECHERT BERTOLD , ZHAO CHENG-LI , WIESE HARM , HUEMMER WOLFGANG
IPC: C04B41/48 , C04B41/63 , C08F20/12 , C09D133/06 , C09D201/02
Abstract: An aqueous composition (I) containing a copolymer (II), formed of ethylenically unsaturated monomers, as a film forming component, is used for coating mineral based molded articles. The copolymer (II) has a glass transition temperature of 25-80 degrees C and the monomer contains 0.2-5.0 wt.% itaconic acid. Independent claims are included for: (i) the production of coated, mineral molded articles by application of (I) onto at least one surface of the article and drying; and (ii) the resulting coated, molded article.
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公开(公告)号:DK0821660T3
公开(公告)日:2004-12-27
申请号:DK96910954
申请日:1996-04-04
Applicant: BASF AG
Inventor: RECK BERND , FRANZMANN GERNOT , BECHERT BERTOLD , BAECHER REINHARD , REHMER GERD
IPC: C04B41/48 , C04B41/63 , C08F20/38 , C08F20/58 , C08F220/06 , C08F220/38 , C08F220/54 , C08F246/00 , C08F265/04 , C08F265/10 , C08L33/14 , C08L33/26 , C08L51/00 , C09D133/06 , C09D133/14 , C09D133/26 , C09D151/00
Abstract: In a process for preserving a mineral molding by coating the surface of the mineral molding with an aqueous composition comprising an aqueous polymer dispersion, the dispersed polymer P comprises an ethylenically unsaturated acid of the 2-acrylamido-2-methylpropanesulfonic acid type polymerized into it in free-radically polymerized form.
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公开(公告)号:NO20030986D0
公开(公告)日:2003-03-03
申请号:NO20030986
申请日:2003-03-03
Applicant: BASF AG
Inventor: SANDOR MARIO , SCHWARTZ MANFRED , BECHERT BERTOLD , WIESE HARM
Abstract: Moldings comprise a base element consisting of a cement-bound mineral material, which may be modified with polymers, and a mineral coating present on at least one of the main surfaces of the base element and comprising a polymer-modified mineral material which contains at least one clay mineral as the main component and at least one film-forming, hydrophobic polymer distributed in the mineral material.
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公开(公告)号:NO20010041L
公开(公告)日:2001-07-09
申请号:NO20010041
申请日:2001-01-04
Applicant: BASF AG
Inventor: SCHWARTZ MANFRED , BECHERT BERTOLD , DENU HANS-JUERGEN , WISTUBA ECKEHARDT
Abstract: The use of an aqueous polymer dispersion for modifying cement bonded mineral coatings for concrete mold bodies. The polymer comprises: (A) a polymer P in the form of ethylenic unsaturated polymer particles with a glass transition temperature of -20 - + 80 C; and (B) an emulsifier for stabilizing the polymer particles. (A) comprises: (i) 90 - 99.9 wt. % hydrophobic, monoethylenic unsaturated monomer(s) (M1) from styrene, butadiene, 1 - 4 C alkylester of methacrylic acid and 2 - 12 C alkylester of acrylic acid; and (ii) 0.1 - 10 wt. % hydrophilic, monoethylenic unsaturated monomer (M2) comprising up to 2 wt. %, based on the total amount of monomer of a monoethylenic unsaturated monomer(s) containing an acid group (M2a) and/or up to 10 weight. % thereof different hydrophilic monomer (M2b). (B) comprises: (a) the salt of a sulfuric acid half ester of an alkoxylated alcohol, containing a 4 - 20 C alkyl chain(s) (salt a); and (b) an alkoxylated alcohol containing a 4 - 20 C alkyl chain(s) (compound b). An independent claim is also included for the preparation of a mineral coated concrete roofing slabs, comprising: (i) conventional manufacture of the uncoated roofing slabs blank; (ii) application to the damp blank of a cement bonded mineral mixture comprising the novel aqueous polymer dispersion, inorganic pigment dye, conventional additives, cement and water; and (iii) removal of the roofing product.
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公开(公告)号:NO20010041A
公开(公告)日:2001-07-09
申请号:NO20010041
申请日:2001-01-04
Applicant: BASF AG
Inventor: SCHWARTZ MANFRED , BECHERT BERTOLD , DENU HANS-JUERGEN , WISTUBA ECKEHARDT
CPC classification number: C04B41/5076 , C04B24/26 , C04B24/2688 , C04B40/0039 , C04B2111/00594 , E04D1/04 , E04D13/002 , C04B28/02 , C04B2103/40 , C04B41/4578 , C04B2103/54
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公开(公告)号:DE19951068A1
公开(公告)日:2001-04-26
申请号:DE19951068
申请日:1999-10-22
Applicant: BASF AG
Inventor: SCHWARTZ MANFRED , BECHERT BERTOLD
IPC: C09D201/10 , C09D125/06 , C08K5/54 , C09D133/04
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公开(公告)号:NO20004494A
公开(公告)日:2000-10-30
申请号:NO20004494
申请日:2000-09-08
Applicant: BASF AG
Inventor: SCHWARTZ MANFRED , BECHERT BERTOLD , WIESE HARM , HUEMMER WOLFGANG , RECK BERND
CPC classification number: C04B41/483 , C08F20/18
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公开(公告)号:NO20004494D0
公开(公告)日:2000-09-08
申请号:NO20004494
申请日:2000-09-08
Applicant: BASF AG
Inventor: SCHWARTZ MANFRED , BECHERT BERTOLD , WIESE HARM , HUEMMER WOLFGANG , RECK BERND
Abstract: The present invention provides for the use of aqueous film-forming formulations comprising at least one copolymer P as film-forming constituent which is present in disperse form in the formulation and is composed of ethylenically unsaturated monomers M, the monomers M comprisingi. from 70 to 99.9% by weight of at least one ester of methacrylic acid with a C1-C10-alkanol andii. from 0.1 to 30% by weight of at least one different monoethylenically unsaturated monomerand at least 50% by weight of the monomers M being other than methyl methacrylate and not more than 1% by weight of the monomers M having two or more ethylenically unsaturated double bonds, for coating mineral moldings.The present invention additionally provides a method of coating the mineral moldings, and also the mineral moldings themselves.
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