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公开(公告)号:DE10038037A1
公开(公告)日:2002-04-18
申请号:DE10038037
申请日:2000-08-02
Applicant: BASF AG
Inventor: BARTSCH MICHAEL , KUNSMANN-KEITEL DAGMAR PASCAL , BAUMANN ROBERT , HADERLEIN GERD , SIEGEL WOLFGANG
IPC: B01J31/18 , B01J31/28 , C07F9/145 , C07F9/46 , C07F9/48 , C07F9/6574 , C07F15/04 , B01J31/22 , C07C5/25 , C07C253/10
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公开(公告)号:BRPI0507197B1
公开(公告)日:2014-12-30
申请号:BRPI0507197
申请日:2005-01-27
Applicant: BASF AG
Inventor: JUNGKAMP TIM , SCHEIDEL JENS , SIEGEL WOLFGANG , BAUMANN ROBERT , BARTSCH MICHAEL , HADERLEIN GERD , LUYKEN HERMANN , AECHTNER TOBIAS , PFAB PETER , DECKERT PETRA , BASSLER PETER
IPC: C07C253/10 , C07C255/07
Abstract: A process is described for preparing 3-pentenenitrile, characterized by the following process steps: (a) isomerizing a reactant stream which comprises 2-methyl-3-butenenitrile over at least one dissolved or dispersed isomerization catalyst to give a stream 1 which comprises the at least one isomerization catalyst, 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile, (b) distilling stream 1 to obtain a stream 2 as the top product which comprises 2-methyl-3-butenenitrile, 3-pentenenitrile and (Z)-2-methyl-2-butenenitrile, and a stream 3 as the bottom product which comprises the at least one isomerization catalyst, (c) distilling stream 2 to obtain a stream 4 as the top product which, compared to stream 2, is enriched in (Z)-2-methyl-2-butenenitrile, based on the sum of all pentenenitriles in stream 2, and a stream 5 as the bottom product which, compared to stream 2, is enriched in 3-pentenenitrile and 2-methyl-3-butenenitrile, based on the sum of all pentenenitriles in stream 2, (d) distilling stream 5 to obtain a stream 6 as the bottom product which comprises 3-pentenenitrile and a stream 7 as the top product which comprises 2-methyl-3-butenenitrile.
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公开(公告)号:BRPI0516617A
公开(公告)日:2008-09-16
申请号:BRPI0516617
申请日:2005-10-12
Applicant: BASF AG
Inventor: DECKERT PETRA , BASSLER PETER , HADERLEIN GERD , LUYKEN HERMANN , SCHEIDEL JENS , PFAB PETER , AECHTNER TOBIAS , SIEGEL WOLFGANG
Abstract: A process for extractively removing homogeneously dissolved catalysts from a reaction effluent of a hydrocyanation of unsaturated mononitriles to dinitriles with a hydrocarbon H, including performing the steps of a) concentrating the reaction effluent before step b) by distillation at pressures of from 0.1 to 5000 mbar and temperatures of from 10 to 150° C., b) adding a hydrocarbon H to the concentrated reaction effluent to obtain a stream I, and c) feeding stream I, without prior separation of the liquid phases, into an extraction apparatus and extracting it at a temperature T with the hydrocarbon H to obtain a stream II comprising the hydrocarbon H enriched with the catalyst and a stream III having a low catalyst content.
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64.
公开(公告)号:ES2289689T3
公开(公告)日:2008-02-01
申请号:ES05701205
申请日:2005-01-27
Applicant: BASF AG
Inventor: SCHEIDEL JENS , JUNGKAMP TIM , BARTSCH MICHAEL , HADERLEIN GERD , BAUMANN ROBERT , LUYKEN HERMANN
IPC: C07F9/00 , C07C253/34 , C07C255/04 , C07F9/02
Abstract: Procedimiento para la separación por extracción de complejos de níquel (0) con ligandos fosforados y/o ligandos fosforados libres a partir de una descarga de reacción de un hidrocianado de mononitrilos insaturados para dar dinitrilos, mediante extracción por medio de un hidrocarburo efectuándose una separación de fases de hidrocarburo y descarga de reacción en dos fases a una temperatura T (en ºC), caracterizado porque, en la descarga de reacción de hidrocianado, el contenido en complejos de níquel (0) con ligandos fosforados y/o ligandos fosforados libres, dependiendo de la temperatura T, asciende al menos a y % en peso, e independientemente de la temperatura T asciende a un máximo de un 60 % en peso, determinándose el valor numérico del contenido mínimo y mediante la ecuación Y = 0, 5 . T + 20 y debiéndose emplear T en la ecuación como valor numérico adimensional.
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公开(公告)号:PL1713816T3
公开(公告)日:2007-12-31
申请号:PL05701205
申请日:2005-01-27
Applicant: BASF AG
Inventor: SCHEIDEL JENS , JUNGKAMP TIM , BARTSCH MICHAEL , HADERLEIN GERD , BAUMANN ROBERT , LUYKEN HERMANN , DECKERT PETRA , PFAB PETER , SIEGEL WOLFGANG , AECHTNER TOBIAS
IPC: C07F9/00 , C07C253/34 , C07C255/04 , C07F9/02
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公开(公告)号:BRPI0507194A
公开(公告)日:2007-06-26
申请号:BRPI0507194
申请日:2005-01-26
Applicant: BASF AG
Inventor: JUNGKAMP TIM , POLKA HANS-MARTIN , BAUMANN ROBERT , BARTSCH MICHAEL , HADERLEIN GERD , LUYKEN HERMANN , SCHEIDEL JENS
IPC: C07C253/34 , C07C255/04 , C07C255/07
Abstract: A process is described for removing hydrogen cyanide from mixtures comprising pentenenitrile, wherein the removal is effected by an azeotropic distillation of hydrogen cyanide with 1,3-butadiene.
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公开(公告)号:DE50210044D1
公开(公告)日:2007-06-06
申请号:DE50210044
申请日:2002-10-01
Applicant: BASF AG
Inventor: BARTSCH MICHAEL , BAUMANN ROBERT , KUNSMANN-KEITEL DAGMAR PASCALE , HADERLEIN GERD , JUNGKAMP TIM , ALTMAYER MARCO , SIEGEL WOLFGANG , MOLNAR FERENC
IPC: B01J31/18 , B01J31/22 , C07B61/00 , C07C253/10 , C07C253/30 , C07C255/04 , C07C255/07 , C07F9/48
Abstract: Phosphonites I of the formula 1 or 2 where R1, R2 are each, independently of one another, hydrogen, an alkyl or alkylene group having from 1 to 8 carbon atoms or an alkoxy group having from 1 to 8 carbon atoms, with the proviso that R1 and R2 are not simultaneously H, R3 is H or methyl, R4 is t-butyl, R5, R6, R7, R8, R9 are each, independently of one another, H or an alkyl or alkylene group having from 1 to 8 carbon atoms.
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公开(公告)号:AT359254T
公开(公告)日:2007-05-15
申请号:AT04739502
申请日:2004-06-02
Applicant: BASF AG
Inventor: FLORES MIGUEL ANGEL , BARTSCH MICHAEL , BAUMANN ROBERT , HADERLEIN GERD , JUNGKAMP TIM , SCHEIDEL JENS , LUYKEN HERMANN , SIEGEL WOLFGANG , MEYER CHRISTA , WIDMAIER RALF
Abstract: The invention is a process for preparing tetraalkyl-substituted biphenol which comprises reacting a 2,4- or 2,6-dialkyl substituted phenol in which the alkyl groups contain 1 to 6 carbon atoms with a peroxidase enzyme in the presence of a peroxide in an aqueous medium to yield a tetraalkyl-substituted biphenol by oxidative coupling of the 2,4- or 2,6-dialkyl substituted phenol, or yielding a tetra-alkyl substituted quinone, and reducing the quinone to obtain a tetraalkyl-substituted biphenol. The invention further includes a process for preparing a tetraaryl-substituted biphenol in which the aryl groups contain 6 to 10 carbon atoms which comprises racting a 2,4 or 2,6 diarylphenol with a peroxidase enzyme to yield a tetraaryl-substituted biphenol. A process for reducing a tetraalkyl-substituted quinone to corresponding tetraalkyl-substituted biphenol which comprises reducing the quinone with a phenol in an aqueous medium at a temperature of about 60° to 120° C. is also included.
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公开(公告)号:BRPI0506574A
公开(公告)日:2007-04-10
申请号:BRPI0506574
申请日:2005-01-26
Applicant: BASF AG
Inventor: JUNGKAMP TIM , BAUMANN ROBERT , SCHROEDER THORSTEN , BARTSCH MICHAEL , HADERLEIN GERD , LUYKEN HERMANN , SCHEIDEL JENS
IPC: C07C253/10 , C07C255/07
Abstract: A process is described for preparing 3-pentenenitrile by hydrocyanating 1,3-butadiene in the presence of at least one catalyst, wherein unhydrocyanated 1,3-butadiene is removed from the effluent of the hydrocyanation and recycled into the process, and the recycled 1,3-butadiene is monitored for the content of hydrogen cyanide.
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公开(公告)号:AT355902T
公开(公告)日:2007-03-15
申请号:AT04722843
申请日:2004-03-24
Applicant: BASF AG
Inventor: BARTSCH MICHAEL , BAUMANN ROBERT , HADERLEIN GERD , FLORES MIGUEL ANGEL , JUNGKAMP TIM , LUYKEN HERMANN , SCHEIDEL JENS , SIEGEL WOLFGANG , MOLNAR FERENC
IPC: B01J23/755 , B01J31/02 , B01J31/14 , B01J31/18 , C07C253/10 , C07C255/04 , B01J27/14
Abstract: A system which is suitable as a catalyst for the hydrocyanation of olefinically unsaturated compounds and comprises a) Ni(0) b) a compound which complexes Ni(0) as a ligand and contains trivalent phosphorus, c) a Lewis acid and d) a compound of the formula M Rn where M: Al or Ti R: identical or different monovalent alkoxy radicals, in which case a plurality of alkoxy radicals may be bonded together, and additionally, in the case that M=Al, R may be identical or different monovalent alkyl radicals, in which case a plurality of alkyl radicals may be bonded together or one or more alkyl radicals may be bonded to one or more of the abovementioned alkoxy radicals, n: valency of M, and processes for hydrocyanating an olefinically unsaturated compound in the presence of such a system.
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