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    66.
    发明专利
    未知

    公开(公告)号：DE59309262D1

    公开(公告)日：1999-02-11

    申请号：DE59309262

    申请日：1993-10-19

    Applicant: BASF AG

    Inventor： KLINTZ RALF ,  HAMPRECHT GERHARD ,  HEISTRACHER ELISABETH ,  SCHAEFER PETER ,  KARDORFF UWE ,  WESTPHALEN KARL-OTTO ,  GERBER MATTHIAS ,  WALTER HELMUT

    IPC: A01N37/46 ,  A01N43/40 ,  C07C233/07 ,  C07C233/34 ,  C07C233/54 ,  C07C323/60 ,  C07C327/38 ,  C07D211/84 ,  C07D211/86 ,  C07D211/88 ,  C07D211/90 ,  C07D211/96

    Abstract: PCT No. PCT/EP93/02879 Sec. 371 Date Apr. 26, 1995 Sec. 102(e) Date Apr. 26, 1995 PCT Filed Oct. 19, 1993 PCT Pub. No. WO94/10147 PCT Pub. Date May 11, 1994Substituted N-phenylglutarimides I I X1, X2=O, S; R1=halogen, NO2, CN, CF3; R2=H, halogen; R3, R4, R5=H, halogen, CN, alkyl, cyctoalkyl, alkenyl, alkynyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkyl-thio, cyanoalkyl, alkoxycarbonyl, unsubstituted or substituted phenyl or benzyl, or 2 substituents of a C atom or 2 substituents of adjacent C atoms of the glutarimide ring are bonded to one another via a chain which may be substituted; A=CHR6-CHR7-CO-B or CR6=CR8-CO-B; R6=H, C1-C6-alkyl or C1-C6-haloalkyl; R7=halogen, haloalkyl, OH, alkoxy or alkylcarbonyloxy; R8=H, CN, alkyl, alkylcarbonyl, alkoxycarbonyl or B=H, alkyl, alkenyl, alkynyl, haloalkyl, cycloalkyl, alkoxy-alkyl, dialkoxyalkyl, alkylthioalkyl, alkoxy, alkylthio or amino, the last three radicals may be substituted, unsubstituted or functionalized; and plant-tolerable salts of I; their preparation and use as herbicides and desiccating/defoliating agents, and precursors for the preparation of the N-phenylglutarimides I.

    BENCILHIDROXILAMINAS Y PRODUCTOS INTERMEDIOS PARA SU PREPARACION.
    69.
    发明专利
    BENCILHIDROXILAMINAS Y PRODUCTOS INTERMEDIOS PARA SU PREPARACION. 未知

    公开(公告)号：MX9800081A

    公开(公告)日：1998-11-29

    申请号：MX9800081

    申请日：1998-01-07

    Applicant: BASF AG

    Inventor： KLINTZ RALF ,  HAMPRECHT GERHARD ,  HEISTRACHER ELISABETH ,  SCHAEFER PETER ,  ZAGAR CYRILL ,  WESTPHALEN KARL-OTTO ,  WALTER HELMUT ,  MISSLITZ ULF ,  MENKE OLAF

    IPC: A01N43/54 ,  A01N47/12 ,  A01N47/24 ,  A01N47/30 ,  A01N53/00 ,  C07C239/08 ,  C07C239/10 ,  C07C239/16 ,  C07C239/20 ,  C07C265/12 ,  C07C271/22 ,  C07C271/28 ,  C07C271/54 ,  C07C271/58 ,  C07C275/32 ,  C07C275/40 ,  C07D239/54 ,  C07D405/12

    Abstract: Bencilhidroxilamina I: ver formula (I): (x = -N(R7)-O-; Y = O, S; R1 = halogeno, CN, NO2, CF3; R2 = H, halogeno ; R3 = H, NH2, CH3; R4 ¿ H, halogeno, alquilo C1-C6, haloalquilo C1-C6, alquiltio C1-C6, alquilsulfinilo C1-C6 o bien alquilsulfonilo C1-C6; R5 = H, halogeno, alquilo C1-C6; R6 = H, alquilo C1-C6, haloalquilo C1-C6, cicloalquilo C3-C6, alquenilo C2-C6; R7 = H, alquilo C1-C6, cicloalquilo C3-C8, haloalquilo C1-C6, alquenilo C3-C6, alquinilo C3-C6, alquilcarbonilo C1-C6, alquenilcarbonilo C3-C6, alquinilcarbonilo C3-C6, alcoxicarbonilo C1-C6, alqueniloxicarbonilo C2-C8, alquiniloxicarbonilo C2-C6, alquiltiocarbonilo C1-C6, alquilsulfonilo C1-C6, alquilcarbamoilo C1-C6, siendo posible que los 14 radicales mencionados en ultima instancia tengan fijados sobre ellos 1-3 sustituyentes: -NO2, CN, halogeno, cicloalquilo C3-C8, OH, alcoxi C1-C6, cicloalcoxi C3-C8, alqueniloxi C3-C6, alquiniloxi C3-C6, alcoxi C1-C6-alcoxi C1-C6, alquiltio C1-C6, alquilcarbonilo C1-C6, alquilcarboniloxi C1-C6, alquilsulfinilo C1-C6, alquilsulfonilo C1-C6, alquilidenaminoxi C1-C6, alquilacarbamoilo C1-C6, -fenilo, fenoxi, o bien fenilsulfonilo no sustituido o bien sustituido, -un grupo de heterociclilo o heterocicliloxi de 3 a 7 miembros que tiene 1-3 heteroátomos, siendo posible que este grupo esté saturado, insaturado o bien aromático y tenga fijado sobreél 1-3 sustituyentes; --CO-Z1R9, -OCO-Z1R9, -N(R9)R10 o bien R7 = cicloalquilcarbonilo, fenilcarbonilo, fenilsulfonilo, fenilcarbamoilo sustituido o no sustituido; R8 = H, alquilo C1-C6, cicloalquilo C3-C8, haloalquilo C1-C6, alquenilo C3-C6 o bien alquinilo, C3-C6, siendo posible que cada uno de los 5 radicales mencionados en ultima instancia tengan fijados sobre ellos 1-3 sustituyentes: -NO2, CN, halogeno, cicloalquilo C3-C8, OH, alcoxi C1-C6, cicloalcoxi C3-C8, alqueniloxi C3-C6, alquiniloxi C3-C6, alcoxi C1-C6-alcoxi C1-C6, alquiltio C1-C6, alquilsulfinilo C1-C6, alquilsulfonilo C1-C6, alquilidenaminoxi C1-C6, - fenil- (sic), fenoxi- (sic) o bien fenilsulfonilo sustituido o no sustituido, - un grupo de heterociclilo o heterocicliloxi de 3 a 7 miembros que tiene 1-3 heteroátomos, siendo posible que este grupo este saturado, insaturado o bien aromático y tenga fijado sobre el 1-3 sustituyentes. - -CO-Z2R11, -OCO-Z2R11, -N(R11)R12; irais Z1 es un enlace químico, oxígeno, azufre o bien -N(R10)-; Z2 es un enlace químico, oxígeno, azufre o bien -N(R12)-; R9, R11, alquilo C1-C6, haloalquilo C1-C6, cicloalquilo C3-C8, alquenilo C3-C6, alquinilo C3-C6, alcoxi C1-C6-alquilo C1-C6, (alcoxi C1-C6)carbonilalquilo C1-C6, fenilo o bien fenilalquilo C1-C6, sustituido o no sustituido o bien Z1 y R9 y/o R11 juntos = un heterociclo de 3 a 7 miembros que tiene de 1 a 3 heteroátomos y unido a través de nitrogeno, siendo posible que el heterociclo esté saturado, parcial o totalmente insaturado o bien aromático y, si se desea, tenga fijado sobre él de 1 a 3 sustituyentes, R10, R12 = H, OH, alquilo C1-C6, cicloalquilo C3-C8, alcoxi C1-C6 y las sales de I donde R3, R7 y/o R8 = hidrogeno se emplean como herbicidas y para la desecacion/defoliacion de plantas.

    1-AMINO-3-BENZYLURACILS
    70.
    发明专利
    1-AMINO-3-BENZYLURACILS 未知

    公开(公告)号：BG102184A

    公开(公告)日：1998-08-31

    申请号：BG10218498

    申请日：1998-01-14

    Applicant: BASF AG

    Inventor： MENKE OLAF ,  KLINTZ RALF ,  HAMPRECHT GERHARD ,  HEISTRACHER ELISABETH ,  SCHAEFER PETER ,  ZAGAR CYRILL ,  GOETZ NORBERT ,  WESTPHALEN KARL-OTTO ,  MISSLITZ ULF ,  WALTER HELMUT

    IPC: A01N43/54 ,  C07C275/24 ,  C07C281/02 ,  C07C281/06 ,  C07D239/54 ,  C07D413/12 ,  C07D419/12

    Abstract: The invention relates to 1-amino-3-benzyluracils and to theirsalts finding application as herbicides, for desiccation anddefoliation of plants. The compounds have the formulawhere R1 is halogen, R2 & R3 are H, CN, SCH, halogen, C1-C4halogenalkyl, C1-C4 halogenalkoxy or C1-C4 halogenalkylthio, R4matches R3 and can include C1-C4 alkyl, C1-C4 alkyl, C1-C4 alkoxy,C1-C4-alkyl-NHCO-, R5 is H, CN, NO2, OH, halogen, optionallysubstituted NH2, optionally substituted C1-C6 halogenalkoxy, C1-C6halogenalkylthio, C1-C4 alkoxy, C1-C6 alkylthio, C3-C8cycloalkoxy, C3-C8 cycloalkylthio, C3-C6 alkenyloxy, C3-C6alkyenylthio, C3-C6 alkynyloxy, C3-C6 alkynylthio,C1-C6-alkyl-COO, C1-C6-alkyl-COS-, C3-C6-alkenyl-COO,C3-C6-alkenyl-COS, C3-C6-alkynyl-COO-, C3-C6-alkynyl COS-, C1-C6alkyl-SO2-0- or C1-C6-alkyl-SO2, R6 is H, OH, SH, halogen, C1-C6halogenalkoxy, C1-C6 halogen alkylthio,C1-C6-alkylthio-(C1-C6-alkyl)carbonyl, (C1-C6)iminooxy-CO-;optionally substituted C1-C6 alkoxy, C1-C6 alkylthio, C3-C8cyloalkoxy, C3-C8 cycloalkylthio, C2-C6 alkenyloxy, C2-C6alkenylthio, C2-C6 alkynyloxy, C2-C6 alkynyilthio,C1-C6-alkyl-COO-, C2-C6-alkyl-COS-, C1-C6-alkoxy-COO-,C2-C6-alkyenyl-COO-, C2-C6-alkyenyl-COS-, C2-C6 alkynyl-COO-,C2-C6-alkynyl-COS-, 1-C6-SO2-0-, or C1-C6-alkyl-SO2; -CY-R11 {Y =-O-, -S-, optionally substituted -NH-}, -C-(R11)(Z1R12)(Z2R13)[{Z1and Z2 = -O-, -S-}, -C(R11 = C(R14)-CN, -C(R11) = C(R14)-CO-R15,-CH(R11)-CH(R12)-CO-R15, -C(R11) = C(R14)-CH2-CO-R15,-C(R11)=C(R14)-C(R16)=C(R17)-CO-R15-C(R11)=C(R14)-CH2-CH(R18)-CO-R15, -CO-OR19, -CO-SR19,-CO-N(R19)-OR20, -C=C-CO-NH-OR20,-C=C-CO-N(R19)-OR20,-C=C-CS-NH-OR20, -C=C-CS-N(R19)-OR20, -C(R11)=C(R14)-CO-NH-OR20,-C(R11)=C(R14)-CO-N(R19)-OR20, -C(R11)=C(R14)-CS-NH-OR20,-C(R11)=C(R14)-CS-N(R19)-OR20, -C(R11)=C(R14)-C(R21)=N-OR20,-C(R21)-N-OR20, -C=C-C(R21)=N-OR20, -C(Z1R12)(Z2R13)-OR19,-C(Z1R12) (Z2R13), -C(Z1R12)(Z2R13)-N(R23)R24, optionallysubstituted amino or -CONH2, azaheterocyclyl, -CO-azaheterocyclyl,or a chain containing (N + O or N + O + S) heterocyclyl.14 claims

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