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    New 4-azo- and 4-hydrazino-pyrimidine compounds
    65.
    发明专利
    New 4-azo- and 4-hydrazino-pyrimidine compounds 未知

    公开(公告)号：DE19650378A1

    公开(公告)日：1998-06-10

    申请号：DE19650378

    申请日：1996-12-05

    Applicant: BASF AG

    Inventor： WAGNER OLIVER DR ,  ROEHL FRANZ DR ,  LORENZ GISELA DR ,  AMMERMANN EBERHARD DR ,  STRATHMANN SIEGFRIED DR

    IPC: A01N43/54 ,  C07D239/42

    Abstract: Pyrimidyl compounds of formula (I) are new. R = N(R4)NR5R6, N=NR6 or N(R6)NHR4; R1 = H, halo, alkyl or 3-8C cycloalkyl; R2, R3 = halo, CN, 1-8C alkyl, haloalkyl, 1-8C alkoxy, alkylthio, alkylthioalkyl, haloalkoxy, alkoxyalkyl, alkoxycarbonyl, alkoxycarbonylalkyl, 3-8C cycloalkyl or 3-8C halocycloalkyl; or CR2R3 = Z; Z = 4-8 membered ring which may contain one or two O, S, NH or N-alkyl (optionally with C atoms mono- or di-substituted by halo, CN, alkyl, alkoxyalkyl, haloalkyl, alkoxy, 1-4C haloalkoxy, alkylthio, alkoxycarbonyl, aryl or aryloxy); R4 = H, alkyl, formyl, alkylcarbonyl or alkoxycarbonyl; R5 = H, formyl, 1-8C alkyl, 2-8C alkenyl, 2-8C alkynyl, 1-8C alkylcarbonyl, 3-7C cycloalkyl or 5-7C cycloalkenyl (all partially or fully halogenated), aryl or heteroaryl (both optionally substituted by 1-3 NO2, halo, CN, alkyl, haloalkyl, alkoxy, haloalkoxy, 1-4C alkoxyalkyl, alkylthio, alkylamino, dialkylamino, alkylsulphonyl, alkylsulphonyloxy, alkylsulphoxy, alkylcarbonyl, alkylcarbonyloxy, alkoxycarbonyl, aryl or aryloxy; R6 = 1-8C alkyl, 2-8C alkenyl or 2-8C alkynyl (all partially or fully halogenated and/or substituted by 1-3 CN, alkoxy, haloalkoxy, alkylthio or Cyc), or 3-7C cycloalkyl or cycloalkenyl, (both partially or fully halogenated and optionally substituted by 1-3 CN, alkoxy, haloalkoxy, alkylthio, Cyc), Z, or aryl or heteroaryl, (both optionally substituted by 1-3 halo, CN, alkyl (optionally substituted by Ar'), 1-4C alkoxyalkyl, haloalkyl, alkoxy (optionally substituted by Ar'), haloalkoxy, alkylthio, Ar', OAr', 3-7C cycloalkyl optionally substituted by 1-3 Rc), alkylamino, dialkylamino, alkylsulphonyl, alkylsulphonyloxy, haloalkylsulphonyl, alkylsulphoxy, alkylcarbonyl, alkylcarbonyloxy, alkoxycarbonyl or cyanoalkyl); Ar' = aryl or heteroaryl (both optionally substituted by 1-3 Rc); Cyc = 3-7C cycloalkyl, 5-7C cycloalkenyl, aryl, aryloxy or heteroaryl (all optionally substituted by 1-3 Rc); Rc = halo, CN, alkyl, 1-4C alkoxyalkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, aryl, aryloxy or heteroaryl; alkyl, alkoxy have 1-4C unless specified otherwise. The use of a compound (Ic) is also claimed.

    New imino:oxy:phenyl:acetic acid derivatives
    69.
    发明专利
    New imino:oxy:phenyl:acetic acid derivatives 未知

    公开(公告)号：DE19604732A1

    公开(公告)日：1997-08-14

    申请号：DE19604732

    申请日：1996-02-09

    Applicant: BASF AG

    Inventor： GROTE THOMAS DR ,  SAUTER HUBERT DR ,  KIRSTGEN REINHARD DR ,  BAYER HERBERT DR ,  MUELLER RUTH DR ,  MUELLER BERND DR ,  OBERDORF KLAUS DR ,  GRAMMENOS WASSILIOS DR ,  GOETZ NORBERT DR ,  RACK MICHAEL DR ,  HARREUS ALBRECHT DR ,  ROEHL FRANZ DR ,  AMMERMANN EBERHARD DR ,  HARRIES VOLKER DR ,  LORENZ GISELA DR ,  STRATHMANN SIEGFRIED DR

    IPC: C07C251/60 ,  A01N37/34 ,  A01N37/50 ,  A01N43/00 ,  C07C69/757 ,  C07C255/62 ,  C07C255/64 ,  C07C323/24

    Abstract: 2-Iminooxyphenylacetic acid derivatives of formula (I) and their salts are new. R = C(CO2Me)=NOMe, C(CONHMe)=NOMe, C(CONH2)=NOMe, C(CO2Me)=COMe or C(CO2Me)=CHMe; R2 = CN, NO2, halo, 1-4C alkyl, 1-4C haloalkyl or 1-4C alkoxy; m = 0-2; R3 = H, CN, OH, halo, 1-6C alkyl (optionally substituted by halo or 1-6C alkoxy) 1-6C alkoxy, 1-6C haloalkoxy, 1-6C alkylthio, cyclopropyl, 2-6C alkenyl, or aryloxy-1-6C alkyl, benzyl or benzyloxy (all optionally ring-substituted by 1-3 CN, NO2, halo, 1-6C alkyl, 1-6C alkoxy, 1-6C haloalkyl or 1-6C haloalkoxy) or C(Me)=N-Y-Ra; Ra = 1-6C alkyl; Y = O, NH or NRa; R4 = H, CN, -Qp-C(R5)=N-Y'-R6 or -Q-O-N=CR7R8; or alkyl, alkenyl, alkynyl, cycloalkyl, heterocyclyl, aryl, heteroaryl, alkoxy, alkenyloxy, alkynyloxy, cycloalkoxy, heterocyclyloxy, aryloxy, heteroaryloxy, arylthio or heteroarylthio (all optionally substituted); or CR3R4 = 4-8 membered ring containing C atoms an optionally 1 or 2 of O, S, NH and/or N(1-4C alkyl) (optionally substituted on C by halo, 1-6C alkyl or 1-4C alkoxyimino), provided R3 and R4 are not both bonded to C via hetero atoms; Q = bond, CH2, CH(Me), CH(Et) or 1,1-cyclopropyl; p = 0 or 1; Y' = O, NH or N(1-4C alkyl); R5 = as for R3 or optionally substituted cycloalkoxy, heterocyclyloxy, aryloxy, heteroaryloxy, arylthio or heteroarylthio; R6 = optionally substituted 1-10C alkyl, 3-6C cycloalkyl, 2-10C alkenyl, 2-10C alkynyl, 1-10C alkylcarbonyl, 2-10C alkenylcarbonyl, 2-10C alkynylcarbonyl, 1-10C alkylsulphonyl, aryl, heteroaryl, arylcarbonyl, heteroarylcarbonyl, arylsulphonyl or heteroarylsulphonyl; R7, R8 = Me, Et, Ar or CH2Ar; Ar = phenyl (optionally mono-, di- or trisubstituted by CN, NO2, halo, 1-6C alkyl, 1-6C alkoxy, 1-6C haloalkyl or 1-6C haloalkoxy.

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