公开(公告)号：DE19620392A1

公开(公告)日：1997-11-27

申请号：DE19620392

申请日：1996-05-21

Applicant: BASF AG

Inventor： OBERDORF KLAUS DR ,  GRAMMENOS WASSILIOS DR ,  SAUTER HUBERT DR ,  GROTE THOMAS DR ,  KIRSTGEN REINHARD DR ,  MUELLER RUTH DR ,  MUELLER BERND DR ,  ROEHL FRANZ DR ,  RACK MICHAEL DR ,  BAYER HERBERT DR ,  LORENZ GISELA DR ,  AMMERMANN EBERHARD DR ,  STRATHMANN SIEGFRIED DR ,  HARRIES VOLKER DR

IPC: C07D239/34 ,  A01N37/18 ,  A01N43/54

Abstract: 2-(pyrimidin-4-yloxy)methyl)phenylacetic acid derivatives of formula (I) and their salts and N-oxides are new. R1 = H or 1-4C alkyl; R2 = halo, CH3, CH2CH3, halomethyl or haloethyl; R3 = phenyl, phenoxy, phenoxymethyl, benzyloxy or heteroaryl, (all optionally ring-substituted), H, amino, OH, SH, halo, 1-8C alkyl (optionally substituted by Ar or halo), alkoxy-(1-4C alkyl), alkoxy, mono- or di- alkylamino, alkylthio, alkylsulphoxy, alkylsulphonyl, 3-8C cycloalkyl, trialkylsilyloxy; Ar = phenyl (optionally mono- or di-substituted by halo, CN, NO2, 1-4C alkyl, 1-4C haloalkyl or 1-4C alkoxy); R4 = H, CN, halo, 1-4C alkyl, 1-4C haloalkyl or 1-4C alkoxy; Q = C(=NOCH3)CONHCH3, C(=NOCH3)COOCH3 or N(OCH3)COOCH3; alkyl, alkoxy have 1-8 C unless specified otherwise.

公开(公告)号：DE19604732A1

公开(公告)日：1997-08-14

申请号：DE19604732

申请日：1996-02-09

Applicant: BASF AG

Inventor： GROTE THOMAS DR ,  SAUTER HUBERT DR ,  KIRSTGEN REINHARD DR ,  BAYER HERBERT DR ,  MUELLER RUTH DR ,  MUELLER BERND DR ,  OBERDORF KLAUS DR ,  GRAMMENOS WASSILIOS DR ,  GOETZ NORBERT DR ,  RACK MICHAEL DR ,  HARREUS ALBRECHT DR ,  ROEHL FRANZ DR ,  AMMERMANN EBERHARD DR ,  HARRIES VOLKER DR ,  LORENZ GISELA DR ,  STRATHMANN SIEGFRIED DR

IPC: C07C251/60 ,  A01N37/34 ,  A01N37/50 ,  A01N43/00 ,  C07C69/757 ,  C07C255/62 ,  C07C255/64 ,  C07C323/24

Abstract: 2-Iminooxyphenylacetic acid derivatives of formula (I) and their salts are new. R = C(CO2Me)=NOMe, C(CONHMe)=NOMe, C(CONH2)=NOMe, C(CO2Me)=COMe or C(CO2Me)=CHMe; R2 = CN, NO2, halo, 1-4C alkyl, 1-4C haloalkyl or 1-4C alkoxy; m = 0-2; R3 = H, CN, OH, halo, 1-6C alkyl (optionally substituted by halo or 1-6C alkoxy) 1-6C alkoxy, 1-6C haloalkoxy, 1-6C alkylthio, cyclopropyl, 2-6C alkenyl, or aryloxy-1-6C alkyl, benzyl or benzyloxy (all optionally ring-substituted by 1-3 CN, NO2, halo, 1-6C alkyl, 1-6C alkoxy, 1-6C haloalkyl or 1-6C haloalkoxy) or C(Me)=N-Y-Ra; Ra = 1-6C alkyl; Y = O, NH or NRa; R4 = H, CN, -Qp-C(R5)=N-Y'-R6 or -Q-O-N=CR7R8; or alkyl, alkenyl, alkynyl, cycloalkyl, heterocyclyl, aryl, heteroaryl, alkoxy, alkenyloxy, alkynyloxy, cycloalkoxy, heterocyclyloxy, aryloxy, heteroaryloxy, arylthio or heteroarylthio (all optionally substituted); or CR3R4 = 4-8 membered ring containing C atoms an optionally 1 or 2 of O, S, NH and/or N(1-4C alkyl) (optionally substituted on C by halo, 1-6C alkyl or 1-4C alkoxyimino), provided R3 and R4 are not both bonded to C via hetero atoms; Q = bond, CH2, CH(Me), CH(Et) or 1,1-cyclopropyl; p = 0 or 1; Y' = O, NH or N(1-4C alkyl); R5 = as for R3 or optionally substituted cycloalkoxy, heterocyclyloxy, aryloxy, heteroaryloxy, arylthio or heteroarylthio; R6 = optionally substituted 1-10C alkyl, 3-6C cycloalkyl, 2-10C alkenyl, 2-10C alkynyl, 1-10C alkylcarbonyl, 2-10C alkenylcarbonyl, 2-10C alkynylcarbonyl, 1-10C alkylsulphonyl, aryl, heteroaryl, arylcarbonyl, heteroarylcarbonyl, arylsulphonyl or heteroarylsulphonyl; R7, R8 = Me, Et, Ar or CH2Ar; Ar = phenyl (optionally mono-, di- or trisubstituted by CN, NO2, halo, 1-6C alkyl, 1-6C alkoxy, 1-6C haloalkyl or 1-6C haloalkoxy.

公开(公告)号：DE19548783A1

公开(公告)日：1997-07-03

申请号：DE19548783

申请日：1995-12-27

Applicant: BASF AG

Inventor： BAYER HERBERT DR ,  MUELLER RUTH DR ,  SAUTER HUBERT DR ,  GRAMMENOS WASSILIO DR ,  GROTE THOMAS DR ,  KIRSTGEN REINHARD DR ,  MUELLER BERND DR ,  OBERDORF KLAUS DR ,  ROEHL FRANZ DR ,  AMMERMANN EBERHARD DR ,  HARRIES VOLKER DR ,  LORENZ GISELA DR ,  STRATHMANN SIEGFRIED DR

IPC: A01N37/34 ,  A01N47/40 ,  C07C255/61 ,  C07C261/04 ,  A01N37/42 ,  A01N37/50 ,  A01N43/08 ,  A01N43/26 ,  A01N43/28 ,  A01N43/36 ,  A01N43/38 ,  A01N43/40 ,  A01N43/54 ,  A01N43/653

Abstract: The invention relates to cyanimino oxime ethers of formula (I), in which X is NOCH3, CHOCH3, CHCH3; Y is O, NZ, where Z is H, alkyl; R is H, alkyl; R is cyano, nitro, trifluoromethyl, halogen, alkyl, alcoxy; m is 0, 1, 2, the radicals R possibly being different when m is 2; R is H, cyano, alkyl, alkylhalide, alkoxy or cycloalkyl; R is H, optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, heterocyclyl. The invention also relates to salts of said ethers, and the process and intermediates for the preparation and use thereof for the control of noxious fungi and animal pests.

公开(公告)号：DE19721847A1

公开(公告)日：1998-12-03

申请号：DE19721847

申请日：1997-05-26

Applicant: BASF AG

Inventor： GROTE THOMAS DR ,  SAUTER HUBERT DR ,  KIRSTGEN REINHARD DR ,  BAYER HERBERT DR ,  MUELLER RUTH DR ,  GOETZ ROLAND DR ,  GOETZ NORBERT DR ,  MUELLER BERND DR ,  GRAMMENOS WASSILIOS DR ,  PTOCK ARNE DR ,  GYPSER ANDREAS DR ,  RACK MICHAEL DR ,  ROEHL FRANZ DR ,  AMMERMANN EBERHARD DR ,  HARRIES VOLKER DR ,  LORENZ GISELA DR ,  STRATHMANN SIEGFRIED DR

IPC: A01N37/38 ,  A01N37/50 ,  C07C251/60 ,  A01N35/10 ,  C07C67/343 ,  C07C69/716 ,  C07C249/06 ,  C07C249/08 ,  C07C251/38 ,  C07C251/40

Abstract: Alkoxyalkyl-substituted bisoximes of formula (I) are new. R1 = C(CO2CH3)=NOCH3 (a), C(CONHCH3)=NOCH3 (b), C(CONH2)=NOCH3 (c), C(CO2CH3)=CHOCH3 (d) or C(CO2CH3)=CHCH3 (e); R2 = CN, NO2, halo, 1-4C alkyl, 1-4C haloalkyl or 1-4C alkoxy; m = 0-3; R3 = 1-4C alkyl, 2-4C alkenyl or 2-4C alkynyl; R4 = 1-4C alkoxy-1-4C alkyl; R5 = 1-4C alkyl (optionally substituted by 3-6C cycloalkyl or 3-6C halocycloalkyl) or 3-6C alkenyl or 3-6C alkynyl (optionally substituted by halo).

公开(公告)号：DE19548786A1

公开(公告)日：1997-07-03

申请号：DE19548786

申请日：1995-12-27

Applicant: BASF AG

Inventor： KIRSTGEN REINHARD DR ,  BAYER HERBERT DR ,  GOETZ NORBERT DR ,  GRAMMENOS WASSILIOS DR ,  GROTE THOMAS DR ,  MUELLER BERND DR ,  MUELLER RUTH DR ,  OBERDORF KLAUS DR ,  RACK MICHAEL DR ,  ROEHL FRANZ DR ,  SAUTER HUBERT DR ,  AMMERMANN EBERHARD DR ,  HARRIES VOLKER DR ,  LORENZ GISELA DR ,  STRATHMANN SIEGFRIED DR

IPC: A01N43/56 ,  C07D231/12 ,  C07D231/20 ,  C07D231/22 ,  C07D231/18

Abstract: Compounds of the general formula (I) and their salts, in which the variables mean: n is 0, 1, 2, 3 or 4, where the radical R may be different if n is greater than 1; Q is -C(=CHCH3)-COOCH3, -C(=CHOCH3)-COOCH3, -C(=NOCH3)-COOCH3 or -C(=NOCH3)-NH(CH3); Het is a possibly substituted pyrazol ring; R is nitro, cyano, halogen, C1-C4 alkyl, C1-C4 halogen alkyl, C1-C4 alkoxy, C1-C4 halogen alkoxy, C1-C4 alkylthio or possibly substituted phenyl, phenoxy or, if n is greater than 1, a possible substituted 1,3 butadiene-1,4-diyl group bonded to two adjacent carbon atoms of the phenyl radical; R is hydrogen or a possible substituted one or two-nuclear carbo or heterocyclic aromatic ring which is bonded to the radical Het directly or via a (-CR R -) [R , R = H or alkyl or -CR R - = (-C(=O)-) or (-C(=NOR )-); R = alkyl or alkinyl], agents containing them and the use of the compounds (I) and the agents to combat damaging fungi and animal pests.

公开(公告)号：DE19542629A1

公开(公告)日：1997-05-22

申请号：DE19542629

申请日：1995-11-15

Applicant: BASF AG

Inventor： BAYER HERBERT DR ,  SAUTER HUBERT DR ,  OBERDORF KLAUS DR ,  GRAMMENOS WASSILIOS DR ,  GROTE THOMAS DR ,  KIRSTGEN REINHARD DR ,  MUELLER BERND DR ,  MUELLER RUTH DR ,  ROEHL FRANZ DR ,  AMMERMANN EBERHARD DR ,  HARRIES VOLKER DR ,  LORENZ GISELA DR ,  STRATHMANN SIEGFRIED DR

IPC: C07D521/00 ,  A01N37/50 ,  A01N43/08 ,  A01N43/10 ,  A01N43/36 ,  A01N43/40 ,  A01N43/50 ,  A01N43/54 ,  A01N43/56 ,  A01N43/647 ,  A01N43/653 ,  A01N43/76 ,  A01N43/78 ,  A01N43/80 ,  A01N43/824 ,  A01N43/836 ,  C07C249/16 ,  C07C251/74 ,  C07C251/88 ,  C07C255/66 ,  C07C259/06 ,  C07C251/60 ,  C07C249/04 ,  C07C251/36 ,  C07C255/17 ,  C07C255/61 ,  C07D413/12 ,  C07D417/12 ,  A01N43/00 ,  A01N35/10

Abstract: Disclosed are azinooximethers of formula (I) in which X stands for NOCH3, CHOCH3, CHCH3, Y stands for O, NZ, Z being H or alkyl, R stands for H, alkyl, R stands for cyano, nitro, trifluoromethyl, halogen, alkyl, alkoxy, m is 0, 1 or 2, (the R rests can be different if m is 2), R is H, cyano, alkyl, alkyl halide, alkoxy, cycloalkyl, R , R and R independently of one another stand for H or optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, heterocyclyl. Also disclosed are the salts of these compounds and process and intermediate products for manufacturing them, and the uses thereof in combating harmful fungi and pests.

公开(公告)号：DE19540092A1

公开(公告)日：1997-05-07

申请号：DE19540092

申请日：1995-10-27

Applicant: BASF AG

Inventor： MUELLER BERND DR ,  SAUTER HUBERT DR ,  BAYER HERBERT DR ,  GRAMMENOS WASSILIOS DR ,  GROTE THOMAS DR ,  KIRSTGEN REINHARD DR ,  OBERDORF KLAUS DR ,  ROEHL FRANZ DR ,  GOETZ NORBERT DR ,  RACK MICHAEL DR ,  MUELLER RUTH DR ,  LORENZ GISELA DR ,  AMMERMANN EBERHARD DR ,  STRATHMANN SIEGFRIED DR ,  HARRIES VOLKER DR

IPC: A01N37/50 ,  C07C251/88 ,  C07D213/53 ,  C07D231/12 ,  C07D261/08 ,  C07C251/48 ,  A01N37/10 ,  C07C245/18 ,  C07C249/12 ,  C07C251/40 ,  C07C255/63 ,  C07D213/24

Abstract: Phenylacetic acid derivs. of formula (I) and their salts are new. X = NOMe, CHOMe or CHMe; Y = O or NRa; Ra = H or 1-4C alkyl; R = CN, NO2, CF3, halo, 1-4C alkyl or 1-4C alkoxy; m = 0-2; R = H or 1-6C alkyl; R , R = H, CN, NO2, OH, NH2, halo or 1-6C alkyl, 1-6C alkoxy, 1-6C alkylthio, 1-6C alkylamino, di-1-6C alkylamino, 2-6C alkenyl, 2-6C alkenyloxy, 2-6C alkenylthio, 2-6C alkynyl, 2-6C alkynyloxy, 2-6C alkynylthio, 2-6C alkynylamino or N 2-6C alkynyl-N-1-6C alkylamino etc. (in which the hydrocarbon gps. are opt. substd.) or 3-6C cycloalkyl, 3-6C cycloalkoxy, 3-6C cycloalkylthio, 3-6C cycloalkylamino, N-3-6C cycloalkyl-N-1-6C alkylamino, 3-6C cycloalkenyl, 3-6C cycloalkenyloxy, 3-6C cycloalkenylthio, heterocyclyloxy, heterocyclylthio, heterocyclylamino, N-heterocyclyl-N-1-6C alkylamino, aryl, aryloxy, arylthio etc. in which the cyclic gps. are opt. substd.; R = R or CRd=NORe: Rd = R ; Re = H or 1-10C alkyl, 2-10C alkenyl, 2-10C alkynyl, 1-10C alkylcarbonyl etc. each opt. substd.

公开(公告)号：DE19528651A1

公开(公告)日：1997-02-06

申请号：DE19528651

申请日：1995-08-04

Applicant: BASF AG

Inventor： BAYER HERBERT DR ,  MUELLER RUTH DR ,  SAUTER HUBERT DR ,  HARREUS ALBRECHT DR ,  ROEHL FRANZ DR ,  AMMERMANN EBERHARD DR ,  HARRIES VOLKER DR ,  LORENZ GISELA DR ,  STRATHMANN SIEGFRIED DR

IPC: C07D261/12 ,  A01N37/36 ,  A01N37/50 ,  A01N37/52 ,  C07C259/06 ,  C07C327/58 ,  C07D261/08 ,  C07C259/04 ,  C07C259/12 ,  A01N37/18 ,  A01N37/10

Abstract: Hydroximic acid derivatives have the formula (I), in which the substituents have the following meanings: X stands for CH, CHO or NO; Y stands for O or NH; Z stands for O, S or NR ; R stands for hydrogen, alkyl, alkenyl or alkinyl; R stands for hydrogen, alkyl or halogen alkyl; R stands for optionally substituted alkyl, alkenyl, alkinyl or cycloalkyl; R stands for optionally substituted alkyl, alkenyl or alkinyl. Also disclosed are a process for preparing these compounds and agents containing the same for controlling animal pests and harmful fungi.

公开(公告)号：DE4441674A1

公开(公告)日：1996-05-30

申请号：DE4441674

申请日：1994-11-23

Applicant: BASF AG

Inventor： MUELLER BERND DR ,  MUELLER RUTH DR ,  BAYER HERBERT DR ,  SAUTER HUBERT DR ,  ROEHL FRANZ DR ,  AMMERMANN EBERHARD DR ,  LORENZ GISELA DR ,  GOETZ NORBERT DR

IPC: A01N37/22 ,  A01N37/34 ,  A01N47/20 ,  A01N47/24 ,  A01N47/30 ,  A01N47/40 ,  A01P3/00 ,  A01P7/04 ,  C07C20060101 ,  C07C205/34 ,  C07C239/08 ,  C07C251/58 ,  C07C255/64 ,  C07C259/06 ,  C07C269/06 ,  C07C271/28 ,  C07C271/38 ,  C07C271/58 ,  C07C271/60 ,  C07C273/18 ,  C07C275/64 ,  C07C317/26 ,  C07C317/28 ,  C07C323/18 ,  C07C323/23 ,  C07C327/38 ,  C07C327/42 ,  C07D213/56 ,  C07D239/24 ,  C07D241/10 ,  C07D521/00 ,  C07C275/32 ,  C07C251/28 ,  C07C273/02 ,  C07C269/00 ,  C07C249/08 ,  C07C249/12 ,  A01N43/34 ,  A01N43/48

Abstract: Iminooxymethylene anilides have the formula (I), in which the substituents and indices have the following meanings: R stands for hydrogen, optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, cycloalkinyl, alkylcarbonyl or alk-oxycarbonyl; R stands for alkyl, alkenyl, alkinyl, cycloalkyl or cycloalkenyl and when X stands for NR it may also stand for hydrogen; X stands for a direct bond, O or NR ; R stands for hydrogen, alkyl, alkenyl, alkinyl, cycloalkyl or cycloalkenyl; R stands for cyano, nitro, trifluoromethyl, halogen, alkyl or alkoxy; n equals 0, 1 or 2; R stands for hydrogen, hydroxy, halogen, alkyl, alkylhalide, alkoxy, alkylthio, optionally substituted cycloalkyl, heterocyclyl, aryl, arylalkyl, hetaryl or hetarylalkyl; R stands for hydrogen, optionally substituted alkyl, cycloalkyl, alkenyl, alkinyl, alkylcarbonyl, alkenylcarbonyl, alkinylcarbonyl or alkylsulfonyl; optionally substituted aryl, hetaryl, arylcarbonyl, hetarylcarbonyl, arylsulfonyl or hetarylsulfonyl. Also disclosed are the salts of said compounds, a process and intermediate products for preparing the same and agents containing the same.

公开(公告)号：CZ288053B6

公开(公告)日：2001-04-11

申请号：CZ315597

申请日：1996-03-25

Applicant: BASF AG

Inventor： MUELLER RUTH DR ,  BENOIT REMY DR ,  BAYER HERBERT DR ,  GOETZ NORBERT DR ,  SAUTER HUBERT DR

IPC: C07D231/12 ,  C07B61/00 ,  C07C249/04 ,  C07C249/12 ,  C07C249/14 ,  C07C251/38 ,  C07C251/48 ,  C07C255/62 ,  C07D261/08

Abstract: In the present invention there is disclosed a process for preparing of alpha-bis-oxime isomers of the general formula Ia: Re1O-N=CRe2-CRe3=N-ORe4 (Ia), wherein the groups Re1O- and Re2 on the N=C bond are in mutual position cis and wherein Re1 represents alkyl containing 1 to 6 carbon atoms, alkenyl containing 3 to 6 carbon atoms and alkynyl having 3 to 6 carbon atoms, Re2 represents an optionally substituted phenyl or an optionally substituted hetaryl, Re3 represents a hydrogen atom, a cyano group, a halogen atom, alkyl containing 1 to 4 carbon atoms, haloalkyl containing 1 to 4 carbon atoms and cycloalkyl having 3 to 6 carbon atoms and Re4 represents hydrogen. The proposed preparation process is characterized in that {alpha}-bis-oxime isomer of the general formula Ib: Re1O-N=CRe2-CRe3=N-ORe4 (Ib), wherein the groups Re1O- and Re2 on the N=C bond are in mutual position trans and wherein Re1, Re2, Re3 and Re4 are as specified above, optionally in a mixture with the {alpha}-bis-oxime isomer of the general formula Ia: Re1O-N=CRe2-CRe3=N-ORe4 (Ia) is treated in an aromatic hydrocarbon with a Lewis acid.