PRODUCTION OF SACCHARINCARBONYL HALIDE

    公开(公告)号:JPH11322732A

    公开(公告)日:1999-11-24

    申请号:JP8217999

    申请日:1999-03-25

    Applicant: BASF AG

    Abstract: PROBLEM TO BE SOLVED: To provide a method for selectively producing a saccharinecarbonyl halide useful as a herbicide from readily available starting materials while avoiding the formation of a byproduct by reacting a specific amide with an inorganic acid halide. SOLUTION: This method for producing a compound of formula I (X is a halogen; R and R are each H, a 1-6C alkyl, a 3-6C cycloalkyl or the like; R is H, a 1-6C alkyl, a 3-8C cycloalkyl or the like) comprises reacting (A) isophthalylsulfonamide of formula II with (B) an inorganic acid halide. Preferably, the reaction is carried out by using tionyl chloride, phosphorus oxychloride, oxalyl chloride or the like as the component B, in an organic solvent such as toluene within the temp. range of 25-130 deg.C.

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