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公开(公告)号:DE3540118A1
公开(公告)日:1987-05-14
申请号:DE3540118
申请日:1985-11-13
Applicant: BASF AG
Inventor: TAUBITZ CHRISTOF DR , SEILER ERHARD DR , SCHLEMMER LOTHAR
Abstract: A process for the preparation of modified polyphenylene ether resins by grafting fumaric acid, preferably at from 270 DEG to 350 DEG C., onto polyphenylene ethers which are mixed with vinylaromatic polymers, and modified polyphenylene ether resins consisting of from 4.95 to 95 parts by weight of polyphenylene ether, from 95 to 4.95 parts by weight of vinylaromatic polymer and from 0.05 to 10 parts by weight of grafted fumaric acid.
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公开(公告)号:DE3535274A1
公开(公告)日:1987-04-09
申请号:DE3535274
申请日:1985-10-03
Applicant: BASF AG
Inventor: TAUBITZ CHRISTOF DR , SEILER ERHARD DR , MITULLA KONRAD DR , BOEHLKE KLAUS DR
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公开(公告)号:DE3529866A1
公开(公告)日:1987-02-26
申请号:DE3529866
申请日:1985-08-21
Applicant: BASF AG
Inventor: TAUBITZ CHRISTOF DR , SEILER ERHARD DR , HAMBRECHT JUERGEN DR
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公开(公告)号:DE3516070A1
公开(公告)日:1986-11-06
申请号:DE3516070
申请日:1985-05-04
Applicant: BASF AG
Inventor: TAUBITZ CHRISTOF DR , SEILER ERHARD DR , HAMBRECHT JUERGEN DR
IPC: C08G81/02 , C08F212/10 , C08F212/14 , C08F220/44 , C08L25/04 , C08L25/16 , C08L33/20
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公开(公告)号:DE3515638A1
公开(公告)日:1986-11-06
申请号:DE3515638
申请日:1985-05-02
Applicant: BASF AG
Inventor: TAUBITZ CHRISTOF DR , SEILER ERHARD DR , HAMBRECHT JUERGEN DR , VOLKER MUENCH DR
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公开(公告)号:DE3261076D1
公开(公告)日:1984-11-29
申请号:DE3261076
申请日:1982-11-19
Applicant: BASF AG
Inventor: VYVIAL RUDOLF , TAUBITZ CHRISTOF DR , SCHLEMMER LOTHAR , BLECKMANN GERHARD , ZUERGER MANFRED , KRIEGER HEINRICH , THIELE HEINO DR
Abstract: A sheet-like structure is produced from a vinyl alcohol polymer by a method wherein, in a self-cleaning multi-screw extruder, the polymer is mixed with a small amount of water, the mixture is melted, homogenized, devolatilized and finally extruded as a melt, and the extrudate is shaped in a conventional manner into the sheet-like structure.
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公开(公告)号:DE2241129A1
公开(公告)日:1974-03-21
申请号:DE2241129
申请日:1972-08-22
Applicant: BASF AG
Inventor: SCHARF EMIL DR , WENDEL KURT DR , TAUBITZ CHRISTOF DR , GUENDER WOLF DR
Abstract: Paper fibres are bonded in absence of metallic salts at pH 5-9 pref. 6-8 using anionic polymer dispersions by polymsn. with a hydrophobic monomer in aq. medium in presence of emulsifiers contng. COOH gps., where the dispersions contain particles of mean size 200 nm and having Tg. 70 degrees C. Monomers are e.g. (meth)acrylic acid esters with >3C alcohols, or vinyl aromatic cpds. Emulsifiers are salts of (iso) fatty acids or resinic acids and their hydrogenation/disproportionation products or ethylene or diene reacted with maleic acid derivs. The process prevents growth of algae and deposits of adhesive and foaming. Corrosion is also reduced because the soln. is at near neutral pH in absence of salts.
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公开(公告)号:DE3850334D1
公开(公告)日:1994-07-28
申请号:DE3850334
申请日:1988-09-22
Applicant: BASF AG
Inventor: TAUBITZ CHRISTOF DR , GAUSEPOHL HERMANN DR , BOEHLKE KLAUS DR
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公开(公告)号:DE3871420D1
公开(公告)日:1992-07-02
申请号:DE3871420
申请日:1988-03-29
Applicant: BASF AG
Inventor: TAUBITZ CHRISTOF DR , SEILER ERHARD DR , BOEHLKE KLAUS DR , OSTERMAYER BERTRAM DR , GAUSEPOHL HERMANN DR
Abstract: A thermoplastic moulding compsn. is obtd. by mixing, at 200-320 deg. C for 0.5-30 mins., (A) 2-95.99 pts. wt., w.r.t. A+B+C+D, of a modified polyphenylene ether prepd. from (a1) 70-99.95 wt.% of a polymer with at least 30 wt.% of a polyphenylene ether and at most 70% of a vinyl-aromatic polymer, (a2) 0.5-10% of (a21) a monomer contg. amide gps. and a polymerisable C=C bond, (a22) a monomer contg. lactam gps. and a polymerisable C=C bond, and/or (a23) an alpha,beta-unsatd. dicarbonyl cpd., and (a3) 0-20% of a comonomer which can react with (a) and/or (a2), (B) 2-95.99 pts. wt., w.r.t. A+B+C+D, of a thermoplastic copolymer from (b11) 30-90.9% of an 8-12C vinylaromatic hydrocarbon, (b12) 9-40% of a 3-6C ethylenically unsatd. nitrile monomer, (b13) 0.1-30% of a maleic acid deriv., or a copolymerisable ethylenically unsatd. monomer with (b14) an epoxy gp., (b15) an oxazoline gp., and/or (b16) an OH gp., and (b17) 0-30% of an ethylenically unsatd. monomer copolymerisable with (b11-B16), (C) 2-95.99 pts. wt., w.r.t. A+B+C+D+, of a graft copolymer from 30-90% of a butadiene and/or acrylaterubber with Tg below 0 deg. C as graft backbone, and 70-10% of copolymer (B), prepd. in presence of the graft backbone, as graft sheath, and (D) 0.01-10 pts. w.r.t. A+B+C+D, of a cpd. with at least 2OH, thiol, epoxy and/or amino gps.
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公开(公告)号:DE3871419D1
公开(公告)日:1992-07-02
申请号:DE3871419
申请日:1988-03-29
Applicant: BASF AG
Inventor: TAUBITZ CHRISTOF DR , SEILER ERHARD DR , BOEHLKE KLAUS DR , OSTERMAYER BERTRAM DR , GAUSEPOHL HERMANN DR
Abstract: Compsns. (I) claimed are obtainable by mixing at 200-320 deg. C for 0.5-30 minutes (A) 3-96.9 pts. (all pts. wt.), on (A) + (B) + (C), modified polyphenylene ether prepd. from (a1) 70-99.95% on (A), component contg., on (a1), at least 30% polyphenylene ether and at most 70% vinyl aromatic polymer (a2) 0.05-10%, on (A), amide gp.-contg. monomer (II) and/or lactam gp.-contg. monomer (III), (II) and (III) each having polymerisable double bond, and/or alpha, beta-unsatd. dicarbonyl cpd. (IV) (a3) 0-20%, on (A), other, non-vinyl aromatic comonomer reacting with (a1) under prepn. conditions (B) 3-96.9 pts., on (A) + (B) + (C), SAN, ABS, and/or ASA polymer (C) 0.1-30 pts., on (A) + (B) + (C), poly-epsilon caprolactone of wt. average mol. wt. 400-100,000 g/mol and/or polymer of structure (I) where r is such that wt. average mol. wt. is 400-100,000 g/mol., where sum of components under (A), (B) and (C) = 100 pts..
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