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公开(公告)号:DE59006458D1
公开(公告)日:1994-08-25
申请号:DE59006458
申请日:1990-01-30
Applicant: BASF AG
Inventor: HESSE MICHAEL DR , SCHARF EMIL DR
IPC: C07D487/04
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公开(公告)号:CH541023A
公开(公告)日:1973-08-31
申请号:CH1407770
申请日:1970-09-23
Applicant: BASF AG
Inventor: SCHMIDT HORST DR , SCHARF EMIL DR , SPOOR HERBERT DR , ENDRES HORST DR
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公开(公告)号:CH411836A
公开(公告)日:1966-04-30
申请号:CH1045462
申请日:1962-09-03
Applicant: BASF AG
Inventor: LAUTENSCHLAGER HANS DR , SCHARF EMIL DR , WITTENBERG DIETMAR DR , MUELLER HERBERT DR
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公开(公告)号:DE59408268D1
公开(公告)日:1999-06-24
申请号:DE59408268
申请日:1994-07-21
Applicant: BASF AG
Inventor: HUELLMANN MICHAEL DR , BECKER RAINER DR , SCHARF EMIL DR
IPC: B01J23/74 , B01J23/88 , C07B61/00 , C07D295/08 , C07D295/088
Abstract: N-(2-Hydroxyethyl)piperazine of the formula I is prepared by reaction of triethanolamine of the formula II with ammonia in the presence of hydrogen at temperatures from 100 to 500 DEG C and pressures from 10 to 500 bar on heterogeneous catalysts, employing heterogeneous catalysts having an active mass containing 20 to 85% by weight of ZrO2 and/or Al2O3, 1 to 30% by weight of oxygen-containing compounds of copper, calculated as CuO, 1 to 60% by weight of oxygen-containing compounds of cobalt calculated as CoO and/or oxygen-containing compounds of nickel, calculated as NiO and/or oxygen-containing compounds of molybdenum, calculated as MoO3.
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公开(公告)号:DE3903622A1
公开(公告)日:1990-08-09
申请号:DE3903622
申请日:1989-02-08
Applicant: BASF AG
Inventor: HESSE MICHAEL DR , LERMER HELMUT DR , STECK WERNER DR , FISCHER ROMAN DR , MUELLER HERBERT DR , SCHARF EMIL DR
IPC: C07D487/08
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公开(公告)号:CH616170A5
公开(公告)日:1980-03-14
申请号:CH931375
申请日:1975-07-16
Applicant: BASF AG
Inventor: SCHARF EMIL DR , FIKENTSCHER ROLF DR , AUHORN WERNER , STREIT WERNER DR
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公开(公告)号:DE2241129A1
公开(公告)日:1974-03-21
申请号:DE2241129
申请日:1972-08-22
Applicant: BASF AG
Inventor: SCHARF EMIL DR , WENDEL KURT DR , TAUBITZ CHRISTOF DR , GUENDER WOLF DR
Abstract: Paper fibres are bonded in absence of metallic salts at pH 5-9 pref. 6-8 using anionic polymer dispersions by polymsn. with a hydrophobic monomer in aq. medium in presence of emulsifiers contng. COOH gps., where the dispersions contain particles of mean size 200 nm and having Tg. 70 degrees C. Monomers are e.g. (meth)acrylic acid esters with >3C alcohols, or vinyl aromatic cpds. Emulsifiers are salts of (iso) fatty acids or resinic acids and their hydrogenation/disproportionation products or ethylene or diene reacted with maleic acid derivs. The process prevents growth of algae and deposits of adhesive and foaming. Corrosion is also reduced because the soln. is at near neutral pH in absence of salts.
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公开(公告)号:DE4325848A1
公开(公告)日:1995-02-02
申请号:DE4325848
申请日:1993-07-31
Applicant: BASF AG
Inventor: HUELLMANN MICHAEL DR , BECKER RAINER DR , SCHARF EMIL DR
IPC: B01J23/74 , B01J23/88 , C07B61/00 , C07D295/08 , C07D295/088 , C07D295/023 , C07B37/10 , B01J23/70
Abstract: N-(2-Hydroxyethyl)piperazine of the formula I is prepared by reaction of triethanolamine of the formula II with ammonia in the presence of hydrogen at temperatures from 100 to 500 DEG C and pressures from 10 to 500 bar on heterogeneous catalysts, employing heterogeneous catalysts having an active mass containing 20 to 85% by weight of ZrO2 and/or Al2O3, 1 to 30% by weight of oxygen-containing compounds of copper, calculated as CuO, 1 to 60% by weight of oxygen-containing compounds of cobalt calculated as CoO and/or oxygen-containing compounds of nickel, calculated as NiO and/or oxygen-containing compounds of molybdenum, calculated as MoO3.
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公开(公告)号:DE3267921D1
公开(公告)日:1986-01-23
申请号:DE3267921
申请日:1982-09-01
Applicant: BASF AG
Inventor: HERTEL OTTO DR , LINHART FRIEDRICH DR , SCHARF EMIL DR
Abstract: Water-soluble, nitrogen-containing condensates are prepared by reacting a cross-linking agent, obtained by (a) condensing 1 mole of a dicarboxylic acid of 4 to 10 carbon atoms with from 1 to 2 moles of a polyalkylenepolyamine, having 3-10 basic nitrogen atoms in the molecule, to give a polyamidoamine and (b) reacting the polyamidoamine with epichlorohydrin and/or dichlorohydrin in aqueous solution at a pH of from 4.5 to 8.5 and at below 100 DEG C., from 1 to 130 parts by weight of epichlorohydrin and/or dichlorohydrin being employed per 100 parts by weight of the polyamidoamine from (a), with ammonia, a primary amine, a polyamine containing 2 to 4 N atoms, a polyether-amine or a polyamidoamine in aqueous solution at below 100 DEG C. The condensates are used as retention aids, flocculants and drainage aids in papermaking.
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公开(公告)号:DE3248326A1
公开(公告)日:1984-06-28
申请号:DE3248326
申请日:1982-12-28
Applicant: BASF AG
Inventor: HERTEL OTTO DR , BOETTGER GUENTER DR , KOERNIG WOLFGANG DR , LEBKUECHER ROLF DR , WACHE HARRO DR , SCHANZ RUDI DR , SCHARF EMIL DR
IPC: C07B61/00 , B01J23/00 , C07C67/00 , C07C209/00 , C07C209/02 , C07C209/48 , C07C209/60 , C07C211/14 , C07C85/12 , C07C87/18 , C07C87/20
Abstract: Process for the preparation of polyamines by hydrogenation of mono-, bis- or tris(2-cyanoethyl)amines or mixtures thereof on a cobalt catalyst with the addition of a diamine.
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