4.
    发明专利
    未知

    公开(公告)号:DE59408268D1

    公开(公告)日:1999-06-24

    申请号:DE59408268

    申请日:1994-07-21

    Applicant: BASF AG

    Abstract: N-(2-Hydroxyethyl)piperazine of the formula I is prepared by reaction of triethanolamine of the formula II with ammonia in the presence of hydrogen at temperatures from 100 to 500 DEG C and pressures from 10 to 500 bar on heterogeneous catalysts, employing heterogeneous catalysts having an active mass containing 20 to 85% by weight of ZrO2 and/or Al2O3, 1 to 30% by weight of oxygen-containing compounds of copper, calculated as CuO, 1 to 60% by weight of oxygen-containing compounds of cobalt calculated as CoO and/or oxygen-containing compounds of nickel, calculated as NiO and/or oxygen-containing compounds of molybdenum, calculated as MoO3.

    Paper pulp sizing - with aq dispersions contg reactive monomer with no salts

    公开(公告)号:DE2241129A1

    公开(公告)日:1974-03-21

    申请号:DE2241129

    申请日:1972-08-22

    Applicant: BASF AG

    Abstract: Paper fibres are bonded in absence of metallic salts at pH 5-9 pref. 6-8 using anionic polymer dispersions by polymsn. with a hydrophobic monomer in aq. medium in presence of emulsifiers contng. COOH gps., where the dispersions contain particles of mean size 200 nm and having Tg. 70 degrees C. Monomers are e.g. (meth)acrylic acid esters with >3C alcohols, or vinyl aromatic cpds. Emulsifiers are salts of (iso) fatty acids or resinic acids and their hydrogenation/disproportionation products or ethylene or diene reacted with maleic acid derivs. The process prevents growth of algae and deposits of adhesive and foaming. Corrosion is also reduced because the soln. is at near neutral pH in absence of salts.

    8.
    发明专利
    未知

    公开(公告)号:DE4325848A1

    公开(公告)日:1995-02-02

    申请号:DE4325848

    申请日:1993-07-31

    Applicant: BASF AG

    Abstract: N-(2-Hydroxyethyl)piperazine of the formula I is prepared by reaction of triethanolamine of the formula II with ammonia in the presence of hydrogen at temperatures from 100 to 500 DEG C and pressures from 10 to 500 bar on heterogeneous catalysts, employing heterogeneous catalysts having an active mass containing 20 to 85% by weight of ZrO2 and/or Al2O3, 1 to 30% by weight of oxygen-containing compounds of copper, calculated as CuO, 1 to 60% by weight of oxygen-containing compounds of cobalt calculated as CoO and/or oxygen-containing compounds of nickel, calculated as NiO and/or oxygen-containing compounds of molybdenum, calculated as MoO3.

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