公开(公告)号：DE19525187A1

公开(公告)日：1997-01-16

申请号：DE19525187

申请日：1995-07-11

Applicant: BASF AG

Inventor： BREITSCHEIDEL BORIS DR ,  POLANEK PETER DR ,  VOIT GUIDO DR ,  WITZEL TOM DR ,  LINDEN GERD DR ,  HESSE MICHAEL DR

IPC: B01J23/889 ,  B01J27/185 ,  B01J27/187 ,  C07C209/48 ,  C07C209/52

Abstract: Cobalt catalysts (I) are claimed, in which the active material contains 55-98 wt% Co, 0.2-15 wt% P, 0.2-15 wt% Mn and 0.05-5 wt% alkali metal, calcd. as oxide. The calcined catalyst is reduced in a stream of hydrogen at final temps. of 200-400[deg]C and then surface-oxidised in a stream of air at final temps. of 20-60[deg]C. Also claimed is a process for the hydrogenation of organic nitriles and/or imines at 60-150[deg]C and 50-300 bar using (I) as catalyst.

公开(公告)号：DE19507398C1

公开(公告)日：1996-09-12

申请号：DE19507398

申请日：1995-03-03

Applicant: BASF AG

Inventor： VOIT GUIDO DR ,  WITZEL TOM DR ,  BREITSCHEIDEL BORIS DR ,  HARDER WOLFGANG DR ,  LUYKEN HERMANN ,  PAUL AXEL DR ,  ROS KARL-HEINZ DR ,  WAHL PETER DR

IPC: B01J23/46 ,  B01J23/75 ,  B01J23/755 ,  C07B61/00 ,  C07C209/48 ,  C07C211/36 ,  C07C209/22

Abstract: Prepn. of 3-aminomethyl-3,5,5-trimethylcyclohexylamine (isophorone diamine; IPDA) from 3-cyano-3,5,5-trimethyl-cyclohexanone (isophorone nitrile; IPN) is carried out in three separate reaction zones by: (a) reacting IPN with excess liquid NH3 at 20-150 deg.C and 50-300 bar; (b) hydrogenating the reaction prod. with H2 in the presence of excess NH3 at 50-100 deg.C and 50-300 bar; and (c) hydrogenating the reaction prod. with N2 at 110-160 deg.C and 150-300 bar. Acidic metal oxide catalyst is used in stage (a); and hydrogenation catalyst, opt. with basic components or on neutral or basic supports, in stages (b) and (c).

公开(公告)号：DE4325847A1

公开(公告)日：1995-02-02

申请号：DE4325847

申请日：1993-07-31

Applicant: BASF AG

Inventor： BREITSCHEIDEL BORIS DR ,  POLANEK PETER DR ,  IRGANG MATTHIAS DR ,  PETERSEN HERMANN DR ,  LINDEN GERD DR ,  VOIT GUIDO DR ,  WITZEL TOM DR

IPC: B01J23/889 ,  B01J27/185 ,  B01J27/187 ,  B01J37/08 ,  C07B61/00 ,  C07C209/48 ,  C07C209/50 ,  C07C211/36 ,  B01J23/74 ,  C07C209/52

Abstract: Cobalt catalysts whose catalitically active composition consists of from 55 to 98% by wt. of cobalt, from 0.2 to 15% by wt. of phosphorus, from 0.2 to 15% by wt. of manganese and from 0.2 to 15% by wt. of alkali, calculated as oxide, by calcining the catalyst composition in a first step at final temperatures of from 550 to 750 DEG C and in a second step at final temperatures of from 800 to 1000 DEG C and also a process for hydrogenating organic nitriles and/or imines by use of the new cobalt catalysts.