公开(公告)号：ES2112003T3

公开(公告)日：1998-03-16

申请号：ES95114707

申请日：1995-09-19

Applicant: BASF AG

Inventor： GUNTHERBERG NORBERT DR ,  WEBER MARTIN DR ,  GRUBER FREDDY DR ,  LINDENSCHMIDT GERHARD DR

IPC: B29C45/00 ,  B29C48/03 ,  B29C48/305 ,  C08F265/06 ,  C08L9/06 ,  C08L21/00 ,  C08L25/02 ,  C08L25/04 ,  C08L51/00 ,  C08L51/04 ,  C08L51/06 ,  C08L53/02 ,  C08L71/02

Abstract: Thermoplastic moulding materials (I) contain: (A) 30-98 wt.% of a graft copolymer of: (ak) 30-90 wt.% rubber-elastic grafting core, obtd. by copolymerisation of: (ak1) 80-99.99 wt.% (1-10C alkyl) acrylate, (ak2) 0.01-20 wt.% crosslinking monomer, and (ak3) 0-40 wt.% other comonomer(s); and (as) 10-70 wt.% of a grafted shell derived from: (as1) 50-100 wt.% styrene cpd. of formula (a); and (as2) 0-50 wt.% other comonomer(s); (B) 1-50 wt.% of a thermoplastic polymer of: (b1) 50-100 wt.% styrene and/or alpha -methylstyrene (AMS), (b2) 0-50 wt.% acrylonitrile, and (b3) 0-50 wt.% other comonomer(s); and (C) 1-70 wt.% of a copolymer of: (c1) 30-90 wt.% styrene and AMS, (c2) 10-70 wt.% butadiene, and (c3) 0-30 wt.% other comonomer(s); comprising: (i) block X obtd. by polymerising (c2) and opt. (c3) and block Y by polymerising (c1) and opt. (c3), or (ii) a polymer with a butadiene-rich initial segment, increasing amts. of styrene along the chain, and a terminal segment of homo-polystyrene (PS); or (iii) a star-shaped polymer obtd. by linking several polymer chains contg. (c1)-(c3) with polyfunctional mols., and in which the olefinic double bonds are completely or almost completely hydrogenated. Also claimed are films and moulded prods. obtd. from (I). R , R = H or 1-8C alkyl, and/or (1-8C alkyl) (meth)acrylate.

公开(公告)号：DE59501363D1

公开(公告)日：1998-03-05

申请号：DE59501363

申请日：1995-09-19

Applicant: BASF AG

Inventor： GUENTHERBERG NORBERT DR ,  WEBER MARTIN DR ,  GRUBER FREDDY DR ,  LINDENSCHMIDT GERHARD DR

IPC: B29C45/00 ,  B29C48/03 ,  B29C48/305 ,  C08F265/06 ,  C08L9/06 ,  C08L21/00 ,  C08L25/02 ,  C08L25/04 ,  C08L51/00 ,  C08L51/04 ,  C08L51/06 ,  C08L53/02 ,  C08L71/02

Abstract: Thermoplastic moulding materials (I) contain: (A) 30-98 wt.% of a graft copolymer of: (ak) 30-90 wt.% rubber-elastic grafting core, obtd. by copolymerisation of: (ak1) 80-99.99 wt.% (1-10C alkyl) acrylate, (ak2) 0.01-20 wt.% crosslinking monomer, and (ak3) 0-40 wt.% other comonomer(s); and (as) 10-70 wt.% of a grafted shell derived from: (as1) 50-100 wt.% styrene cpd. of formula (a); and (as2) 0-50 wt.% other comonomer(s); (B) 1-50 wt.% of a thermoplastic polymer of: (b1) 50-100 wt.% styrene and/or alpha -methylstyrene (AMS), (b2) 0-50 wt.% acrylonitrile, and (b3) 0-50 wt.% other comonomer(s); and (C) 1-70 wt.% of a copolymer of: (c1) 30-90 wt.% styrene and AMS, (c2) 10-70 wt.% butadiene, and (c3) 0-30 wt.% other comonomer(s); comprising: (i) block X obtd. by polymerising (c2) and opt. (c3) and block Y by polymerising (c1) and opt. (c3), or (ii) a polymer with a butadiene-rich initial segment, increasing amts. of styrene along the chain, and a terminal segment of homo-polystyrene (PS); or (iii) a star-shaped polymer obtd. by linking several polymer chains contg. (c1)-(c3) with polyfunctional mols., and in which the olefinic double bonds are completely or almost completely hydrogenated. Also claimed are films and moulded prods. obtd. from (I). R , R = H or 1-8C alkyl, and/or (1-8C alkyl) (meth)acrylate.

公开(公告)号：DE19625604A1

公开(公告)日：1998-01-02

申请号：DE19625604

申请日：1996-06-26

Applicant: BASF AG

Inventor： WEBER MARTIN DR ,  SEIBRING JOACHIM DR

IPC: C08J5/00 ,  C08J5/18 ,  C08K5/00 ,  C08K5/13 ,  C08K5/3477 ,  C08K5/36 ,  C08K5/49 ,  C08K5/51 ,  C08L25/02 ,  C08L25/04 ,  C08L25/06 ,  C08L71/00 ,  C08L71/12 ,  C08L85/02 ,  D01F1/07 ,  D01F6/44 ,  C08K5/5317 ,  C08K5/5393 ,  C08L27/18 ,  C08L53/00

公开(公告)号：DE19621732A1

公开(公告)日：1997-12-04

申请号：DE19621732

申请日：1996-05-30

Applicant: BASF AG

Inventor： WEBER MARTIN DR ,  HORN PETER DR ,  WEIS ROBERT DR ,  HECKMANN WALTER DR ,  HINGMANN ROLAND DR

IPC: C08K3/04 ,  C08K5/49 ,  C08K7/00 ,  C08K7/22 ,  C08K7/24 ,  C08L25/00 ,  C08L25/06 ,  C08L71/12 ,  D01F1/07 ,  C08J5/18 ,  D01F6/56 ,  D01F6/88 ,  C08L25/04 ,  C08J3/20 ,  C08J5/00 ,  D01F6/96

Abstract: The invention relates to non-flammable, thermoplastic moulded materials containing (A) at least one polyphenylene ether, (B) at least one vinyl aromatic polymer, and (C) at least one flame-proofing agent. Said materials are characterised in that they also comprise (D) a quantity of expandable graphite, which quantity improves the anti-drip properties. The invention also relates to the use of said materials in the production of non-flammable moulded structures, fibres and sheets.

公开(公告)号：DE19547884A1

公开(公告)日：1997-06-26

申请号：DE19547884

申请日：1995-12-21

Applicant: BASF AG

Inventor： WEBER MARTIN DR ,  WEIS ROBERT DR ,  GUENTHERBERG NORBERT DR ,  MASSONNE KLEMENS DR ,  SEIBRING JOACHIM DR ,  ZIMMER GUENTHER DR

IPC: C08L25/12 ,  C08L51/04 ,  C08L69/00 ,  C08L71/00 ,  C08K5/523 ,  C09K21/14 ,  D01F6/88

Abstract: Moulding materials (MM), containing (A) 5-97.9 wt% polycarbonate with a mol. wt. (Mw) of 10000-64000, (B) 1-93.9 wt% graft copolymer, (C) 1-93.9 wt% of a copolymer of (c1) a vinylaromatic compound of formula (I), in which R = H or 1-8C alkyl, R = 1-8C alkyl and n = 0-3, or a (1-8C alkyl) acrylate and/or (1-8C alkyl) (1-8C alkyl)acrylate and (c2) acrylonitrile and/or (1-8C alkyl)acrylonitrile, (D) 0.01-10 wt% polyhydroxy- ether derived from an aliphatic or aromatic diol and epihalohydrin, (E) 0-25 wt% halogen-free phosphorus compound and (F) 0-50 wt% additives. Also claimed are: (i) mouldings, film or fibres containing MM, and (ii) fire retardants containing 0.01-10 wt% component (D) and 90-99.99 wt% component (E).

公开(公告)号：DE19535417A1

公开(公告)日：1997-03-27

申请号：DE19535417

申请日：1995-09-23

Applicant: BASF AG

Inventor： WUENSCH JOSEF DR ,  GOTTSCHALK AXEL DR ,  WEBER MARTIN DR ,  ALTSTAEDT VOLKER DR ,  KRESSLER JOERG DR ,  THOMANN RALF

IPC: C08L25/06 ,  C08L71/12 ,  C08L77/00 ,  C08L25/00 ,  D01F6/56

Abstract: The invention concerns thermoplastic shaping compounds containing: A) between 5 and 97.9 wt.% of a vinylaromatic polymer with a syndiotactic structure; B) between 2 and 90 wt.% of a thermoplastic polyamide; and C) between 0.1 and 50 wt.% of a polyphenylene ether modified by polar groups.

公开(公告)号：DE19501450A1

公开(公告)日：1996-07-25

申请号：DE19501450

申请日：1995-01-19

Applicant: BASF AG

Inventor： GOTTSCHALK AXEL DR ,  FISCH HERBERT DR ,  PIPPER GUNTER ,  WEBER MARTIN DR

IPC: C08G69/26 ,  C08L35/06 ,  C08L77/00 ,  C08L77/06 ,  C08L25/00 ,  D01F6/92

公开(公告)号：DE4437501A1

公开(公告)日：1996-04-25

申请号：DE4437501

申请日：1994-10-20

Applicant: BASF AG

Inventor： GUENTHERBERG NORBERT DR ,  WEBER MARTIN DR ,  GRUBER FREDDY DR ,  LINDENSCHMIDT GERHARD DR

IPC: B29C45/00 ,  B29C48/03 ,  B29C48/305 ,  C08F265/06 ,  C08L9/06 ,  C08L21/00 ,  C08L25/02 ,  C08L25/04 ,  C08L51/00 ,  C08L51/04 ,  C08L51/06 ,  C08L53/02 ,  C08L71/02 ,  B29C47/14

Abstract: Thermoplastic moulding materials (I) contain: (A) 30-98 wt.% of a graft copolymer of: (ak) 30-90 wt.% rubber-elastic grafting core, obtd. by copolymerisation of: (ak1) 80-99.99 wt.% (1-10C alkyl) acrylate, (ak2) 0.01-20 wt.% crosslinking monomer, and (ak3) 0-40 wt.% other comonomer(s); and (as) 10-70 wt.% of a grafted shell derived from: (as1) 50-100 wt.% styrene cpd. of formula (a); and (as2) 0-50 wt.% other comonomer(s); (B) 1-50 wt.% of a thermoplastic polymer of: (b1) 50-100 wt.% styrene and/or alpha -methylstyrene (AMS), (b2) 0-50 wt.% acrylonitrile, and (b3) 0-50 wt.% other comonomer(s); and (C) 1-70 wt.% of a copolymer of: (c1) 30-90 wt.% styrene and AMS, (c2) 10-70 wt.% butadiene, and (c3) 0-30 wt.% other comonomer(s); comprising: (i) block X obtd. by polymerising (c2) and opt. (c3) and block Y by polymerising (c1) and opt. (c3), or (ii) a polymer with a butadiene-rich initial segment, increasing amts. of styrene along the chain, and a terminal segment of homo-polystyrene (PS); or (iii) a star-shaped polymer obtd. by linking several polymer chains contg. (c1)-(c3) with polyfunctional mols., and in which the olefinic double bonds are completely or almost completely hydrogenated. Also claimed are films and moulded prods. obtd. from (I). R , R = H or 1-8C alkyl, and/or (1-8C alkyl) (meth)acrylate.

公开(公告)号：DE4429107A1

公开(公告)日：1996-02-22

申请号：DE4429107

申请日：1994-08-17

Applicant: BASF AG

Inventor： WEBER MARTIN DR ,  FISCH HERBERT DR ,  PIPPER GUNTER ,  GOTTSCHALK AXEL DR

IPC: C08L23/00 ,  C08L23/16 ,  C08L51/00 ,  C08L71/00 ,  C08L71/08 ,  C08L71/10 ,  C08L71/12 ,  C08L73/00 ,  C08L77/00 ,  C08L77/06 ,  C08L81/00 ,  C08L81/06 ,  C08L87/00 ,  C08L79/00 ,  D01F6/90 ,  D01F6/94

公开(公告)号：DE4414044A1

公开(公告)日：1995-10-26

申请号：DE4414044

申请日：1994-04-22

Applicant: BASF AG

Inventor： GOTTSCHALK AXEL DR ,  FISCH HERBERT DR ,  PIPPER GUNTER ,  WEBER MARTIN DR

IPC: C08J5/18 ,  C08L53/00 ,  C08L71/12 ,  C08L77/00 ,  C08L77/06 ,  D01F6/90 ,  C08L21/00 ,  D01F6/94

Abstract: Thermoplastic moulding materials (I) contain (A) 5-95 wt.% partly aromatic, partly crystalline copolyamide, derived mainly from (a1) 30-44 mole% terephthalic acid (TPA) units, (a2) 6-20 mole% isophthalic acid (IPA) units, (a3) 43-49.5 mole% hexamethylenediamine (HDA) units and (a4) 0.5-7 mole% 6-30C aliphatic cyclic diamine units, (B) 5-95 wt.% polyphenylene ether (PPE), (C) 0-30 wt.% rubber-elastic polymer, (D) 0-45 wt.% fibrous and/or particulate filler, (E) 0-20 wt.% fire retardant and (F) 0-30 wt.% normal additives and processing aids. Also claimed are moulded prods. obtd. from (I).