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公开(公告)号:BR0313757A
公开(公告)日:2005-06-21
申请号:BR0313757
申请日:2003-08-25
Applicant: BASF AG
Inventor: DANIEL THOMAS , RIEGEL ULRICH , ELLIOTT MARK , WEISMANTEL MATTHIAS , WENDKER MARTIN
IPC: B01J20/26 , A61L15/24 , A61L15/60 , C08J3/24 , C08L33/02 , C08L33/24 , C08L33/26 , C08L101/14 , C08L39/02 , C08L101/00 , C08L57/00
Abstract: Water-absorbing product comprises water-absorbing polymer particles and a nitrogen-containing polymer containing 5-17 mole/kg of protonatable nitrogen atoms. An Independent claim is also included for production of the water-absorbing product by applying the nitrogen-containing polymer or a solution thereof onto the water-absorbing polymer particles and optionally drying the product.
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公开(公告)号:ZA200403357B
公开(公告)日:2005-05-04
申请号:ZA200403357
申请日:2004-05-04
Applicant: BASF AG
Inventor: DANIEL THOMAS , MASSONNE KLEMENS , MICHAEL EXNER KAI , RIEGEL ULRICH , WEISMANTEL MATTHIAS
IPC: B65D65/02 , A61L15/00 , A61L15/60 , C07D265/32 , C08F8/30 , C08K5/357 , C08L101/14 , C08F , A61L
Abstract: The invention relates to a method for gel post-crosslinking or surface post-crosslinking water-absorbing hydogels with morpholine-2,3-diones, to the post-crosslinked hydrogels and to the use thereof.
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公开(公告)号:BR0311498A
公开(公告)日:2005-03-15
申请号:BR0311498
申请日:2003-06-10
Applicant: BASF AG
Inventor: DANIEL THOMAS , SCHROEDER JUERGEN , JAWOREK THOMAS , FUNK RUEDIGER , SCHWALM REINHOLD , WEISMANTEL MATTHIAS , RIEGEL ULRICH , POPP ANDREAS
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公开(公告)号:MX225754B
公开(公告)日:2005-01-24
申请号:MXPA01005256
申请日:2001-05-25
Applicant: BASF AG
Inventor: DANIEL THOMAS , RIEGEL ULRICH , WEISMANTEL MATTHIAS , HERFERT NORBERT , ENGELHARDT FRIEDRICH
IPC: A61F13/53 , A61F5/44 , A61F13/15 , A61F13/49 , A61L15/18 , A61L15/60 , C08F2/44 , C08F20/04 , C08K3/34
Abstract: The invention relates to hydrogels capable of absorbing aqueous fluids, which hydrogels are produced by polymerization of olefinically unsaturated carboxylic acids or their derivatives. The hydrogels are characterized in that before, during or after the polymerization reaction and before drying a silicic acid alkali salt of the general formula (I) M2O×nSiO2 is added to the polymerization reaction mixture. In said formula M is an alkali metal and n is a number between 0.5 and 4. The hydrogel obtained in this way is then dried at an elevated temperature. The invention also relates to a method for producing said hydrogels and to their use for absorbing aqueous fluids.
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公开(公告)号:DE10358369A1
公开(公告)日:2004-12-23
申请号:DE10358369
申请日:2003-12-11
Applicant: BASF AG
Inventor: RIEGEL ULRICH , DANIEL THOMAS , WEISMANTEL MATTHIAS , ELLIOTT MARK , FUNK RUEDIGER , SCHWALM REINHOLD
IPC: C08G65/26 , C08G65/332 , A61L15/26 , B65D65/38 , C04B24/32 , C09D171/02
Abstract: New mixtures (F i) of at least two (preferably 2-4) compounds (I), each having at least two double bonds and where at least two of (I) have at least two (meth)acrylate ester groups as double bond components, have a weight-functionality ratio (WFR) value (defined as the sum of the (molar fraction times molecular weight divided by number of double bonds) values for all the components (I)) of 200-600 (preferably 250-350) g per mole double bond. Independent claims are included for: (a) the preparation of (F i); (b) the production of a crosslinked hydrogel (CHG), by polymerizing the mixture (F i) with (meth)acrylic acid, optionally other monoethylenically unsaturated monomers (N) and optionally further copolymerizable hydrophilic comonomer(s) (M) in presence of radical initiator(s) (K) and optionally graft substrate(s) (L), then optionally post-crosslinking, drying and optionally milling and/or screening; (c) polymers obtained by the above CHG production method; (d) CHG's, containing at least one M in polymerized form and crosslinked with (F i); (e) mixtures comprising (by weight) 0.1-40% (F i) and (meth0acrylic acid, 0.5-99.9% (M), 0-10% esterification catalyst(s) (C), 0-5% polymerization inhibitor(s) (D), 0-10% solvent (E) and optionally diluents (G) to 100%; (f) CHG's obtained from the mixtures, followed by optionally post-crosslinking, drying and optionally milling and/or screening.
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公开(公告)号:BR0212952A
公开(公告)日:2004-10-13
申请号:BR0212952
申请日:2002-09-27
Applicant: BASF AG
Inventor: DANIEL THOMAS , EXNER KAI MICHAEL , MASSONNE KLEMENS , RIEGEL ULRICH , WEISMANTEL MATTHIAS
IPC: B65D65/02 , A61L15/00 , A61L15/60 , C07D265/32 , C08F8/30 , C08K5/357 , C08L101/14
Abstract: The invention relates to a method for gel post-crosslinking or surface post-crosslinking water-absorbing hydogels with morpholine-2,3-diones, to the post-crosslinked hydrogels and to the use thereof.
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公开(公告)号:DE59909423D1
公开(公告)日:2004-06-09
申请号:DE59909423
申请日:1999-11-18
Applicant: BASF AG
Inventor: DANIEL THOMAS , RIEGEL ULRICH , WEISMANTEL MATTHIAS , HERFERT NORBERT , ENGELHARDT FRIEDRICH
IPC: A61F13/53 , A61F5/44 , A61F13/15 , A61F13/49 , A61L15/18 , A61L15/60 , C08F2/44 , C08F20/04 , C08K3/34
Abstract: The invention relates to hydrogels capable of absorbing aqueous fluids, which hydrogels are produced by polymerization of olefinically unsaturated carboxylic acids or their derivatives. The hydrogels are characterized in that before, during or after the polymerization reaction and before drying a silicic acid alkali salt of the general formula (I) M2O×nSiO2 is added to the polymerization reaction mixture. In said formula M is an alkali metal and n is a number between 0.5 and 4. The hydrogel obtained in this way is then dried at an elevated temperature. The invention also relates to a method for producing said hydrogels and to their use for absorbing aqueous fluids.
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公开(公告)号:ES2205788T3
公开(公告)日:2004-05-01
申请号:ES99910242
申请日:1999-02-19
Applicant: BASF AG
Inventor: FUNK RUDIGER , FRENZ VOLKER , RIEGEL ULRICH , WEISMANTEL MATTHIAS , ENGELHARDT FRITZ , DANIEL THOMAS
IPC: C07D263/20 , A61L15/00 , A61L15/60 , C08F8/30
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公开(公告)号:CA2488226A1
公开(公告)日:2003-12-18
申请号:CA2488226
申请日:2003-06-06
Applicant: BASF AG
Inventor: JAWOREK THOMAS , SCHROEDER JUERGEN , SCHWALM REINHOLD , FUNK RUEDIGER , RIEGEL ULRICH , WEISMANTEL MATTHIAS , POPP ANDREAS , DANIEL THOMAS
IPC: C08G65/332 , A61L15/60 , C07B61/00 , C07C67/08 , C07C69/54 , C08F290/06 , C08G65/26 , C08G65/28
Abstract: The invention relates to the novel (meth)acrylic esters of polyalkoxylated trimethylolpropane of formula (I) wherein AO independently represents EO, PO or BO, whereby EO represents O-CH2-CH2-, PO independently represents O-CH2- CH(CH3)- or O-CH(CH3)-CH2-, BO independently represents O-CH2-CH(CH2-CH3)- o r O-CH(CH2-CH3)-CH2-, p1 + p2 + p3 equals 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74 o r 75, and R1, R2, R3 independently represent H or CH3. The invention also relates to a simplified method for producing said esters and to the use of t he reaction mixtures thereby obtained.
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公开(公告)号:AU2002250836A1
公开(公告)日:2002-08-12
申请号:AU2002250836
申请日:2002-01-18
Applicant: BASF AG
Inventor: DANIEL THOMAS , RIEGEL ULRICH , WEISMANTEL MATTHIAS
IPC: A61F13/53 , A61F5/44 , A61F13/15 , A61F13/49 , A61L15/18 , A61L15/60 , B01J20/26 , B01J20/30 , C08K3/32 , C09K17/02 , C09K17/20 , C09K17/40 , C09K101/00
Abstract: Disclosed is a water absorbent comprising particles of a water absorbent polymer whose surface is associated with a water insoluble metal phosphate. It possesses an improved performance profile comprising high absorption capacity, improved fluid transportation performance and a faster swell rate.
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