VERWENDUNG VON MEHRKERNIGEN PHENOLISCHEN VERBINDUNGEN ALS STABILISATOREN

    公开(公告)号:EP1991643A2

    公开(公告)日:2008-11-19

    申请号:EP07726453.9

    申请日:2007-02-21

    Applicant: BASF SE

    Abstract: The invention relates to the use of polynuclear phenolic compounds with up to 20 bezene nuclei per molecule, obtained by reaction of a tetrahydrobenzoxazine I, where R1 = a hydrocarbon group and R2, R3, R4 and R5 independently = H, OH, or hydrocarbon groups, with one or more of the same or different phenols II, where R7, R8, R9 and R10 independently = H, OH or hydrocarbon groups and/or with one or more of the same or different tetrahydrobenzoxazines I, with the proviso that at least one of the substituents has 13 to 3,000 carbon atoms and the remaining substituents, when hydrocarbon groups, have 1 to 20 carbon atoms, as stabilisers for stabilising inanimate organic materials against the effects of light, acid and heat.

    Abstract translation: 使用通过四氢苯并恶嗪化合物(I)与一种或多种酚化合物(II)或一种或多种其它四氢苯并恶嗪反应得到的每分子多达20个苯核的多核酚类化合物(Q)作为用于稳定无生命有机材料的稳定剂 光,酸和热的影响。 通过式(I)的四氢苯并恶嗪化合物与一种或多种式(II)的酚化合物或一种或多种其它的四氢苯并恶嗪反应得到的每分子多达20个苯核的多核酚类化合物(Q)用作用于稳定无生命的稳定剂 有机材料抵抗光,酸和热的影响。 R 1>:1-3000C烃,其可被一个或多个杂原子O,S和/或NR 6>中断; R 6>:H或1-4C烷基; R 2>,R 3> R 5>:H,OH或可以被一个或多个O,S和/或NR 6>中断的1-3000C烃基; R 4>:H,OH,1-3000C烃基,其可以被一个或多个式(Z)的O,S和/或NR 6>或四氢苯并恶嗪基团中断; 或R 2> + R 3>,R 3> + R 4>,R 4> + R 5+ +结构式为OCH 2 NR 13 CH 2的苯核心结构:第二个四氢恶嗪环; 或R 2> + R 3>,R 3> + R 4>,R 4> + R 5>,其结构与式-O-CH 2 -NR 13的苯核心键合; -CH 2或-OCH 2 -NR 14→-CH 2-:第二或第三个四氢恶嗪环; R 7>:可被一个或多个O,S和/或NR 6>或来自(I)的残基中间的H,OH,1-3000C烃基; R 8> R 10>:H,OH或1-3000C烃,其可被一个或多个O,S和/或NR 6>中断; 可以被一个或多个O,S和/或NR 6>或式(Za)的苯酚基团间隔的H,OH,1-3000C烃基; R 15> H或衍生自(I)的残基; R 11>,R 12>:H或1-10C-烷基; 和R 13> R 14> 1-3000的烃基,其被一个或多个O,S和/或NR 6>中断。 条件是当R 1> -R 10>,R 13>或R 14>中的至少一个为烃基时,R 1> -R 10>,R 13>或R 14'的其余部分为烃基 ,为1-20C。 独立权利要求包括:(1)包括涡轮燃料(喷气燃料)和至少(Q)的涡轮机燃料组合物; (2)用于涡轮燃料的添加剂浓缩物,其至少包含(Q),稀释剂和任选的至少一种添加剂; (3)至少包含(Q)的润滑剂组合物; (4)(Q); (5)其中n = 0-18的式(III)的寡聚和四氢苯并恶嗪; (6)式(IV)的双核酚类化合物; 和(7)式(V)的三核酚类化合物。 R 2a> -R 5a>,R 8a> -R 10a> = H或1-3000C烃,其可被一个或多个O,S和/或NR 6>中断。 [图像] [图像] [图像] [图像] [图像]。

    VERFAHREN ZUR HERSTELLUNG VON SILIZIUMHALTIGEN POLYAMID-KOMPOSITMATERIALIEN
    65.
    发明公开
    VERFAHREN ZUR HERSTELLUNG VON SILIZIUMHALTIGEN POLYAMID-KOMPOSITMATERIALIEN 审中-公开
    VERFAHREN ZUR HERSTELLUNG VON SILISIUMHALTIGEN POLYAMID-KOMPOSITMATEIALIEN

    公开(公告)号:EP2997082A1

    公开(公告)日:2016-03-23

    申请号:EP14724744.9

    申请日:2014-05-16

    Applicant: BASF SE

    Abstract: The invention relates to a method for producing polyamide composite materials containing silicon, comprising the copolymerisation of: a) at least one silicon compound (SV) having at least one silicon atom, said silicon atom having at least one lactamyl group of formula (A) bonded by means of the nitrogen atom thereof; b) the method also comprises copolymerisation with at least one comonomer (CM) that is selected from among ammonium salts of dicarboxilic acids, amino acids, amino acid amides and lactams. In formula (A), m represents a whole number between 1 and 11, in particular in between 2 and 9, and specifically 3, and # represents the connection to the silicon atom of the compound (SV).

    Abstract translation: 本发明涉及一种生产含硅的聚酰胺复合材料的方法,包括以下共聚合:a)至少一种具有至少一个硅原子的硅化合物(SV),所述硅原子具有至少一个式(A)的内酰胺基, 通过其氮原子键合; b)该方法还包括与至少一种选自二羧酸,氨基酸,氨基酰胺和内酰胺的铵盐的共聚单体(CM)的共聚合。 在式(A)中,m表示1和11之间的整数,特别是在2和9之间,具体地3和#表示与化合物(SV)的硅原子的连接。

    VERFAHREN ZUR HERSTELLUNG EINES KOMPOSITMATERIALS
    67.
    发明公开
    VERFAHREN ZUR HERSTELLUNG EINES KOMPOSITMATERIALS 审中-公开
    用于生产复合材料

    公开(公告)号:EP2864381A1

    公开(公告)日:2015-04-29

    申请号:EP13731744.2

    申请日:2013-06-25

    Applicant: BASF SE

    Abstract: The present invention relates to a process for producing a composite material composed of a) at least one oxidic phase and b) an organic polymer phase, comprising the copolymerization of at least one compound which is described by the following general formula I [(ArO)
    m MO
    n R
    r H
    p ]
    q (I) in which M is B, Al, Ga, In, Si, Ge, Sn, P, As or Sb, m is 1, 2 or 3, n is 0 or 1, r is 0, 1 or 2, p is 1, 2 or 3, q is 1 or an integer > 1, for example an integer from 2 to 20, especially an integer from 3 to 6, m + 2n + r + p is 1, 2, 3, 4 or 5 and corresponds to the valency of M, Ar is phenyl or naphthyl, where the phenyl ring or the naphthyl ring is unsubstituted or may have one or more, for example 1, 2 or 3, substituents selected from independently alkyl, cycloalkyl, alkoxy, cycloalkoxy and NR
    a R
    b in which R
    a and R
    b are each independently hydrogen, alkyl or cycloalkyl, R is alkyl, alkenyl, cycloalkyl or aryl, where aryl is unsubstituted or may have one or more substituents selected independently from alkyl, cycloalkyl, alkoxy, cycloalkoxy and NR
    a R
    b in which R
    a and R
    b are each as defined above, with at least one compound selected from formaldehyde and formaldehyde equivalents, in a reaction medium which is essentially anhydrous, to obtain a composite material having an arrangement of phase domains similar to those nanocomposite materials obtainable by twin polymerization as described in the prior art, and to the use of the composite material for production of gas storage materials, rubber mixtures, low-K dielectrics and electrode materials for lithium ion batteries.

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