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公开(公告)号:RO83586A
公开(公告)日:1984-04-02
申请号:RO10523681
申请日:1981-09-04
Applicant: MITSUI TOATSU CHEMICALS
Inventor: HONDA TADATOSHI , ITOH HIROSHI , SATTO JUN , MITSUISHI TOKATOSHI
IPC: B01D21/01 , C07C233/09 , C08F2/00 , C08F2/10 , C08F2/16 , C08F20/52 , C08F20/56 , C08F220/56
Abstract: Polyacrylamide useful as a high- molecular-weight, water-soluble cationic flocculant, is produced by polymerizing acrylamide which is substantially free from N-acryloyl acrylamide with a minor amount of cationic monomer. Crude acrylamide is preferably obtained by catalytic hydration of acrylonitrile with water in the presence of a metallic copper catalyst at a pH in the range of from 4 to 10, and then rendered substantially free from N-acryloyl acrylamide by physical adsorption, reactive adsorption, decomposition by a chemical reaction or a solvent extraction.
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公开(公告)号:GB2123822A
公开(公告)日:1984-02-08
申请号:GB8317676
申请日:1983-06-29
Applicant: MITSUI TOATSU CHEMICALS
Inventor: KUDOH AKIHIDE , HONDA TADATOSHI , KOTANI MAKOTO , TERADA KAZUHIRO , TSUDA TAKESHI , KIYONO SHINJI
IPC: C07D209/04 , B01J21/00 , B01J23/00 , B01J27/00 , C07B61/00 , C07D209/08
Abstract: Indoles are prepared by subjecting an N-(???-hydroxy) alkylaniline, in the presence of a catalyst and at a superatmospheric pressure, to a gas-phase catalytic reaction, whereby the selectivity of the reaction and the service life of the catalyst are improved.
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公开(公告)号:DE3324092A1
公开(公告)日:1984-01-12
申请号:DE3324092
申请日:1983-07-05
Applicant: MITSUI TOATSU CHEMICALS
Inventor: KUDOH AKIHIDE , HONDA TADATOSHI , KOTANI MAKOTO , TERADA KAZUHIRO , TSUDA TAKESHI , KIYONO SHINJI
IPC: C07D209/04 , B01J21/00 , B01J23/00 , B01J27/00 , C07B61/00 , C07D209/08
Abstract: Disclosed herein is a preparation process for an indole, which process comprises subjecting an N-( beta -hydroxy)-alkylaniline, in the presence of a catalyst and at a super-atmospheric pressure, to a gas-phase catalytic reaction. The present process improves the selectivity of the reaction and the service life of the catalyst.
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公开(公告)号:DE3248986T1
公开(公告)日:1983-10-20
申请号:DE3248986
申请日:1982-08-25
Applicant: MITSUI TOATSU CHEMICALS
Inventor: HONDA TADATOSHI , TERADA KAZUHIRO
IPC: C07B61/00 , C07D209/08
Abstract: PCT No. PCT/JP82/00337 Sec. 371 Date Apr. 22, 1983 Sec. 102(e) Date Apr. 22, 1983 PCT Filed Aug. 25, 1982 PCT Pub. No. WO83/00691 PCT Pub. Date Mar. 3, 1983.Preparation process of indole from aniline and ethylene glycol. Upon preparing indole by reacting aniline and ethylene glycol in a gas phase and in the presence of a catalyst, ethylene glycol is charged in portions to a multiplicity of catalyst stages formed by dividing a catalyst bed and connected in series. This divided supply of ethylene glycol permits the suppresing of the decomposition of ethylene glycol, even if the molar ratio of feed aniline to total feed ethylene glycol is small. The above process permits making the yield of indole large and reducing the amount of unreacted aniline to be separated and recovered from the reaction effluent.
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公开(公告)号:CA1149397A
公开(公告)日:1983-07-05
申请号:CA375979
申请日:1981-04-22
Applicant: MITSUI TOATSU CHEMICALS
Inventor: MATSUDA FUJIO , KATO TAKAZO , HONDA TADATOSHI
IPC: B01J27/00 , C07D209/08 , C07D209/04
Abstract: SPECIFICATION Title of the Invention Process for the Preparation of Indole and Derivatives Thereof A process for the preparation of indole and derivatives thereof wherein an aniline is reacted with a 1,2glycol in the vapor phase, the liquid phase or a mixed vapor-liquid phase. A salt of a metal of group IIa of the periodic table, a salt of iron, a salt of cobalt and/or a salt of nickel are used as the catalyst for this reaction. The present invention makes it possible to prepare indole and derivatives thereof in a single step by using inexpensive compounds as the starting materials.
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公开(公告)号:AU7350181A
公开(公告)日:1982-09-23
申请号:AU7350181
申请日:1981-07-28
Applicant: MITSUI TOATSU CHEMICALS
Inventor: HONDA TADATOSHI , ITOH HIROSHI , SAITO JUN , MITSUISHI TAKATOSHI
IPC: B01D21/01 , C07C233/09 , C08F2/00 , C08F2/10 , C08F2/16 , C08F20/52 , C08F20/56 , C08F220/56 , C08F4/44
Abstract: Polyacrylamide useful as a high- molecular-weight, water-soluble cationic flocculant, is produced by polymerizing acrylamide which is substantially free from N-acryloyl acrylamide with a minor amount of cationic monomer. Crude acrylamide is preferably obtained by catalytic hydration of acrylonitrile with water in the presence of a metallic copper catalyst at a pH in the range of from 4 to 10, and then rendered substantially free from N-acryloyl acrylamide by physical adsorption, reactive adsorption, decomposition by a chemical reaction or a solvent extraction.
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公开(公告)号:FR2479196A1
公开(公告)日:1981-10-02
申请号:FR8019783
申请日:1980-09-12
Applicant: MITSUI TOATSU CHEMICALS
Inventor: ITOH HIROSHI , HONDA TADATOSHI , SAITOH JUN , MITSUISHI TAKATOSHI
IPC: C07C20060101 , C08F8/12 , C08F120/56 , G01N11/00 , C07C103/133
Abstract: A process for purifying an aqueous acrylamide solution which has been obtained through catalytic hydration of acrylonitrile in the presence of a copper-containing catalyst, by the steps of passing said solution through a OH-form strongly basic anion exchange resin layer and then, through a H-form cation exchange resin layer, is disclosed.
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公开(公告)号:SG34250A1
公开(公告)日:1996-12-06
申请号:SG1995001021
申请日:1995-08-01
Applicant: MITSUI TOATSU CHEMICALS
Inventor: OHE HIROSHI , KUBOYAMA HISAHARU , MIYAZOE SATORU , ICHIKAWA SHINICHIRO , HONDA TADATOSHI
IPC: B01J23/72 , C01G3/00 , C07C231/06 , B01J37/18 , C07C233/09
Abstract: A copper catalyst is obtained by reducing a precursor containing copper and aluminum and not containing substantially malachite and aluminum hydroxide. It's use in the hydration of nitriles permits the preparation of amides with a high productivity and in a high selectivity.
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公开(公告)号:DE69119035T2
公开(公告)日:1996-10-02
申请号:DE69119035
申请日:1991-11-14
Applicant: MITSUI TOATSU CHEMICALS
Inventor: HONDA TADATOSHI , HORIUCHI NOBUNHIKO , KITAGAWA JUN , MURAKAMI MASAMI , KAWAHARA KAZUNORI , IO HIROFUMI
IPC: B01J27/199 , B01J27/24 , C07C51/25 , F16G5/16
Abstract: A composite oxide catalyst represented by the general formula: Mo-V-P-X-Y (wherein X represents at least one element selected from the group consisting of Sb, Cu, Co, Bi and As; Y represents at least one element selected from the group consisting of K, Rb, Cs and Tl) and a method for preparing methacrylic acid through gas phase catalytic oxidation of methacrolein with molecular oxygen in the presence of the foregoing catalyst are herein disclosed. The catalyst exhibits excellent catalytic activity, selectivity to methacrylic acid, catalytic stability and lifetime.
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公开(公告)号:DE3579511D1
公开(公告)日:1990-10-11
申请号:DE3579511
申请日:1985-06-25
Applicant: MITSUI TOATSU CHEMICALS
Inventor: HONDA TADATOSHI , TSUDA TAKESHI
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