公开(公告)号：GB1272923A

公开(公告)日：1972-05-03

申请号：GB528770

申请日：1970-02-04

Applicant: OREAL

Inventor： CHARLE ROGER ,  ZVIAK CHARLES ,  KALOPISSIS GREGOIRE

IPC: A45D29/00 ,  A61K8/02 ,  A61K8/11 ,  A61Q3/04 ,  C09D9/00

Abstract: 1,272,923. Nail varnish remover. L'OREAL. 4 Feb., 1970 [4 Feb., 1969], No. 5287/70. Heading C5D. A nail varnish removing composition in the form of a liquid, a paste or a solid comprises an appropriate vehicle and pressure-rupturable microcapsules containing at least one solvent which is ethyl, isopropyl, butyl or amyl acetate, butyl propionate, ethyl lactate, butyl stearate or acetone. Optional ingredients which may be mixed with the solvents are castor oil, olive oil, γ-valerolactone, monoethylether of ethylene glycol and the monoethyl ether of diethylene glycol. The encapsulating material may be a styrene/maleic acid copolymer, polyethylene, polethylene/ethyl cellulose mixture, polyurethane, a polyester, gelatine, natural waxes, polyamide, acrylic resin, urea-formaldehyde resin, acetal homo- or copolymer, casein, an epoxy resin, polypropylene or cellulose acetophthalate. The microcapsules may be double walled or may be mixtures of microcapsules having different wall thickness and/or of different encapsulating materials. The diameter of the microcapsules may be 50 to 250 microns. A cosmetic pencil (Example 3) is prepared by melting beeswax, ozokerite, carnauba wax, paraffin and lanolin, dispersing micro-capsules containing a solvent mixture in the molten mix and moulding to form a "lead" by means of a press. The compositions are applied to the nail varnish and the microcapsules are ruptured with the aid of a rag, a spatula, a pad of absorbent cotton or by rubbing.

公开(公告)号：DE1768740A1

公开(公告)日：1971-11-25

申请号：DE1768740

申请日：1968-06-25

Applicant: OREAL

Inventor： LACHAMPT FELIX ,  ZVIAK CHARLES ,  D OISE FRANCONVILLE VAL ,  VELON PIERRE

IPC: A61K8/41 ,  A61K8/49 ,  A61Q1/06

Abstract: 1,206,542. Lipsticks and rouses. L'OREAL. 28 June, 1968 [30 June, 1967], No. 31002/68. Heading A5B. Cosmetic compositions suitable for use as lipsticks or rouge comprise a salt of a bromacid dyestuff and a non-aromatic primary, secondary or tertiary monoamine in which the groups attached to the nitrogen atom contain at most a total of six carbon atoms and a substance which is at least a partial solvent therefore. Specific dyes are those of formulae I, II, III and IV. and amines include triethanolamine, 2-amino-2- methyl propanediol-1,3, diethanolamine, monoisopropanolamine, trihydroxymethyl-aminomethane, diglycolamine and morpholine. The solvent may be vegetable, animal, or mineral waxes or vegetable or mineral oils, or fatty alcohol, e.g. carnauba wax, bee's wax or ozokerite, lanolin, lecithin, or castor oil. Fillers, pigments and perfumes may also be added.

公开(公告)号：DE1617706A1

公开(公告)日：1971-04-15

申请号：DE1617706

申请日：1967-01-05

Applicant: OREAL

Inventor： KALOPISSIS GREGOIRE ,  ROUSSOPOULOS PAUL ,  ZVIAK CHARLES

IPC: A45D7/04 ,  A61K8/46 ,  A61Q5/04 ,  A61K7/10

Abstract: 1,170,133. Treating hair. L'OREAL. 6 Jan., 1967 [7 Jan., 1966], No. 863/67. Heading D1P. Hair which is not constrained is treated with a composition comprising a thiol, which, under the conditions of treatment has at least as strong a reducing action as a composition comprising glycerol thioglycolate at the same molar concentration in the cold, capable of reducing -S-S- bonds in the keratin of the hair, and immediately thereafter rinsing the hair without constraining it to improve its ability to be satisfactorily subsequently set. The reducing agent may be thioglycolic acid, thiolactic acid, thioglycerol, thioglycolic amide or glycerol thioglycolate and the treating composition may also contain swelling agents, e.g. urea, sequestrating agents, e.g. ethylene diamine tetraacetic acid, bases, e.g. ammonia, monoethanolamine or morpholine, buffers, e.g. ammonium bicarbonate, to maintain a pH of 5-10, dyestuffs and perfumes. The hair may be washed, contacted with the reducing composition for 5-20 minutes, rinsed, optionally treated with a neutralising agent, e.g. an aqueous solution of hydrogen peroxide or an alkali metal bromate, or with a catalyst, e.g. manganese sulphate or a glycol dimethacrylate, which promotes the reconstitution of the reduced -S-S- bonds in the keratin, and subsequently set using water or an aqueous solution comprising a cosmetic resin, e.g. polyvinylpyrrolidone or a vinyl pyrrolidene vinyl acetate copolymer. Alternatively the catalyst may be added to the reducing composition or to the hair-setting solution. The treating compositions may be in the form of a solution, fluid cream, gel or aerosol. The use of a basic composition comprising a mixture of at least one thiol and at least one disulphide of a thiol, the mole ratio of disulphide to thiol being at least 1.5:1 is disclaimed.

公开(公告)号：DE1617720A1

公开(公告)日：1971-03-25

申请号：DE1617720

申请日：1967-07-20

Applicant: OREAL

Inventor： ZVIAK CHARLES ,  HITTNER STEPHANE

IPC: A61K8/26 ,  A61K8/37 ,  A61K8/73 ,  A61Q1/02 ,  A61Q3/02

公开(公告)号：DE1617717A1

公开(公告)日：1971-03-25

申请号：DE1617717

申请日：1967-04-26

Applicant: OREAL

Inventor： ZVIAK CHARLES ,  BOUVET RENE ,  HITTNER STEPHANE

IPC: A61K8/33 ,  A61K8/92 ,  A61Q3/00 ,  A61Q3/02

公开(公告)号：CA863909A

公开(公告)日：1971-02-16

申请号：CA863909D

Applicant: L OREAL SOC

Inventor： CHARLE ROGER ,  KALOPISSIS GREGOIRE ,  ZVIAK CHARLES

公开(公告)号：GB1206542A

公开(公告)日：1970-09-23

申请号：GB3100268

申请日：1968-06-28

Applicant: OREAL

Inventor： LACHAMPT FELIX ,  ZVIAK CHARLES

IPC: A61K8/41 ,  A61K8/49 ,  A61Q1/06

Abstract: 1,206,542. Lipsticks and rouses. L'OREAL. 28 June, 1968 [30 June, 1967], No. 31002/68. Heading A5B. Cosmetic compositions suitable for use as lipsticks or rouge comprise a salt of a bromacid dyestuff and a non-aromatic primary, secondary or tertiary monoamine in which the groups attached to the nitrogen atom contain at most a total of six carbon atoms and a substance which is at least a partial solvent therefore. Specific dyes are those of formulae I, II, III and IV. and amines include triethanolamine, 2-amino-2- methyl propanediol-1,3, diethanolamine, monoisopropanolamine, trihydroxymethyl-aminomethane, diglycolamine and morpholine. The solvent may be vegetable, animal, or mineral waxes or vegetable or mineral oils, or fatty alcohol, e.g. carnauba wax, bee's wax or ozokerite, lanolin, lecithin, or castor oil. Fillers, pigments and perfumes may also be added.

公开(公告)号：DE1811291A1

公开(公告)日：1970-08-27

申请号：DE1811291

申请日：1968-11-27

Applicant: OREAL

Inventor： ZVIAK CHARLES ,  PHILIPPE DE BEAULIEU HENRI

公开(公告)号：GB1183513A

公开(公告)日：1970-03-11

申请号：GB1965067

申请日：1967-04-28

Applicant: OREAL

Inventor： ZVIAK CHARLES ,  BOUVET RENE ,  HITTNER STEPHANE

IPC: A61K8/33 ,  A61K8/92 ,  A61Q3/00 ,  A61Q3/02

Abstract: 1,183,513. Nail-hardening composition. L'OREAL. 28 April, 1967 [28 April, 1966], No. 19650/67. Heading A5B. [Also in Divisions C3 and C4] A nail hardening composition comprises 3- 10% by wt. of one or more monoaldehydes containing at least 2 carbon atoms or polyaldehydes containing more than 2 carbon atoms, one or more natural or synthetic resins, and one or more solvents for the resin. Specified aldehydes are acetaldehyde, propionaldehyde, butyraldehyde, glutaric aldehyde, saccharose dialdehyde, and starch dialdehyde. Water-soluble resins are preferred, and form a water-washable coating; water-insoluble resins, when used, can be compounded in a conventional clear or coloured nail varnish. Specified resins include vinyl polymers and copolymers, as such or in salt or semiester form, acrylic polymers, cellulose derivatives, shellac and gum arabic.

公开(公告)号：GB1174816A

公开(公告)日：1969-12-17

申请号：GB731567

申请日：1967-02-15

Applicant: OREAL

Inventor： ZVIAK CHARLES ,  GHILARDI GUILIANA

IPC: A61K20060101 ,  C09B51/00

Abstract: 1,174,816. Bleach dyeing compositions. L'OREAL. 15 Feb., 1967 [15 Feb., 1966; 22 Aug., 1966], No. 7315/67. Heading D1B. Compositions suitable for bleach dyeing human hair comprises (1) at least one watersoluble nitrobenzene or anthraquinone dye; (2) at least one disperse water-insoluble anthraquinone or azo dye and (3) hydrogen peroxide, the nitrobenzene or anthraquinone dye being one of the following; (a) a nitro-p-phenylene diamine of the formula: wherein R 1 R 2 and R 3 may be the same or different and represent H, C 1 -C 6 alkyl, C 1 -C 6 hydroxyalkyl, or -(CH 2 ) n -N(R 4 )R 5 wherein n is 2 to 6, and R 4 and R 5 which may be the same or different represent H, C 1 -C 6 alkyl, C 1 -C 6 hydroxyalkyl, or may together with the N atom form a heterocyclic ring, the radical -(CH 2 ) n -N(R 4 )R 5 optionally being quaternised when R 4 and R 5 are both other than H and when R 1 does not represent -(CH 2 ) n -N(R 4 )R 5 R 2 may also be a #-hydroxyethyl-amino propyl or a diethylaminoethyl radical; (b) a nitro-O- phenylene diamine of the formula: wherein R 1 and R 2 are as above except that R 2 is not a #-hydroxyethyl aminopropyl or diethylaminoethyl radical; (c) a nitro-m-phenylene diamine of the formula: wherein R 6 is H, halogen, C 1 -C 6 alkyl, or C 1 -C 6 alkoxy, R 7 and R 8 which may be the same or different represent H, C 1 -C 6 alkyl, C 1 -C 6 hydroxyalkyl, R 1 and R 2 are as defined in (a) above with the proviso that when at least one of R, and R 8 is other than the H and one of R 1 and R 2 is a radical -(CH 2 ) n -N(R 4 )R 5 in which R 4 and R 5 are as defined above the other of R 1 and R 2 is not a C 1 -C 6 hydroxy alkyl radical; (d) a nitrobenzene compound of the formula: wherein R 9 is H or C 1 -C 6 alkyl and R 10 is H, C 1 -C 6 alkyl or C 1 -C 6 hydroxyalkyl; (e) a nitroaniline of the formula: wherein R, and R 2 are as defined in (a) above except that R 2 is not a #-hydroxyethylaminopropyl or diethylaminoethyl group; or (f) a water-soluble anthraquiuone compound of the formula A-NH-(CH 2 ) @ NHR 1 wherein R 1 is H, C 1 -C 6 alkyl or C 1 -C 6 hydroxyalkyl, n is as defined in (a) above and A is a radical wherein Z 1 is H or -NHR 13 wherein R 13 is H or C 1 -C 6 alkyl, and Z is H or -NHR 11 in which R 111 is H, C 1 -C 6 alkyl or -(CH 2 ) n NHR 1 in which R 1 and n are as defined above with the proviso that the radical -NH-(CH 2 ) n -NHR 1 may occupy only the following positions on the anthraquinone nucleus; (i) the 1-position, in which case Z 1 is H or Z, if other than H, occupies the 4, 5 or 8 position, (ii) the 2-position, in which case R 1 , Z and Z 1 are all H or (ii) the 5-position in which case R 1 is H, Z 1 is NHR 13 in the 4-position and Z is NHR" in the 1- position R" being H or C 1 -C 6 alkyl, R 13 and R" being the same or different, or their acid addition salts. The compositions may also contain surface active agents, thickeners, perfumes, inorganic and organic bases, aliphatic alcohols and ethers and preferably have a pH of 8 to 11. The composition may comprise twin packs, one containing hydrogen peroxide and the other the dyestuffs. The composition may be applied to the hair for 15 to 45 minutes which is then shampooed, rinsed and dried.