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    62.
    发明专利
    未知

    公开(公告)号：PT82287B

    公开(公告)日：1988-02-17

    申请号：PT8228786

    申请日：1986-03-26

    Applicant: STANDARD OIL CO OHIO

    Inventor： GRASSELLI ROBERT K ,  TENHOVER MICHAEL A ,  HARRIS JONATHAM H

    IPC: B22F9/00 ,  C01B3/00 ,  C22C38/00 ,  C22C5/00 ,  C22C14/00 ,  C22C19/00 ,  C22C45/02 ,  C22C45/10 ,  C22C1/00

    Abstract: @ Novel materials having the ability to reversibly store hydrogen are amorphous metal alloys of the formula A a M b M' c wherein A is at least one metal selected from the group consisting of Ag, Au, Hg, Pd, and Pt;M is at least one metal selected from the group consisting of Pb, Ru, Cu, Cr, Mo, Si, W, Ni, Al, Sn, Co, Fe, Zn, Cd, Ga and Mn; andM' is at least one metal selected from the group consisting of Ca, Mg, Ti, Y, Zr, Hf, Nb, V, Ta and the rare earths; andwherein a ranges from greater than zero to about 0.80;b ranges from zero to about 0.70; andc ranges from about 0.08 to about 0.95; characterized in that 1) a substantial portion of A is disposed on the surface of said material and/or 2) that said material functions as an active surface layer for adsorbing/desorbing hydrogen in conjunction with. a bulk storage material comprising a reversible hydrogen storage material.

    63.
    发明专利
    未知

    公开(公告)号：BR8601191A

    公开(公告)日：1987-03-04

    申请号：BR8601191

    申请日：1986-03-18

    Applicant: STANDARD OIL CO OHIO

    Inventor： TENHOVER MICHAEL A ,  HENDERSON RICHARD S ,  GRASSELLI ROBERT K

    IPC: B22F9/20 ,  B22F9/00 ,  B22F9/16 ,  C22C1/00 ,  C22C33/00 ,  C22C45/00 ,  C22C32/00

    Abstract: Amorphous metal alloy compositions are synthesized by solid state incorporation/reduction reactions wherein a high-surface area support is brought in contact with a precursor metal-bearing compound in such a manner that the compound is incorporated into the support or caused to deposit metal onto the surface of the support. The composition obtained is an amorphous alloy composition or can be made so by heat treating at a temperature below the crystallization temperature of the amorphous metal alloy desired to be formed.

    65.
    发明专利
    未知

    公开(公告)号：BR8602910A

    公开(公告)日：1987-02-17

    申请号：BR8602910

    申请日：1986-06-24

    Applicant: STANDARD OIL CO OHIO

    Inventor： HARRIS JONATHAN H ,  TENHOVER MICHAEL A ,  GRASSELLI ROBERT K

    IPC: C25B11/10 ,  C22C45/00 ,  C25B11/04 ,  C25B11/08 ,  C25B1/26

    Abstract: Novel rhodium based amorphous metal alloys having the formula RhrAa where: A is B, P, As and mixtures thereof; r is from about 50 to 96 percent; and a is from about 4 to 50 percent. Novel rhodium based amorphous metal alloys are also based on the formula RhrBbDd where: D is Ir, Pd, Ru, Ti, Zr, Nb, Ta, Y, Hf and mixtures thereof; r is from about 50 to 96 percent; b is from about 4 to 50 percent; and d is from about 0 to 60 percent; and r + b + d = 100. Novel process for the generation of halogens from halide-containing solutions can be performed by employing the rhodium based metal alloys of the present invention.

    66.
    发明专利
    未知

    公开(公告)号：NO862525L

    公开(公告)日：1986-12-29

    申请号：NO862525

    申请日：1986-06-23

    Applicant: STANDARD OIL CO OHIO

    Inventor： TENHOVER MICHAEL A ,  HENDERSON RICHARD S ,  HARRIS JONATHAN H ,  GRASSELLI ROBERT K ,  WARD MICHAEL D

    IPC: C25B1/24 ,  C25B11/04 ,  C25B11/08 ,  C25B1/00

    Abstract: Amorphous metal alloys having the formula M¹ a M² b M³ c whereM¹ is Fe, Co, Ni, Pd and combinations thereof;M² is Ti, Zr, Hf, V, Nb, Ta and combinations thereof;M³ is Rh, Os, Ir, Pt and combinations thereof;a ranges from about 0 to 60;b ranges from 10 to 70; andc ranges from about 5 to 70, with the proviso that a + b + c = 100.These alloys have utility as anodes in electrolytic processes and a process for the generation of halogens from halide-containing solutions includes the step of conducting electrolysis of the solutions in an electrolytic cell having an amorphous metal alloy anode of the formula M¹ a M² b M³ c .

    67.
    发明专利
    未知

    公开(公告)号：BR8601379A

    公开(公告)日：1986-12-02

    申请号：BR8601379

    申请日：1986-03-26

    Applicant: STANDARD OIL CO OHIO

    Inventor： GRASSELLI ROBERT K ,  TENHOVER MICHAEL A ,  HARRIS JONATHAN H

    IPC: C22C38/00 ,  B22F9/00 ,  C01B3/00 ,  C22C5/00 ,  C22C14/00 ,  C22C19/00 ,  C22C45/02 ,  C22C45/10 ,  H01M4/38

    Abstract: @ Novel materials having the ability to reversibly store hydrogen are amorphous metal alloys of the formula A a M b M' c wherein A is at least one metal selected from the group consisting of Ag, Au, Hg, Pd, and Pt;M is at least one metal selected from the group consisting of Pb, Ru, Cu, Cr, Mo, Si, W, Ni, Al, Sn, Co, Fe, Zn, Cd, Ga and Mn; andM' is at least one metal selected from the group consisting of Ca, Mg, Ti, Y, Zr, Hf, Nb, V, Ta and the rare earths; andwherein a ranges from greater than zero to about 0.80;b ranges from zero to about 0.70; andc ranges from about 0.08 to about 0.95; characterized in that 1) a substantial portion of A is disposed on the surface of said material and/or 2) that said material functions as an active surface layer for adsorbing/desorbing hydrogen in conjunction with. a bulk storage material comprising a reversible hydrogen storage material.

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