IMPROVED ALKANOLYSIS PROCESS AND METHOD FOR SEPARATING CATALYST FROM PRODUCT MIXTURE AND APPARATUS THEREFOR
    62.
    发明公开
    IMPROVED ALKANOLYSIS PROCESS AND METHOD FOR SEPARATING CATALYST FROM PRODUCT MIXTURE AND APPARATUS THEREFOR 审中-公开
    改进的烷醇解方法和从产物混合物中分离催化剂的方法及其装置

    公开(公告)号:EP2864392A1

    公开(公告)日:2015-04-29

    申请号:EP13806916.6

    申请日:2013-06-12

    Abstract: The present invention provides an improved process and apparatus for alkanolysis of polytetramethylene ether diacetate to polytetraalkylene ether glycol in the presence of a C1 to C4 alkanol and an alkali or alkaline earth metal catalyst wherein the catalyst component of the product mixture comprising polytetraalkylene ether glycol, alkanol and catalyst, essentially free of the alkanol acetate by-product, e.g., methyl acetate is removed by contacting the mixture in the absence of added water with certain ion exchange resin at specified contact conditions. The invention further provides a highly efficient method for removing the catalyst component of a mixture comprising polytetraalkylene ether glycol, alkanol and alkali or alkaline earth metal catalyst by contacting the mixture in the absence of added water with certain ion exchange resin at specified contact conditions,

    Abstract translation: 本发明提供了一种改进的用于在C1-C4链烷醇和碱金属或碱土金属催化剂存在下将聚四亚甲基醚二乙酸酯烷醇解成聚四亚烷基醚二醇的方法和装置,其中产物混合物的催化剂组分包括聚四亚烷基醚二醇,链烷醇 和催化剂,基本上不含乙酸烷基酯副产物,通过在特定的接触条件下,在没有添加水的情况下使混合物与某些离子交换树脂接触而除去。 本发明进一步提供了一种高效方法,用于在特定接触条件下通过使混合物在没有添加水的情况下与某些离子交换树脂接触而除去包含聚四亚烷基醚二醇,链烷醇和碱金属或碱土金属催化剂的混合物的催化剂组分,

    NYLON POLYMER AND PROCESS
    64.
    发明公开
    NYLON POLYMER AND PROCESS 审中-公开
    尼龙聚合物及其方法

    公开(公告)号:EP2797983A2

    公开(公告)日:2014-11-05

    申请号:EP12826666.5

    申请日:2012-10-09

    CPC classification number: C08G69/08 C08G69/04 C08G69/06

    Abstract: Provided is a process for producing a nylon polymer comprising the steps of contacting an omega-terminal fatty acid or fatty acid ester with a pentenenitrile to produce a nitrile-functionalized unsaturated fatty acid or fatty acid ester, hydrogenating the nitrile-functionalized unsaturated fatty acid or fatty acid ester with hydrogen in the presence of a hydrogenation catalyst to produce a saturated amino acid and subjecting the saturated amino acid to polyamidation conditions to provide a nylon polymer.

    PROCEDE DE FABRICATION DE COMPOSES NITRILES A PARTIR DE COMPOSES A INSATURATION ETHYLENIQUE
    66.
    发明公开
    PROCEDE DE FABRICATION DE COMPOSES NITRILES A PARTIR DE COMPOSES A INSATURATION ETHYLENIQUE 有权
    用于制备组合物的方法包括硝酸酯组合物,其包含保护乙烯基

    公开(公告)号:EP2760824A1

    公开(公告)日:2014-08-06

    申请号:EP12769372.9

    申请日:2012-09-27

    CPC classification number: C07C253/10 C07C255/03

    Abstract: The present invention relates to a method for the hydrocyanation of organic ethylenically unsaturated compounds including at least one nitrile function. The invention specifically relates to a method for the hydrocyanation of a hydrocarbon compound including at least one ethylenic unsaturation by a reaction with hydrogen cyanide in a liquid medium and in the presence of a catalyst including a metal element selected from the transition metals and an organophosphorous ligand, the organophosphorous ligand including a compound of general formula (I), where R
    1 and R
    2 , which are identical or different, are a linear or branched alkyl radical having 1-12 carbon atoms, which can include heteroatoms, or an optionally substituted aromatic or cycloaliphatic radical that can include heteroatoms, wherein the covalent bond between P and R
    1 , and that between P and R
    2 , are P-C bonds.

    Abstract translation: 本发明涉及包含至少一个腈官能团的有机烯属不饱和化合物的氢氰化方法。 本发明特别涉及一种通过与氰化氢在液体介质中反应并在包含选自过渡金属和有机磷配体的金属元素的催化剂存在下氢化氰化包括至少一个烯属不饱和度的烃化合物的方法 该有机磷配体包括通式(I)的化合物,其中R 1和R 2相同或不同,是具有1-12个碳原子的直链或支链烷基,其可以包括杂原子或任选被取代的 芳族或脂环族基团,其可以包括杂原子,其中P和R 1之间以及P和R 2之间的共价键是PC键。

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