公开(公告)号：JP2003529576A

公开(公告)日：2003-10-07

申请号：JP2001572449

申请日：2001-04-03

Applicant: ロディア・シミ

Inventor： バルザノ セバスチャン ,  カレル フィリップ

IPC: C07B61/00 ,  C07C201/04 ,  C07C203/00

CPC classification number: C07C201/04 ,  C07C203/00

Abstract: The invention concerns a method for preparing alkyl nitrites of formula (I) R ONO (I) ONO wherein R represents a C1-C20, advantageously C2-C10 linear or branched alkyl group. The invention is characterised in that it consists in gradually and continuously adding in an aqueous medium, an alcohol of formula (II) R OH, R being as defined above, a nitrite of formula (III) M NO2, wherein M represents a metal cation, and a strong acid, so as to form continuously said alkyl nitrite, and in continuously drawing off said alkyl nitrite thus formed from the reaction medium.

公开(公告)号：JP2018527326A

公开(公告)日：2018-09-20

申请号：JP2018503541

申请日：2016-09-14

Applicant: ロンザ・リミテッド

Inventor： テシュラー,クリストフ ,  マイヤーヘーフェル,ウルリッヒ ,  ジラール・クリストフ ,  ビッテル,ミヒャエル ,  カルバーマーテン,ロルフ ,  アルノルト,クラウディオ ,  ガルムス,シュテファン ,  シュナイダー,クリスティアン ,  ティル,シュテファン ,  ファーブル,マニュエル ,  ラボー,ギー ,  シュナイドリッヒ,キリアン ,  ベネッツ,マルティン ,  エゲル,トーマス

IPC: C07C203/04 ,  C07C201/04

CPC classification number: C07C201/04 ,  B01J19/1881 ,  B01J2219/00033 ,  B01J2219/00162 ,  B01J2219/00166 ,  C07C203/00

Abstract: 本発明は、n−ブタノール、酸及びNaNO 2 を連続的に反応させる、n−ブタノールの含有量が低い亜硝酸n−ブチルの連続的な調製方法であって、n−ブタノール、酸及びNaNO 2 は少なくとも1バールの圧力差に備える混合装置内で混合され、酸は、HCl、H 2 SO 4 、ギ酸、メタンスルホン酸、及びそれらの混合物からなる群から選択され、HClの量はn−ブタノールのモル量に基づいて少なくとも1.02モル当量である該方法を開示する。

公开(公告)号：JP2004537587A

公开(公告)日：2004-12-16

申请号：JP2003519011

申请日：2002-08-02

Applicant: ビーエーエスエフ アクチェンゲゼルシャフト

Inventor： アーレスマン，マンフレッド ,  カイル，ミヒャエル ,  クディス，ステフェン ,  ゲバルト，ヨアヒム ,  シュイメットツェーク，ラルフ ,  ラック，ミヒャエル ,  ロヒトマン，レネ

IPC: C07B61/00 ,  C07C201/04 ,  C07C203/00

CPC classification number: C07C201/04 ,  C07C203/00

Abstract: In a continuous process for the preparation of alkyl nitrites and dinitrites, an alkanol or dialkanol is first mixed with an aqueous mineral acid, the reaction mixture obtained is then reacted with an inorganic nitrite and the product obtained can then be isolated immediately.

公开(公告)号：KR101874776B1

公开(公告)日：2018-07-04

申请号：KR1020187003110

申请日：2016-09-14

Applicant: 론자 리미티드

Inventor： 테슐러크리슈토프 ,  마이어회퍼울리히 ,  지라르크리스토쁘 ,  비텔마하엘 ,  칼베르마텐롤프 ,  아르놀트클라우디오 ,  가름스슈테판 ,  슈니더크리슈티안 ,  틸레슈테판 ,  파브르마뉘엘 ,  라부기 ,  슈니트리히킬리안 ,  페네츠마르틴 ,  에겔토마스

IPC: C07C201/04 ,  C07C203/00

CPC classification number: C07C201/04 ,  B01J19/1881 ,  B01J2219/00033 ,  B01J2219/00162 ,  B01J2219/00166 ,  C07C203/00

Abstract: 본발명은연속방식으로의 n-부탄올, 산및 NaNO의반응을포함하는, 낮은 n-부탄올함량의 n-부틸나이트라이트의연속제조방법으로서, n-부탄올, 산및 NaNO가적어도 1 bar 의압력강하를제공하는혼합장치에서혼합되고; 산이 HCl, HSO, 포름산, 메탄술폰산, 및이들의혼합물로이루어진군으로부터선택되고; HCl 의양은 n-부탄올의몰량을기준으로적어도 1.02 몰당량인 n-부틸나이트라이트의연속제조방법을개시한다.

公开(公告)号：US08987496B1

公开(公告)日：2015-03-24

申请号：US14054194

申请日：2013-10-15

Applicant: Southwest Research Institute

Inventor： Joseph A. McDonough ,  Darrel W. Johnston ,  Paul M. Thompson

IPC: C07C203/04 ,  C07C203/00 ,  C07C201/04 ,  A61M5/19

CPC classification number: C07C201/04 ,  C07C203/00

Abstract: The present disclosure relates to devices and methods for the preparation of amyl nitrite formulations at a point of use location from relatively shelf-stable reagents employing acidic cationic exchange resins.

Abstract translation: 本公开涉及在使用酸性阳离子交换树脂的相对稳定的试剂的使用位置制备亚硝酸戊酯制剂的装置和方法。

公开(公告)号：US20110257425A1

公开(公告)日：2011-10-20

申请号：US13088253

申请日：2011-04-15

Applicant: Juntao Liu ,  Siqin Li ,  Lei Li ,  Linna Zhang

Inventor： Juntao Liu ,  Siqin Li ,  Lei Li ,  Linna Zhang

IPC: C07C203/00

CPC classification number: C07C201/04 ,  C07C203/00

Abstract: The present invention relates to a process for producing C1-C4 alkyl nitrite, comprising loading a resin catalyst layer and/or a porous filler layer into a reactor, passing nitrogen oxide, oxygen and C1-C4 alkanol as raw materials through the resin catalyst layer and/or porous filler layer in a counter current, parallel current or cross current manner, reacting under the conditions including a reaction temperature of from 0 to 150° C., a reaction pressure of from −0.09 to 1.5 MPa, a molar ratio of C1-C4 alkanol/nitrogen oxide of 1-100:1, a molar ratio of nitrogen oxide/oxygen of 4-50:1, to obtain an effluent containing C1-C4 alkyl nitrite, wherein said nitrogen oxide is NO, or a mixed gas containing NO and one or more selected from N2O3 and NO2.

Abstract translation: 本发明涉及一种生产C1-C4烷基亚硝酸盐的方法，包括将树脂催化剂层和/或多孔填料层装入反应器中，使氮氧化物，氧和C1-C4链烷醇作为原料通过树脂催化剂层 和/或多孔填料层，以相对电流，并联电流或交叉电流方式，在0〜150℃的反应温度，-0.09〜1.5MPa的反应压力，-0.09〜1.5MPa的反应压力， C1-C4链烷醇/氮氧化物为1-100:1，氮氧化物/氧摩尔比为4-50:1，得到含有C 1 -C 4烷基亚硝酸盐的流出物，其中所述氮氧化物为NO，或混合 含有NO和选自N 2 O 3和NO 2中的一种或多种的气体。

公开(公告)号：US20040199003A1

公开(公告)日：2004-10-07

申请号：US10485209

申请日：2004-01-29

Inventor： Steffen Kudis ,  Rene Lochtman ,  Manfred Ehresmann ,  Michael Keil ,  Joachim Gebhardt ,  Michael Rack ,  Ralf Schimetzek

IPC: C07C23/02

CPC classification number: C07C201/04 ,  C07C203/00

Abstract: In a continuous process for the preparation of alkylnitrites and dinitrites, an alkanol or dialkanol is first mixed with an aqueous mineral acid, the reaction mixture obtained is then reacted with an inorganic nitrite and the product obtained can then be isolated immediately.

Abstract translation: 在用于制备烷基硝酸钠和二硝酸酯的连续方法中，首先将烷醇或二烷醇与无机酸水溶液混合，然后将获得的反应混合物与无机亚硝酸盐反应，然后立即分离得到的产物。

公开(公告)号：US4980496A

公开(公告)日：1990-12-25

申请号：US446028

申请日：1989-12-05

Applicant: Olan S. Fruchey

Inventor： Olan S. Fruchey

IPC: C07C201/04 ,  C07C203/00

CPC classification number: C07C201/04

Abstract: The invention provides a process for the production of C.sub.1 to C.sub.5 alkyl nitrite by forming an aqueous solution of C.sub.1 to C.sub.5 alkyl alcohol an alkali metal nitrite; cooling it; then slowly adding a hydrohalic acid solution while it is stirring; the reaction temperature is maintained in the range of from about -10.degree. C. to about 10.degree. C. until the reaction is substantially complete; and the two formed phases are separated in a separatory funnel.

Abstract translation: 本发明提供一种通过形成C1-C5烷基醇水溶液和碱金属亚硝酸盐来生产C1至C5烷基亚硝酸盐的方法; 冷却 然后在搅拌下缓慢加入氢卤酸溶液; 反应温度保持在约-10℃至约10℃的范围内，直至反应基本完成; 并且两个形成的相在分液漏斗中分离。

公开(公告)号：US4908466A

公开(公告)日：1990-03-13

申请号：US102367

申请日：1987-09-29

Applicant: James R. Nelson

Inventor： James R. Nelson

IPC: C07C201/02 ,  B01D3/00 ,  C07C67/00 ,  C07C201/00 ,  C07C201/04 ,  C07C203/00 ,  C07C203/02 ,  C07C203/04

CPC classification number: B01D3/009 ,  C07C201/04 ,  Y02P20/127

Abstract: A process and reaction vessel for producing alkyl nitrite is disclosed the process comprising (a) contacting nitric oxide, lower alcohol and oxygen in a reaction zone such that alkyl nitrite is formed, said reaction zone comprising a reactor section and a rectification section, (b) supplying a liquid scrubbing agent to an upper portion of the rectification section, (c) withdrawing a gaseous alkyl nitrite product stream from the upper portion of the rectification section, and (d) withdrawing a liquid stream from a lower portion of the reactor section. The reactor section provides intimate vapor-liquid contact sufficient to enhance the conversion of nitric oxide to alkyl nitrite and the rectification section provides sufficient vapor residence time to enhance conversion of oxygen, as well as sufficient rectification capabilities to reduce the amounts of water and nitric acid in the gaseous alkyl nitrite product stream.

公开(公告)号：US3875206A

公开(公告)日：1975-04-01

申请号：US44798474

申请日：1974-03-04

Applicant: HOECHST AG

Inventor： SCHUIERER ERICH ,  ULM KLAUS ,  REBSDAT SIEGFRIED ,  WIMMER IGNAZ

IPC: C07C31/40 ,  C07C203/00 ,  C07C203/04 ,  C07C77/02

CPC classification number: C07C29/132 ,  C07C201/02 ,  C07C201/04 ,  C07C203/04 ,  C07C203/00 ,  C07C31/40

Abstract: 2-Perfluoroalkyl ethanols are obtained by reacting 2-perfluoroalkyl ethyliodides with at least the two-fold molar amount of nitric acid of about 70 to 98 percent strength and hydrogenating the intermediates, which are the nitrates of the desired ethanols. The products are useful as starting materials for the production of hydrophobic and oleophobic textile finishing agents, e.g. the polymer acrylates and methacrylates of said 2perfluoroalkyl-ethanols.

Abstract translation: 2-全氟烷基乙醇通过使2-全氟烷基乙基碘化物与至少两倍摩尔量的硝酸浓度为约70-98％的强度反应并氢化作为所需乙醇的硝酸盐的中间体来获得。 该产品可用作生产疏水和疏油纺织整理剂的起始材料，例如， 所述2-全氟烷基 - 乙醇的聚合物丙烯酸酯和甲基丙烯酸酯。