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    71.
    发明专利
    未知

    公开(公告)号：BR9812343A

    公开(公告)日：2000-09-19

    申请号：BR9812343

    申请日：1998-09-05

    Applicant: BASF AG

    Inventor： SCHOFER PETER ,  HAMPRECHT GERHARD ,  MENGES MARKUS ,  MENKE OLAF ,  RACK MICHAEL ,  REINHARD ROBERT ,  ZAGAR CYRILL ,  MUENSTER PETER ,  WESTPHALEN KARL-OTTOO ,  OTTEN MARTINA ,  WALTER HELMUT

    IPC: A01N43/58 ,  C07D237/20 ,  C07D237/22 ,  C07D405/10

    Abstract: Substituted 2-phenyl-3(2H)-pyridazinones Iand salts thereof, wheren=0, 1, 2; R1=C1-C4-alkyl, C1-C4-haloalkyl;R2=H, halogen; R3=halogen, CN;R4=H, NO2, CN, CHO, NH-OH, C1-C4-alkyl, C1-C4-halogenalkyl, -OR5, -CH=N-OR6, -CH=C(R7)-CO-OR8, -CO-OR9, C1-C6-alkyl-SO2-NH, di(C1-C6-alkylsulfonyl)amino orR5=C1-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl, (C1-C6-alkoxy)carbonyl-C1-C4-alkyl, (C3-C6-alkenyloxy)carbonyl-C1-C4-alkyl, (C3-C6-alkynyloxy)carbonyl-C1-C4-alkyl, C1-C4-alkoxy(C1-C4-alkoxy)carbonyl-C1-C4-alkyl;R6=H, C1-C4-alkyl, hydroxycarbonyl-C1-C4-alkyl, (C1-C4-alkoxy)carbonyl-C1-C4-alkyl;R7=H, halogen, C1-C4-alkyl; R8=H, C1-C6-alkyl;R9=H, C1-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl, C1-C4-alkoxy-C1-C4-alkoxy, hydroxycarbonyl-C1-C4-alkyl, (C1-C6-alkoxy)carbonyl-C1-C4-alkyl, (C3-C6-alkenyloxy)carbonyl-C1-C4-alkyl, (C3-C6-alkynyloxy)carbonyl-C1-C4-alkyl, C1-C4-alkoxy-(C1-C4-alkoxy)carbonyl-C1-C4-alkyl;R10=H, C1-C6-alkyl, COOH, (C1-C6-alkoxy)carbonyl;and their use as herbicides and for the desiccation/defoliation of plants are described.

    SUBSTITUTED PYRAZOL-3-YLBENZAZOLES
    72.
    发明专利
    SUBSTITUTED PYRAZOL-3-YLBENZAZOLES 未知

    公开(公告)号：BG103554A

    公开(公告)日：2000-06-30

    申请号：BG10355499

    申请日：1999-07-05

    Applicant: BASF AG

    Inventor： ZAGAR CYRILL ,  HAMPRECHT GERHARD ,  MENGES MARKUS ,  MENKE OLAF ,  SCHAFER PETER ,  WESTPHALEN KARL-OTTO ,  MISSLITZ ULF ,  WALTER HELMUT

    IPC: A01N43/56 ,  A01N43/74 ,  C07D413/04 ,  C07D413/10 ,  C07D417/04 ,  C07D417/10

    Abstract: The compounds are used as herbicides, as plant desiccators/defoliants. They have the formula where R1 is H, C1-C4 alkyl, C1-C4 halogenalkyl; R2 is cyano, C1-C4 alkyl, C1-C4 halogenalkyl, C1-C4 alkoxy, C1-C4 halognalkoxy, C1-C4 alkylthio, C1-C4 halogenalkylthio, C1-C4 alkylsulphynyl, C1-C4 halogenalkylsulphynyl, C1-C4 alkylsulphonyl, or C1-C4 halogenalkylsulphonyl; R3 is H, halogen, CN, nitro, C1-C4 alkyl or C1-C4 halogenalkyl; R4 means H, halogen, R5 is H, CN, halogen, C1-C4 alkyl, C1-C4 halogenalkyl, C1-C4 alkoxy or C1-C4 halogenalkoxy; Z is the group of -N = C(XR6)-O- or -N=C(XR6)-S- which is bound by the nitrogen, oxygen or sulphur to alpha ; X is chemical bound, oxygen, sulphur, -SO- or -SO2-, -NH- or -N(R7)-; R6 & R7 mean C1-C4 alkyl, Ci-C6 halogenalkyl, cyano-C1-C4 alkyl, hydroxy-C1-C4 alkyl, C3-C6 alkenyl, cyano-C3-C6 alkenyl, C3-C6 halogenalkenyl, C3-C6 alkynyl, cyano-C3-C6 alkynyl, C3-C6 halogenalkynyl, C1-C4 alkoxy-C1-C4 alkyl, C1-C4 halogen-alkoxy- C1-C4 alkyl, C3-C4 alkenylalkoxy- C1-C4 alkyl, C3-C4 alkynylalkoxy- C1-C4 alkyl, C3-C8 cycloalkoxy- C1-C4 alkyl, amino- C1-C4 alkyl, C1-C4 alkylamino C1-C4 alkyl, di (C1-C4 alkyl)amino- C1-C4 alkyl, C1-C4 alkyl, C1-C4 alkylthio- C1-C4 alkyl, C1-C4 halogenalkylthio cicualkyl, C3-C4 alkenylthio- C1-C4 alkyl, C3-C4 alkynylthio- C1-C4 alkyl, C1-C4 alkylsulphynyl- C1-C4 alkyl, C1-C4 halogensulphynyl- C1-C4 alkyl, C3-C4 alkenylsulphynyl- C1-C4 alkyl, C3-C4 alkynylsulphynyl- C1-C4 alkyl, C1-C4 alkylsulphonyl- C1-C4 alkyl, C1-C4 halogenalkylsulphonyl- C1-C4 alkyl, C3-C4 alkenylsulphonyl- C1-C4 alkyl, C3-C4 alkynylsulphonyl- C1-C4 alkyl, hydroxycarbonyl- C1-C4 alkyl, C1-C4 alkoxycarbonyl- C1-C4 alkyl group which can be substituted with CN or C1-C4 alkoxycarbonyl group, (C1-C4 alkyl)thiocarbonyl- C1-C4 alkyl, aminocarbonyl- C1-C4 alkyl, C1-C4 alkylaminocarbonyl- C1-C4 alkyl, di(C1-C4 alkyl)-aminocarbonyl- C1-C4 alkyl, di(C1-C4 alkyl)phosphonyl- C1-C4 alkyl, C1-C4 alkoxyimino- C1-C4 alkyl, C3-C4 alkynyloxyimino- C1-C4 alkyl optionally substituted C3-C8 cycloalkyl, C3-C8 cycloalkyl, phenyl, phenyl- C1-C4 alkyl, 3- to 7-member heterocyclyl or heterocyclyl- C1-C4 alkyl where every cycloalkyl or heterocyclic ring can contain CO- or CS- as a member in the ring; when X means chemical bond -O-, -S-, -NH- or -N(R7)-, R6 can also mean C1-C4 alkylcarbonyl, C1-C4 halogenalkylcarbonyl, C1-C4 alkoxycarbonyl, C1-C4 alkylsulphonyl or C1-C4 halogenalkylsulphonyl; when X means simple chemical bond R6 can also mean CN, SH, amino, halogen, -CH2-CH(halogen)-R8, -CH=CH-R8 or -CH=C(halogen)-R8 where R8 is COOH, C1-C4 alkoxycarbonyl, C1-C4 alkylthiocarbonyl, CONH2, C1-C4 alkylaminocarbonyl and di(C1-C4 alkyl) aminocarbonyl or di(C1-C4 alkyl) phosphonyl; or R6 & R7 optionally mean the substituted chain 1.3-propylene, tetramethylene, pentamethylene or ethyleneoxyethylene. The invention also relates to their salts. 16 claims

    Substituted (4-brompyrazole-3-yl)benzazoles
    74.
    发明专利
    Substituted (4-brompyrazole-3-yl)benzazoles 未知

    公开(公告)号：AU3820299A

    公开(公告)日：1999-11-16

    申请号：AU3820299

    申请日：1999-04-22

    Applicant: BASF AG

    Inventor： ZAGAR CYRILL ,  HAMPRECHT GERHARD ,  MENGES MARKUS ,  MENKE OLAF ,  REINHARD ROBERT ,  SCHAFER PETER ,  WESTPHALEN KARL-OTTO ,  OTTEN MARTINA ,  WALTER HELMUT

    IPC: C07D231/20 ,  A01N43/74 ,  A01N43/76 ,  A01N43/78 ,  C07D231/16 ,  C07D413/04 ,  C07D417/04 ,  C07D417/14 ,  C07F9/6541 ,  C07F9/6558

    Abstract: Substituted (4-bromopyrazol-3-yl)benzazoles Iand their salts whereR1=H, C1-C4-alkyl, C1-C4-haloalkyl;R2=CN, Cl-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkylsulfinyl, C1-C4-haloalkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-haloalkylsulfonyl;R4=H, halogen;R5=H, CN, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy or C1-C4-haloalkoxy;Z=-N=C(XR6)-O- or -N=C(XR6)-S-, attached to alpha via the nitrogen, oxygen or sulfur;X=a chemical bond, oxygen, sulfur, -S(O)-, -SO2-, -NH- or -N(R7)-;R6, R7=Cl-C6-alkyl, Cl-C6-haloalkyl, cyano-Cl-C4-alkyl, hydroxy-C1-C4-alkyl, C3-C6-alkenyl, cyano-C3-C6-alkenyl, C3-C6-haloalkenyl, C3-C6-alkynyl, cyano-C3-C6-alkynyl, C3-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, C3-C4-alkenyloxy-C1-C4-alkyl, C3-C4-alkynyloxy-C1-C4-alkyl, C3-C8-cycloalkyloxy-C1-C4-alkyl, amino-Cl-C4-alkyl, C1-C4-alkylamino-C1-C4-alkyl, di(C1-C4-alkyl)amino-C1-C4-alkyl, Cl-C4-alkylthio-C1-C4-alkyl, C1-C4-haloalkylthio-C1-C4-alkyl, C3-C4-alkenylthio-C1-C4-alkyl, C3-C4-alkynylthio-C1-C4-alkyl, C1-C4-alkylsulfinyl-Cl-C4-alkyl, C1-C4-haloalkylsulfinyl-C1-C4if X=a chemical bond, -O-, -S-, -NH- or -N(R7)-, R6 may also be C1-C4-alkylcarbonyl, C1-C4-haloalkylcarbonyl, C1-C4-alkoxycarbonyl, C1-C4-alkylsulfonyl or C1-C4-haloalkylsulfonyl;if X=a chemical bond, R6 may furthermore be CN, SH, NH2, halogen, -CH2-CH(halogen)-R8, -CH=CH-R8 or -CH=C(halogen)-R8, where R8=COOH, C1-C4-alkoxycarbonyl, C1-C4-alkylthiocarbonyl, CONH2, C1-C4-alkylaminocarbonyl, di(C1-C4-alkyl)aminocarbonyl or di(C1-C4-alkyl)phosphonyl;or R6+R7=an unsubstituted or substituted 1,3-propylene, tetramethylene, pentamethylene or ethyleneoxyethylene chain.Use: As herbicides; for the desiccation/defoliation of plants.

    BENZYLHYDROXYLAMINES AND INTERMEDIATES USED TO PREPARE THEM
    78.
    发明专利
    BENZYLHYDROXYLAMINES AND INTERMEDIATES USED TO PREPARE THEM 未知

    公开(公告)号：HU9802434A2

    公开(公告)日：1999-01-28

    申请号：HU9802434

    申请日：1996-06-27

    Applicant: BASF AG

    Inventor： HAMPRECHT GERHARD ,  HEISTRACHER ELISABETH ,  KLINTZ RALF ,  MENGES MARKUS ,  MENKE OLAF ,  MISSLITZ ULF ,  SCHAEFER PETER ,  WALTER HELMUT ,  WESTPHALEN KARL-OTTO ,  ZAGAR CYRILL

    IPC: A01N43/54 ,  A01N47/12 ,  A01N47/24 ,  A01N47/30 ,  A01N53/00 ,  C07C239/08 ,  C07C239/10 ,  C07C239/16 ,  C07C239/20 ,  C07C265/12 ,  C07C271/22 ,  C07C271/28 ,  C07C271/54 ,  C07C271/58 ,  C07C275/32 ,  C07C275/40 ,  C07D239/54 ,  C07D405/12

    Abstract: PCT No. PCT/EP96/02805 Sec. 371 Date Jan. 5, 1998 Sec. 102(e) Date Jan. 5, 1998 PCT Filed Jun. 27, 1996 PCT Pub. No. WO97/02253 PCT Pub. Date Jan. 23, 1997Benzylhydroxylamines I (X=-N(R7)-O-; Y=O, S; R1=halogen, CN, NO2, CF3; R2=H, halogen; R3=H, NH2, CH3; R4=H, halogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkylthio, C1-C6-alkylsulfinyl or C1-C6-alkylsulfonyl; R5=H, halogen, C1-C6-alkyl; R6=H, C1-C6-alkyl, C1-C6-haloalkyl, C3-C6-cycloalkyl, C2-C6-alkenyl; R7=H, C1-C6-alkyl, C3-C8-cycloalkyl, C1-C6-haloalkyl, C3-C6-alkenyl, C3-C6-alkynyl, C1-C6-alkylcarbonyl, C3-C6-alkenylcarbonyl, C3-C6-alkynylcarbonyl, C1-C6-alkoxycarbonyl, C2-C8-alkenyloxycarbonyl, C2-C6-alkynyloxycarbonyl, C1-C6-alkylthiocarbonyl, C1-C6-alkylsulfonyl, C1-C6-alkylcarbamoyl, it being possible for the 14 last-mentioned radicals to have attached to them 1-3 substituents: NO2, CN, halogen, C3-C8-cycloalkyl, OH, C1-C6-alkoxy, C3-C8-cycloalkoxy, C3-C6-alkenyloxy, C3-C6-alkynyloxy, C1-C6-alkoxy-C1-C6-alkoxy, C1-C6-alkylthio, C1-C6-alkylcarbonyl, C1-C6-alkylcarbonyloxy, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-alkylideneaminoxy, C1-C6-alkylcarbamoyl, unsubstituted or substituted phenyl, phenoxy or phenylsulfonyl, a 3- to 7-membered heterocyclyl or heterocyclyloxy group having 1-3 hetero atoms, it being possible for this group to be saturated, unsaturated or aromatic and to have attached to it 1-3 substituents, -CO-Z1R9, -OCO-Z1R9, -N(R9)R10 or R7=unsubstituted or substituted cycloalkylcarbonyl, phenylcarbonyl, phenylsulfonyl, phenylcarbamoyl; R8=H, C1-C6-alkyl, C3-C8-cycloalkyl, C1-C6-haloalkyl, C3-C6-alkenyl or C3-C6-alkynyl, it being possible for each of the 5 last-mentioned radicals to have attached to it 1-3 substituents: NO2, CN, halogen, C3-C8-cycloalkyl, OH, C1-C6-alkoxy, C3-C8-cycloalkoxy, C3-C6-alkenyloxy, C3-C6-alkynyloxy, C1-C6-alkoxy-C1-C6-alkoxy, C1-C6-alkylthio, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-alkylideneaminoxy, unsubstituted or substituted phenyl- [sic], phenoxy-[sic] or phenylsulfonyl, a 3- to 7-membered heterocyclyl or heterocyclyloxy group having 1-3 hetero atoms, it being possible for this group to be saturated, unsaturated or aromatic and to have attached to it 1-3 substituents, -CO-Z2R11, -OCO-Z2R11, -N(R11)R12; Z1 a chemical bond, oxygen, sulfur or -N(R10)-; Z2=a chemical bond, oxygen, sulfur or -N(R12)-; R9, R11=H, C1-C6-alkyl, C1-C6-haloalkyl, C3-C8-cycloalkyl, C3-C6-alkenyl, C3-C6-alkynyl, C1-C6-alkoxy-C1-C6-alkyl, (C1-C6-alkoxy)carbonyl-C1-C6-alkyl, unsubstituted or sub

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