Triamino-propyl-amino polyoxyalkylated tensides - contg. random or block copolymer gps. propylene oxide, ethylene oxide and butylene oxide

    公开(公告)号:DE2539850A1

    公开(公告)日:1977-03-17

    申请号:DE2539850

    申请日:1975-09-08

    Applicant: BASF AG

    Abstract: New surfactant tri-aminopropylamino polyoxyalkylated cpds. have formula N(CH2CH2CH2NZ2)3 (I). In (I) Z is a random copolymer or block copolymer built up o m mol propylene oxide, n mol. ethylene oxide or p mol butylene oxide; where m = 0-50 (0-35); n = 1-100 (1-85) and p=0-35 (0-25); m and p are different and ratio C2H4O:C3H6O C4H8O = 1 : (0-10): (0-10)). (I) are used as tensides in cleansing agents and detergents. (I) are mainly colourless to yellow liquids and are partic. suitable for liquid compsns. contg. acid builders, e.g. citric acid. Presence of 4 active base centres renders (I) more strongly kryptocationactive (I) have good solubility in acid media. In examples, (I) were prepd. by mixing 1 mol. triaminopropylamine with 1-10 wt.% water and reacting with 6 mol C3H6O, for 3 hrs, 3-8 atmos. excess press. 100-110 degrees C. Prod. was dehydrated at 90-100 degrees C/15 mm Hg. Prod. +1-3 wt.% KOH was mixed and treated with C3H6O at 130-135 degrees C, followed by C2H4O at 120-125 degrees C.

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