公开(公告)号：JPH05214038A

公开(公告)日：1993-08-24

申请号：JP21918292

申请日：1992-08-18

Applicant: BASF AG

Inventor： HARTMANN HEINRICH ,  DENZINGER WALTER ,  KROENER MICHAEL ,  NILZ CLAUDIA ,  LINHART FRIEDRICH ,  STANGE ANDREAS

IPC: C08F251/02 ,  C08F251/00 ,  D21H17/34 ,  D21H17/35 ,  D21H17/37 ,  D21H21/18

公开(公告)号：JPH0770232A

公开(公告)日：1995-03-14

申请号：JP5403494

申请日：1994-03-24

Applicant: BASF AG

Inventor： PFOHL SIGBERG ,  KROENER MICHAEL ,  HARTMANN HEINRICH ,  DENZINGER WALTER

IPC: C08F8/12 ,  C08F16/16 ,  C08F18/02 ,  C08F20/52 ,  C08F26/00 ,  C08F26/06 ,  C08F216/16 ,  C08F216/18 ,  C08F218/02 ,  C08F218/04 ,  C08F218/08 ,  C08F218/10 ,  C08F220/00 ,  C08F220/02 ,  C08F220/10 ,  C08F220/18 ,  C08F220/42 ,  C08F220/56 ,  C08F226/02 ,  C08F226/10 ,  D21H17/34 ,  D21H17/36 ,  D21H17/37 ,  D21H17/45 ,  D21H21/18

Abstract: Water-soluble copolymers containing copolymerized vinylamine units are prepared by copolymerizing (a) from 95 to 10 mol % of N-vinylformamide and (b) from 5 to 90 mol % of an ethylenically unsaturated monomer from the group consisting of vinyl acetate, vinyl propionate, C1-C4-alkyl vinyl ethers, the esters, nitriles and amides of acrylic acid and methacrylic acid and N-vinylpyrrolidone, and then eliminating from 30 to 100 mol % of the formyl groups from the copolymer. Preferred copolymers are copolymers of N-vinylformamide and vinyl acetate, in which from 30 to 100 mol % of the monomer units are hydrolyzed. The copolymers are used in papermaking to increase the dry strength and wet strength of the paper.

公开(公告)号：JPS63182318A

公开(公告)日：1988-07-27

申请号：JP140288

申请日：1988-01-08

Applicant: BASF AG

Inventor： DENZINGER WALTER ,  HARTMANN HEINRICH ,  GOECKEL ULRICH ,  RICHTER FELIX ,  RAUBENHEIMER HANS-JUERGEN ,  WINKLER EKHARD

IPC: C23F14/02 ,  C02F5/00 ,  C02F5/08 ,  C02F5/10 ,  C02F5/12 ,  C02F5/14 ,  C08F2/04 ,  C08F2/06 ,  C08F4/32 ,  C08F20/02 ,  C08F222/06

公开(公告)号：JPS6274902A

公开(公告)日：1987-04-06

申请号：JP22224586

申请日：1986-09-22

Applicant: BASF AG

Inventor： PFOHL SIGBERG ,  KROENER MICHAEL ,  HARTMANN HEINRICH ,  DENZINGER WALTER

IPC: C08F8/12 ,  C08F16/16 ,  C08F18/02 ,  C08F20/52 ,  C08F26/00 ,  C08F26/06 ,  C08F216/16 ,  C08F216/18 ,  C08F218/02 ,  C08F218/04 ,  C08F218/08 ,  C08F218/10 ,  C08F220/00 ,  C08F220/02 ,  C08F220/10 ,  C08F220/18 ,  C08F220/42 ,  C08F220/56 ,  C08F226/02 ,  C08F226/10 ,  D21H17/34 ,  D21H17/36 ,  D21H17/37 ,  D21H17/45 ,  D21H21/18

Abstract: Water-soluble copolymers containing copolymerized vinylamine units are prepared by copolymerizing (a) from 95 to 10 mol % of N-vinylformamide and (b) from 5 to 90 mol % of an ethylenically unsaturated monomer from the group consisting of vinyl acetate, vinyl propionate, C1-C4-alkyl vinyl ethers, the esters, nitriles and amides of acrylic acid and methacrylic acid and N-vinylpyrrolidone, and then eliminating from 30 to 100 mol % of the formyl groups from the copolymer. Preferred copolymers are copolymers of N-vinylformamide and vinyl acetate, in which from 30 to 100 mol % of the monomer units are hydrolyzed. The copolymers are used in papermaking to increase the dry strength and wet strength of the paper.

公开(公告)号：WO9719702A3

公开(公告)日：1997-08-28

申请号：PCT/EP9605062

申请日：1996-11-18

Applicant: BASF AG ,  BREITENBACH JOERG ,  SANNER AXEL ,  DENZINGER WALTER ,  LANG SIEGFRIED

Inventor： BREITENBACH JOERG ,  SANNER AXEL ,  DENZINGER WALTER ,  LANG SIEGFRIED

IPC: A61K47/48 ,  A01N59/12 ,  A61K31/00 ,  A61K31/755 ,  A61K31/787 ,  A61P1/00 ,  A61P1/12 ,  A61P31/00 ,  A61P31/04 ,  C08F8/18 ,  C08F8/20 ,  C08F8/22 ,  C08F26/06 ,  C08F226/06 ,  C08K3/02 ,  C08L39/04

CPC classification number: C08F226/06 ,  C08F8/22 ,  C08F26/06

Abstract: The invention concerns powdery complexes comprising iodine and a crosslinked polymer based on N-vinyl compounds and obtained by the dry heating of iodine and a polymer obtained by polymerizing monovinyl compounds (monomers A), of which the vinyl group is bonded to an N-atom of a nitrogenous heterocyclic ring, in the presence of between 0.5 and 10 wt %, relative to the monomers (A), of a compound (B) of general formula (I), A standing for -CH- or an N-atom and n being 2 or 3. The complexes are suitable for producing anti-diarrhoeal agents.

Abstract translation: 可以通过干燥加热碘和聚合物获得碘粉末形式和基于N-乙烯基化合物的交联聚合物的复合物，该聚合物是通过使乙烯基结合到氮的氮原子上的单乙烯基化合物（单体A） 基于单体（A），式（I）化合物（B）的0.5〜10重量％的存在下，其中A为-CH-或氮原子，n为2 或3.复合物适用于产生止泻药。

公开(公告)号：WO9412571A3

公开(公告)日：1994-08-04

申请号：PCT/EP9303159

申请日：1993-11-11

Applicant: BASF AG ,  PERNER JOHANNES ,  DIESSEL PAUL ,  GUEMBEL HELMUT ,  DENZINGER WALTER ,  HARTMANN HEINRICH ,  KRONER MATTHIAS

Inventor： PERNER JOHANNES ,  DIESSEL PAUL ,  GUEMBEL HELMUT ,  DENZINGER WALTER ,  HARTMANN HEINRICH ,  KRONER MATTHIAS

IPC: H04L27/20 ,  C02F5/10 ,  C08L33/02 ,  C08L35/00 ,  C08L51/02 ,  C08L77/04 ,  C11D3/37 ,  H04B7/00 ,  H04J3/16 ,  H04J3/22 ,  H04J3/24 ,  H04J11/00 ,  H04J13/00 ,  H04J13/18 ,  H04L20060101 ,  H04L1/00 ,  H04L1/08 ,  H04L12/00 ,  H04L27/30 ,  H04L29/06 ,  H04Q7/38

CPC classification number: C11D3/3788 ,  C02F5/10 ,  C08L33/02 ,  C08L35/00 ,  C08L51/02 ,  C08L77/04 ,  C11D3/3757 ,  C11D3/3769 ,  H04J3/1688 ,  H04J3/22 ,  H04J3/24 ,  H04J13/0048 ,  H04J13/18 ,  H04L1/0057 ,  H04L1/0059 ,  H04L1/0065 ,  H04L1/0071 ,  H04L1/08 ,  C08L2666/04 ,  C08L2666/02

Abstract: The invention concerns mixtures of (I) polymers of monoethylenically unsaturated dicarboxylic acids with a molecular weight of 200 to 5,000 and (II) (1) copolymers with a molecular weight of 10,000 to 150,000 consisting of (a) 10 to 70 % by wt. of monoethylenically unsaturated C4 to C8 dicarboxylic acids or salts thereof and (b) 30 to 90 % by wt. of monoethylenically unsaturated C3 to C10 monocarboxylic acids and/or salts thereof, (2) homopolymers and copolymers with a molecular weight of 1,000 to 500,00 consisting of monoethylenically unsaturated C3 to C10 monocarboxylic acids, (3) graft polymers with a molecular weight of 5,000 to 150,000 obtained by the radical-initiated graft polymerization of (A) monoethylenically unsaturated C3 to C10 carboxylic acids, their anhydrides and/or their salts in the presence of (B) mono-, oligo- or polysaccharides derivatives thereof, in the ratio by weight of A:B of (95 to 100):(5 to 80) and/or (4) polyaminocarboxylic acids and/or polymers containing aminocarboxylic groups, the mixtures containing components (I) and (II) in the ratio by weight of 10:0.5 to 0.5:10. The invention also concerns the use of such mixtures as additives in phosphate-free or phosphate-reduced textile-washing agents or as dispersants and deposit-prevention agents in cleaning agents for hard surfaces.

公开(公告)号：EP0205910A2

公开(公告)日：1986-12-30

申请号：EP86106760

申请日：1986-05-17

Applicant: BASF AG

Inventor： MESSMER KARLHEINZ DR ,  HENNIG KARL ,  DENZINGER WALTER ,  HETTCHE ALBERT DR ,  TRIESELT WOLFGANG DR ,  RAUBENHEIMER HANS-JURGEN

IPC: C08F2/00 ,  C08F2/10 ,  C08F2/36 ,  C08F4/00 ,  C08F4/04 ,  C08F4/28 ,  C08F4/32 ,  C08F2/34

CPC classification number: C08F2/10 ,  Y10S526/909

Abstract: Verfahren zur Herstellung von pulverfömigen wasserlöslichen Polymerisaten durch Polymerisieren von wasserlöslichen ethylenisch ungesättigen Monomeren in einem Pulverbett in Gegenwart von Polymerisationsinitiatoren und Wasser unter Aufrechterhaltung des Pulverzustands, Abführen der Polymerisationswärme durch Abdestillieren von Wasser und Umwälzung der Reaktionsmasse, wobei man als Polymerisationsinitiatoren wasserunlösliche, bei Temperaturen von 20°C flüssige organische Peroxide allein oder in Mischung mit bis zu 50 Gew.%, bezogen auf die Initiatormischung, an wasserlöslichen, organischen Azostartern und/oder wasserunlöslichen, bei 20°C festen, Peroxigruppen enthaltenden Verbindungen einsetzt.

Abstract translation: 一种用于通过在聚合引发剂存在下和水在粉末床聚合水溶性烯属不饱和单体，同时保持粉末状态下，通过蒸馏将反应物质，得到作为聚合引发剂的水不溶性的的水和循环去除聚合热，在20的温度下制备pulverfömigen水溶性聚合物的方法 ℃下重量单独或与高达50％的混合物的液体有机过氧化物，基于该引发剂混合物，使用水溶性有机偶氮引发剂和/或固体在20℃下不溶于水的，含有过氧化合物。

公开(公告)号：CA2247312C

公开(公告)日：2008-04-29

申请号：CA2247312

申请日：1997-02-19

Applicant: BASF AG

Inventor： HUMMERICH RAINER ,  SCHORNICK GUNNAR ,  DENZINGER WALTER ,  KISTENMACHER AXEL ,  RECK BERND ,  WEBER MANFRED

IPC: C08L35/00 ,  D06N7/06 ,  C08F8/30 ,  C08F8/32 ,  C08K5/17 ,  C08K7/04 ,  C08L33/02 ,  D04H1/42 ,  D04H1/58 ,  D04H1/64 ,  D06M13/02 ,  D06M13/325 ,  D06M15/263 ,  D06N3/04

Abstract: Formaldehyde-free aqueous binders containing: A) a polymer consisting of 5 t o 100 wt% of an ethylenically unsaturated acid anhydride or an ethylenically unsaturated bicarboxylic acid, the carboxylic acid groups of which can form an anhydride group, and B) an alkanol amine with at least two hydroxyl groups.

公开(公告)号：CA2217295C

公开(公告)日：2006-10-03

申请号：CA2217295

申请日：1996-04-20

Applicant: BASF AG

Inventor： MONCH DIETMAR ,  SCHUHMACHER RUDOLF ,  STANGE ANDREAS ,  DENZINGER WALTER ,  RUBENACKER MARTIN ,  LORENCAK PRIMOZ ,  NILZ CLAUDIA

IPC: C08B31/12 ,  C08F283/06 ,  C08F8/12 ,  C08F283/00 ,  C09B67/46 ,  C09D17/00 ,  D21H17/53 ,  D21H19/20 ,  D21H21/10 ,  D21H21/16 ,  D21H21/18

Abstract: Graft polymers are obtainable by free radical polymerization of (A) monomers or monomer mixtures comprising (a) from 10 to 100% by weight of N-vinylcarboxamides of the formula (see formula I), where R1 and R2 are each H or C1-C6-alkyl, (b) from 0 to 90% by weight of other monoethylenically unsaturated monomers copolymerizable with the monomers (a) and (c) from 0 to 5% by weight of monomers having at least two ethylenically unsaturated, nonconjugated double bonds in the molecule in the presence of (B) polymers which contain at least 3 units of a C2-C4-alkylene oxide, and/or polytetrahydrofurans, in a weight ratio (A) : (B) of (95 to 10) : (5 to 90) , and, if required, subsequent elimination of some or all of the groups (see formula II) from the polymerized monomers (a) of the graft polymer with formation of units of the formula (see formula III) The graft polymers can be used as dry and wet strength agents, as fixing agents fear interfering substances and fillers, as retention aids and drainage aids in the production of paper and as promoters in the diketene sizing of paper, board and cardboard, as dispersants for pigments, as starch cationizing agents and as assistants in the production of tissue papers.

公开(公告)号：CA2203931C

公开(公告)日：2006-02-21

申请号：CA2203931

申请日：1995-10-17

Applicant: BASF AG

Inventor： REUTHER WOLFGANG ,  HARTMANN HEINRICH ,  MEIXNER HUBERT ,  NILZ CLAUDIA ,  DENZINGER WALTER ,  NIESSNER MANFRED ,  LINHART FRIEDRICH ,  SCHUHMACHER RUDOLF ,  STANGE ANDREAS

IPC: C08B31/00 ,  C08L3/02 ,  D21H17/29 ,  D21H21/18

Abstract: Starch is cationically modified by reacting starch with polymers which contain amino and/or ammonium groups in an aqueous medium at from 115 to 180.degree.C under superatmospheric pressure in the absence of oxidizing agents, polymerization initiators and alkali, by a process in which the reaction is carried out in a manner such that a reduction in molecular weight occurs in not more than 10% by weight of the starch, and the reaction products thus obtainable are used as dry strength agents for paper.