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公开(公告)号：JP2000309631A
公开(公告)日：2000-11-07
申请号：JP11899499
申请日：1999-04-27
Applicant: TORAY INDUSTRIES
Inventor： OOME HIROKAZU , KUMAKI JIRO , KUMAZAWA SADANORI
Abstract: PROBLEM TO BE SOLVED: To obtain a polyester having a quality comparable or superior to that of conventional polyester while shortening the polymerization time by supplying and passing a polyester in molten state through a vertical stirring thinfilm evaporator. SOLUTION: A polyester or its oligomer is supplied to and passed through a vertical stirring thin-film evaporator in molten state to increase the polymerization degree of the polyester. Preferably, the polyester or its oligomer has an intrinsic viscosity of 0.3-1.0 before passing through the evaporator, the intrinsic viscosity of the polyester after passing through the evaporator is higher than that of the polyester before passing by >=0.1, the reaction is carried out under a pressure lower than atmospheric pressure or in an inert gas flow and the polyester is a polymer selected from among polybutylene terephthalate, polycyclohexylene dimethylene terephthalate and polyethylene terephthalate.
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公开(公告)号：JP2000212424A
公开(公告)日：2000-08-02
申请号：JP32754199
申请日：1999-11-17
Applicant: TORAY INDUSTRIES
Inventor： UTAZAKI KENICHI , NISHIMURA TORU , KUMAKI JIRO
Abstract: PROBLEM TO BE SOLVED: To provide a polyester resin composition excellent in rigidity, impact resistance, particularly appearance of its molding by improving insufficient points of a conventional polyester. SOLUTION: A polyester resin composition comprises to (A) 100 pts.wt. of a thermoplastic polyester; (B) 0.1-40 pts.wt. of a phyllosilicate wherein an exchangeable cation existing between layers is exchanged with an organic onium ion; and (C) 0.001-5 pts.wt. of at least one of a montanic acid compound and a lower molecular weight polyolefin. The composition is (A) a polybutylene terephthalate (co)polymer of a thermoplastic polyester wherein the terminal group of COOH is preferably not more than 50 eq/t and the intrinsic viscosity is 0.36-1.60.
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公开(公告)号：JP2000212422A
公开(公告)日：2000-08-02
申请号：JP32753999
申请日：1999-11-17
Applicant: TORAY INDUSTRIES
Inventor： UTAZAKI KENICHI , OOME HIROKAZU , KUMAKI JIRO
Abstract: PROBLEM TO BE SOLVED: To provide a polyester resin composition excellent in rigidity, impact resistance, particularly appearance of its molding by improving insufficient points of a conventional polyester. SOLUTION: A polyester resin composition comprises (A) 100 pts.wt. of a thermoplastic polyester; (B) 0.1-40 pts.wt. of a phyllosilicate wherein an exchangeable cation existing between layers is exchanged with an organic onium ion; (C) 0.001-5 pts.wt. of a thioether compound; and 0.001-5 pts.wt. of at least one of hindered phenol and phosphite compounds to (A) 100 pts.wt. of the thermoplastic polyester.
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公开(公告)号：JP2000212421A
公开(公告)日：2000-08-02
申请号：JP32753799
申请日：1999-11-17
Applicant: TORAY INDUSTRIES
Inventor： OOME HIROKAZU , UTAZAKI KENICHI , KUMAKI JIRO
Abstract: PROBLEM TO BE SOLVED: To obtain a reinforced polyester resin composition excellent in dimensional accuracy and moldability as well as good machine characteristics. SOLUTION: A reinforced polyester resin composition comprises (A) 100 pts.wt. of a thermoplastic resin; (B) 0.1-40 pts.wt. of a phyllosilicate wherein an exchangeable cation existing between layers is exchanged with an organic onium ion; (C) 2-100 pts.wt. of a fibrous inorganic filler; and (D) 0-100 pts.wt. of a plate-shaped inorganic material having 3-3,000 μm of an average particle size.
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公开(公告)号：JP2000136296A
公开(公告)日：2000-05-16
申请号：JP31269398
申请日：1998-11-04
Applicant: TORAY INDUSTRIES
Inventor： UTAZAKI KENICHI , KOMORI KENJI , KUMAKI JIRO
Abstract: PROBLEM TO BE SOLVED: To provide a resin composition together having good rigidity, impact resistance and flowability in good balance without deteriorating the excellent original characteristics of a polyester-based resin and thereby suitable for connectors. SOLUTION: This resin composition for connectors comprises (A) 100 pts.wt. of a polyester-based resin, (B) 0.1-80 pts.wt. of a polyester-based block copolymer comprising (b1) a polyester segment and (b2) a polyolefin-based polymer segment, and (C) 0.1-80 pts.wt. of a polyolefin. The polyolefin-based polymer segment b2 of the polyester-based block copolymer B is a block copolymer comprising a hydrogenated or non-hydrogenated aromatic vinyl and a conjugated diene, and is formed from a polyolefin having functional groups at the molecular terminals. The polyolefin C is formed from ethylene homopolymer or an ethylene copolymer with a 3-20C α-olefin.
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Patent Agency Ranking
公开(公告)号：JP2000044779A
公开(公告)日：2000-02-15
申请号：JP21920498
申请日：1998-08-03
Applicant: TORAY INDUSTRIES
Inventor： SAKAI HIDETOSHI , KUMAKI JIRO
IPC: C08K3/34 , C08K7/00 , C08L57/00 , C08L63/00 , C08L67/02 , C08L69/00 , G11B5/73 , G11B5/733 , G11B5/738
Abstract: PROBLEM TO BE SOLVED: To obtain a thermoplastic resin compsn. which is excellent in embossability, heat resistance, durability, and mechanical strengths and is suitable for cards such as magnetic cards or IC cards by compounding an amorphous polyester, an arom. polycarbonate, and a specific vinyl polymer. SOLUTION: The vinyl polymeris a (co)polymer formed from at least one vinyl monomer of formula I (wherein R1 is H or a lower alkyl; and R2 is phenyl, cyano, or an alkyl ester group having a 1-10C alkyl). A glycidyl-ester-group- contg. polymer formed by copolymerizing 99.95 wt.% at least one vinyl monomer of formula I and 0.05-60 wt.% at least one glycidyl-ester-group-contg. vinyl monomer of formula II (wherein R3 is H or a lower alkyl) can also be pref. used. Pref., the compsn. contains 2-25 pts.wt. inorg. platy filler having an average particle size of 0.5-20 μm, based on 100 pts.wt. sum of above polymers.
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公开(公告)号：JPH11315212A
公开(公告)日：1999-11-16
申请号：JP12198698
申请日：1998-05-01
Applicant: TORAY INDUSTRIES
Inventor： SAKAI HIDETOSHI , ISHII HIROMITSU , KUMAKI JIRO
IPC: C08K5/3467 , C08G63/692 , C08L67/02 , C08L101/00 , H01R13/46
Abstract: PROBLEM TO BE SOLVED: To obtain a composition which is excellent in moldability and can give a molding excellent in flame retardancy and mechanical properties, especially, a thin-wall molding excellent in toughness and heat resistance by mixing a thermoplastic resin with a thermoplastic resin containing phosphor-containing units in a specified ratio. SOLUTION: 10-99.5 pts.wt. thermoplastic resin is mixed with 0.5-90 pts.wt. thermoplastic resin containing repeating units of formula I and II and at least one type of phosphorus-containing units of any one of formulae III to VII. In the formulae, Ar is a halogen-free divalent (substituted) aromatic residue; Ar is a halogen-free trivalent (substituted) aromatic residue; R is a halogen-free divalent organic residue; R , R , R , and R are each a halogen-free monovalent (substituted) organic residue; R to R , and R are each a direct bond or a halogen-free divalent organic residue; R , R , R , R , and R are each a halogen-free monovalent organic residue; and R , R , and/or R and R may be combined with each other to form a ring or rings.
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公开(公告)号：JPH11227136A
公开(公告)日：1999-08-24
申请号：JP2874498
申请日：1998-02-10
Applicant: TORAY INDUSTRIES
Inventor： SUGIE RYUICHI , KUMAKI JIRO
Abstract: PROBLEM TO BE SOLVED: To suppress the warpage of a card due to embossing by a method wherein a lamination form, the density distribution to the direction of the thickness of inorganic flake-like filler satisfies the formulae I and II is taken. SOLUTION: In order to form a single layer sheet, a plurality of which compose a multilayer sheet, the loaidngs of an inorganic flake-like filler, the particle form of which is nonisotropic three-dimensionally and has a biaxial orientational property, is preferably 2-25 pts.wt. to 100 pts.wt. of 1 or 2 or more of thermoplastic resins selected from the group consisting of an amorphous polyester and an aromatic polycarbonate. In the multilayer sheet produced by laminating at least these two or three or more single layer sheets, when let the thickness of the multilayer sheet be 2L, the X-axis be in the direction of the thickness, the origin of the X-axis be the center of the multilayer sheet, the density of the inorganic flake-like filler at X be C(X), the single layer sheets are laminated in the form of the multilayer sheet, in which the resultant density distribution of the inorganic flake-like filler in the direction of the thickness satisfy the formulae I and II. In other words, the density distribution of the inorganic flake-like filler in the direction of the thickness is formed through such as laminating fashion that the density in the outer layer is made higher than that in the inner layer, resulting in remarkably improving the embossing characteristics of the multilayer sheet.
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公开(公告)号：JPH10306213A
公开(公告)日：1998-11-17
申请号：JP5463898
申请日：1998-03-06
Applicant: TORAY INDUSTRIES
Inventor： TOGAWA MITSUNARI , MURATA KOZO , KUMAKI JIRO
Abstract: PROBLEM TO BE SOLVED: To obtain a resin composition for an exterior part of a vehicle having excellent stiffness and tenacity simultaneously, especially excellent in surface impact destruction characteristics at a high speed, and also excellent in well- balanced surface appearance and dimensional stability of the formed product thereof. SOLUTION: This resin composition is obtained by melt-mixing 5-150 pts.wt. non-fibrous inorganic filler having 0.05-10 μm means particle diameter and/or fibrous inorganic filler having 0.05-10 μm fiber diameter other than the glass fiber and 0.05-10 pts.wt. olefinic compound having carboxylic acid anhydride group in its molecule or a polymer of the olefinic compound, based on 100 pts.wt. nylon resin.
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公开(公告)号：JPH09217015A
公开(公告)日：1997-08-19
申请号：JP2570996
申请日：1996-02-13
Applicant: TORAY INDUSTRIES
Inventor： YAMANAKA TORU , TOGAWA MITSUNARI , KUMAKI JIRO
IPC: C08J5/10 , B29B9/06 , B29B11/14 , B29C45/00 , B29D99/00 , B29K9/00 , B29K23/00 , B29K67/00 , B29K77/00 , B29K81/00 , B29K503/04 , B29L31/30 , B32B3/00 , C08K3/00 , C08K9/04 , C08L67/00 , C08L77/00 , C08L81/04 , C08L101/00
Abstract: PROBLEM TO BE SOLVED: To provide a car exterior member having excellent balance of heat resistance, rigidity and impact resistance. SOLUTION: This car exterior member is obtained by molding a resin composition composed of at least 3-components, i.e., (A) a thermoplastic resin, (B) an inorganic filler and (C) an elastic polymer having below -20 deg.C glass transition temperature. The thermoplastic resin A is used as a matrix resin and >=30% of dispersed particles of the elastic polymer C in the composition have the shape of bringing their interfaces into contact with the inorganic filler B.
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