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公开(公告)号：JP2000178392A
公开(公告)日：2000-06-27
申请号：JP28654799
申请日：1999-10-07
Applicant: TORAY INDUSTRIES
Inventor： HONMA MASATO , KIDO RYOTA , NISHIMURA TORU
Abstract: PROBLEM TO BE SOLVED: To obtain a styrene resin composition excellent in the balance between stiffness and heat resistance without detriment to impact strength, clarity, and moldability by compounding a styrene resin with a specified amount of a layered silicate which is homogeneously dispersed therein without exhibiting secondary aggregation. SOLUTION: This composition comprises 70-99.9 wt.% styrene resin and 0.1-30 wt.% layered silicate homogeneously dispersed therein without causing secondary aggregation and has a total light transmission of 60% or higher. The styrene resin has a wt. averge mol.wt. of 50,000-300,000 and an Izod impact strength of 50-200 J/m and is polystyrene, a high-impact polystyrene, an ABS resin, an MBS resin, or the like. The layered silicate has a structure wherein plates having a width of 0.05-0.5 μm and a thickness of 6-15 Å are piled up, examples being montmorillonite and hectorite. The silicate is an inclusion compound wherein interlayer exchangeable cations have been exchanged by organic onium ions (e.g. ammonium ions).
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公开(公告)号：JP2000109655A
公开(公告)日：2000-04-18
申请号：JP25257898
申请日：1998-09-07
Applicant: TORAY INDUSTRIES
Inventor： NISHIMURA TORU , KATO KIMIYA , YAMANAKA TORU
Abstract: PROBLEM TO BE SOLVED: To obtain a low-density resin compsn. excellent in stiffness, toughness, and impact resistance by melt mixing and kneading a thermoplastic polyester with a nonfibrous inorg. filler and an org. compd. having a functional group reactive with the thermoplastic polyester. SOLUTION: This compsn. is prepd. by melt mixing and kneading 100 pts.wt. thermoplastic polyester, pref. a polyalkylene terephthalate, with a nonfibrous inorg. filler, pref. a silicate compd., pref. in an amt. of 0.1-40 wt.% (in terms of inorg. ash in the compsn.) and an org. compd., pref. in an amt. of 0.05-10 pts.wt., having at least one functional group reactive with the thermoplastic polyester. Pref., the org. compd. having at least one functional group reactive with the thermoplastic polyester is an olefin compd. (polymer) having a carboxylic anhydride group. Pref., the nonfibrous inorg. filler is a layered silicate having its interlayer exchangeable cations exchanged by org. onium ions.
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公开(公告)号：JP2000063666A
公开(公告)日：2000-02-29
申请号：JP16266499
申请日：1999-06-09
Applicant: TORAY INDUSTRIES
Inventor： NISHIMURA TORU , KATO KIMIYA , YAMANAKA TORU
Abstract: PROBLEM TO BE SOLVED: To provide a polyamide resin compsn, which hardly becomes warped, is excellent in resistances to heat and impact, exhibits a small change in dimension by water absorption, and is suitable for electric pats housing, such as connectors, relay boxes, junction boxes, and fuse boxes, of automobiles. SOLUTION: This compsn. is prepd. by compounding, based on 100 pts.wt. sum of ingredients A to D, (A) 30-90 pts.wt. polyamide resin, (B) 5-40 pts.wt. inorg, silicate filler, (C) 5-40 pts.wt. olefin polymer graft-modified with an unsatd, dicarboxylic acid and/or an unsatd. dicarboxylic acid deriv., and (D) 0-40 pts.wt. olefin polymer other than ingredient C, provided at least 50% of dispersed particles of ingredient B is independently dispersed in ingredient A.
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公开(公告)号：JP2000053859A
公开(公告)日：2000-02-22
申请号：JP22503798
申请日：1998-08-07
Applicant: TORAY INDUSTRIES
Inventor： NISHIMURA TORU , KATO KIMIYA , YAMANAKA TORU
Abstract: PROBLEM TO BE SOLVED: To provide polyamide resin compositions composed of a polyamide resin and a lamellar silicate salt which are excellent in strength and rigidity and possess both toughness and ductility. SOLUTION: The objective polyamide resin compositions are obtained by melt kneading (a) a polyamide resin with (b) a lamellar silicate salt whose exchangeable cations present between the layers have been exchanged with organic onium ions, and have a ratio of the concentration A of the terminal amino groups of the polyamide resin (a) to that B of the terminal carboxy groups of the polyamide resin (a) of not less than 0.9.
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公开(公告)号：JP2000053847A
公开(公告)日：2000-02-22
申请号：JP22503698
申请日：1998-08-07
Applicant: TORAY INDUSTRIES
Inventor： NISHIMURA TORU , KATO KIMIYA , YAMANAKA TORU
Abstract: PROBLEM TO BE SOLVED: To obtain a composition excellent in a balance between rigidity and toughness and capable of weight reduction by melt-kneading a thermoplastic polyester having a specified terminal carboxy content and a layered silicate derived by exchanging the exchangeable cations present among layers for organic onium ions. SOLUTION: The thermoplastic polyester has a terminal carboxy content of 10-80 eq/t and is particularly desirably polybutylene terephthalate, polyethylene terephthalate, polyethylene-2,6-naphthalenedicarboxylate, or the like. The organic onium ions are desirably ammonium ions or phosphonium ions between which the former ions are particularly desirable. Among the ammonium ions, phenyl-containing ammonium ions are particularly desirable. The content of the layered silicate is usually 0.1-40 wt.% (in terms of the inorganic ash content in the composition).
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Patent Agency Ranking
公开(公告)号：JPH11335554A
公开(公告)日：1999-12-07
申请号：JP14630398
申请日：1998-05-27
Applicant: TORAY INDUSTRIES
Inventor： NISHIMURA TORU , KATO KIMIYA , YAMANAKA TORU
Abstract: PROBLEM TO BE SOLVED: To provide with ease a polyamide resin compsn. which comprises a polyamide resin and a layered silicate and has a low specific gravity and an excellent stiffness. SOLUTION: This compsn. is prepd. by melt-kneading 65-99.8 pts.wt. polyamide resin, 0.1-20 pts.wt. layered silicate, and 0.1-15 pts.wt. org. onium salt, and sum of all the ingredients being 100 pts.wt. The melt-kneading is conducted at a temp. which is not lower than the 10% wt. loss temp. but no higher than the 90 %.wt. loss temp. of the org. onium salt.
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公开(公告)号：JPH10100356A
公开(公告)日：1998-04-21
申请号：JP21031997
申请日：1997-08-05
Applicant: TORAY INDUSTRIES
Inventor： SUGIE RYUICHI , NISHIMURA TORU , HIRATSUKA MOTONORI
Abstract: PROBLEM TO BE SOLVED: To provide a multilayered polyester sheet capable of being thermally fused at practical temp. of about 110-150 deg.C in spite of its high heat resistance. SOLUTION: This multilayered polyester sheet is obtained by laminating two or more sheets and at least one layer is constituted of a sheet A composed of a resin compsn. consisting of polyester (A-1) composed of a glycol unit based on dicarboxylic acid unit based on a terephthalic acid unit and ethylene glycol unit (I) and a glycol unit based on 1,4-cyclohexanedimethanol unit (II) and characterized by that a mol ratio (I)/(II) of the ethylene glycol unit (I) and a 1,4- cyclohexanedimethanol unit (II) is 1 or more and aromatic polycarbonate (A-2).
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公开(公告)号：JPH09143348A
公开(公告)日：1997-06-03
申请号：JP4769596
申请日：1996-03-05
Applicant: TORAY INDUSTRIES
Inventor： NISHIMURA TORU , UTAZAKI KENICHI , HIRATSUKA MOTONORI
Abstract: PROBLEM TO BE SOLVED: To obtain a molded item which does not undergo degradation in strengths or toughness at high temp. and humidity by using a polyester resin compsn. prepd. by melt mixing a polyolefin with an unsatd. carboxylic acid and mixing the resultant mixture in a molten state with a thermoplastic polyester. SOLUTION: This resin compsn. is prepd. by melt mixing a polyolefin with an unsatd. carboxylic acid (deriv.) and mixing the resultant mixture in a molten state with a thermoplastic polyester. The polyolefin is an α-olefin (co)polymer and is pref. selected from among polyethylene, polypropylene, and an EP rubber. The acid is pref. an anhydride such as maleic anhydride. An esp. prepf. example of the polyester is polybutylene terephthalate. A thermoplastic polyester having an intrinsic viscosity of 0.52-1.35dl/g is suitable in terms of mechanical strengths and moldability. If necessary, a thermoplastic polyester, which may be the same as or different from one described above, may be further mixed into the compsn. Thus prepd. compsn. is suitable for a thin-walled molded item and is useful for a molded item having a hinge part, esp. for a wire harness connector.
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公开(公告)号：JPH07300562A
公开(公告)日：1995-11-14
申请号：JP4458395
申请日：1995-03-03
Applicant: TORAY INDUSTRIES
Inventor： OKITA SHIGERU , MATSUOKA HIDEO , NISHIMURA TORU
IPC: C08K3/00 , C08K5/13 , C08K5/3477 , C08L67/00 , C08L67/02 , C08L71/08 , C08L71/10 , C08L71/12 , C08L81/02 , C08L85/02 , C08L101/00
Abstract: PURPOSE:To obtain a thermoplastic resin composition having a high degree of flame retardancy and satisfactory in moldability, hydrolytic resistance, and mechanical properties by using a combination of specific compounds. CONSTITUTION:100 pts.wt. thermoplastic resin is mixed with 1-100 pts.wt. aromatic polyphosphate represented by formula I [wherein R is H or a 1-5C alkyl; Ar to Ar each us phenyl or a phenyl substituted with a halogen-free organic group; 5 to R each is H, an aryl, an alkyl, an aralkyl, a cycloalkyl, or -CONH2 and R is -N RR , -NR R , H, an aryl, an alkyl, an aralkyl, a cycloalkyl, -NH2, or -CONH2).
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公开(公告)号：JPH0718178A
公开(公告)日：1995-01-20
申请号：JP16560693
申请日：1993-07-05
Applicant: TORAY INDUSTRIES
Inventor： NISHIMURA TORU , OSANAWA NOBUO , IWAMOTO MASAAKI
Abstract: PURPOSE:To obtain the subject part, excellent in low water absorptivity, calcium chloride resistance, rigidity, heat resistance and mechanical strength by molding a blend containing a specific polyamide resin, a specified aliphatic compound and a specific inorganic filler in a specified proportion. CONSTITUTION:The objective part is obtained by molding a blend comprising (A) 100 pts.wt. polyamide resin containing caproamide and/or hexamethylene adipamide as main constituent units, (B) 0.5-10 pts.wt. aliphatic compound having one or more carboxylic acid groups and/or carboxylic acid derivative groups in the molecule, 400-10000 number-average molecular weight and 50-200 sum total of the saponification value and the acid value such as heptacosanoic acid and (C) 0-100 pts.wt. inorganic reinforcing material such as glass fiber.
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