公开(公告)号：EP2294296A2

公开(公告)日：2011-03-16

申请号：EP09773987.4

申请日：2009-06-02

Applicant: H R D Corporation

Inventor： HASSAN, Abbas ,  ANTHONY, Rayford, G. ,  BORSINGER, Gregory ,  HASSAN, Aziz ,  BAGHERZADEH, Ebrahim

IPC: F02B45/10 ,  B01F3/00 ,  B01F7/16 ,  C10L1/32

CPC classification number: F02B43/00 ,  C10L1/32 ,  F02M29/02

Abstract: Use of a high shear mechanical device in a process to produce aerated fuels for efficient combustion in an engine. In instances, the method comprises forming an emulsion of a gas and liquid fuel in a high shear device prior to introduction to an engine. A vehicular system for producing aerated fuels comprising a high shear device.

公开(公告)号：EP2181090A2

公开(公告)日：2010-05-05

申请号：EP08771704.7

申请日：2008-06-23

Applicant: H R D Corporation

Inventor： HASSAN, Abbas ,  BAGHERZADEH, Ebrahim ,  ANTHONY, Rayford, G. ,  BORSINGER, Gregory ,  HASSAN, Aziz

IPC: C07C263/10 ,  B01F7/26

CPC classification number: C07C263/10 ,  B01F7/00766 ,  B01F13/1013 ,  B01F13/1016 ,  C07C265/14

Abstract: A method for producing toluene diisocyanate is disclosed which comprises forming a dispersion comprising phosgene gas bubbles dispersed in toluene diamine liquid phase, wherein said gas bubbles have a mean diameter less than 1 micron; and subjecting the dispersion to phosgenation reaction conditions, whereby at least a portion of the toluene diamine is phosgenated to form toluene diisocyanate. A system for carrying out the phosgenation of toluene diamine is also disclosed.

公开(公告)号：EP2170790A1

公开(公告)日：2010-04-07

申请号：EP08771946.4

申请日：2008-06-25

Applicant: H R D Corporation

Inventor： HASSAN, Abbas ,  BAGHERZADEH, Ebrahim ,  ANTHONY, Rayford G. ,  BORSINGER, Gregory ,  HASSAN, Aziz

IPC: C07C29/141 ,  C07C1/207 ,  C07C27/00 ,  B01F7/26

CPC classification number: B01J19/1806 ,  B01F7/00766 ,  B01F13/1027 ,  B01F2215/0481 ,  B01J8/025 ,  B01J8/20 ,  B01J19/0066 ,  B01J19/1862 ,  B01J2219/00006 ,  B01J2219/00779 ,  C07C29/141 ,  C07C29/145 ,  C07C31/02

Abstract: Methods and systems for the hydrogenation of aldehydes and/or ketones are described herein. The methods and systems incorporate the novel use of a high shear device to promote dispersion and solubility of the hydrogen-containing gas (e.g. H2 gas) in the aldehydes and/or ketones. The high shear device may allow for lower reaction temperatures and pressures and may also reduce hydrogenation time with existing catalysts.

公开(公告)号：EP2155641A2

公开(公告)日：2010-02-24

申请号：EP08771913.4

申请日：2008-06-25

Applicant: H R D Corporation

Inventor： HASSAN, Abbas ,  BAGHERZADEH, Ebrahim ,  ANTHONY, Rayford G. ,  BORSINGER, Gregory ,  HASSAN, Aziz

IPC: C07C31/34 ,  C07C29/64 ,  B01F7/26 ,  B01F1/00

CPC classification number: C07C29/66 ,  B01F7/00766 ,  B01F13/1013 ,  B01F13/1016 ,  C07C31/42

Abstract: Methods and systems for the preparation of chlorohydrins are described herein. The methods and systems incorporate the novel use of a high shear device to promote dispersion and solubility of olefins into the chlorinating phase. The high shear device may allow for lower reaction temperatures and pressures and may also reduce chlorination time.

公开(公告)号：EP2114173A2

公开(公告)日：2009-11-11

申请号：EP08771702.1

申请日：2008-06-23

Applicant: H R D Corporation

Inventor： HASSAN, Abbas ,  BAGHERZADEH, Ebrahim ,  ANTHONY, Rayford, G. ,  BORSINGER, Gregory ,  HASSAN, Aziz

IPC: A23L1/0522 ,  A23L1/187 ,  C08B30/00 ,  B01F7/26

CPC classification number: C08B30/04 ,  B01F7/00766 ,  B01F13/1013 ,  B01F13/1016 ,  C08B30/044

Abstract: Use of a high shear mechanical device in a process for production of starch by hydration and disruption of corn kernel particles in the presence of sulfur dioxide or bisulfite ions makes possible a decrease in mass transfer limitations, thereby enhancing starch production. A system for production of starch is also provided in which a high shear mixing device is configured to receive an aqueous corn slurry from a pump that is disposed between the reactor and a gaseous sulfur dioxide inlet of the high shear mixing device. The high shear mixing device is also configured to generate a fine dispersion of sulfur dioxide bubbles and small corn particles in the slurry. A reactor is configured to receive the output from the high shear mixing device and to provide for starch production.

公开(公告)号：WO2014116270A1

公开(公告)日：2014-07-31

申请号：PCT/US2013/029826

申请日：2013-03-08

Applicant: H R D CORPORATION

Inventor： HASSAN, Abbas ,  HASSAN, Aziz ,  ANTHONY, Rayford, G. ,  BORSINGER, Gregory

IPC: C10G45/02 ,  C10G45/04

CPC classification number: C10G45/00 ,  B01F7/00766 ,  B01F13/1016 ,  B01J8/222 ,  B01J10/002 ,  B01J19/0066 ,  B01J19/1806 ,  B01J2219/0004 ,  B01J2219/00189 ,  C10G1/065 ,  C10G45/02 ,  C10G45/16 ,  C10G45/22 ,  C10G47/00 ,  C10G47/26 ,  C10G47/34 ,  C10G49/007 ,  Y10T137/0318

Abstract: Herein disclosed is a method for hydrogenation comprising: supersaturating a hydrocarbonaceous liquid or slurry stream in a high shear device with a gas stream comprising hydrogen and optionally one or more C1-C6 hydrocarbons to form a supersaturated dispersion; and introducing the supersaturated dispersion into a reactor in the presence of a hydrogenation catalyst to generate a product stream. In some embodiments, the catalyst is present as a slurry or a fluidized or fixed bed of catalyst. In some embodiments, the hydrogenation catalyst is mixed with the hydrocarbonaceous liquid or slurry stream and the gas stream in the high shear device. In some embodiments, the method further comprises recycling at least a portion of an off gas from the reactor, recycling at least a portion of the product stream from the reactor, or both. Also disclosed herein is a system for hydrogenation.

Abstract translation: 本文公开了一种氢化方法，其包括：在高剪切装置中用含有氢气和任选的一种或多种C 1 -C 6烃的气流来过饱和烃类液体或浆料流以形成过饱和分散体; 并在加氢催化剂的存在下将过饱和分散体引入反应器中以产生产物流。 在一些实施方案中，催化剂作为浆料或催化剂的流化床或固定床存在。 在一些实施方案中，氢化催化剂与烃类液体或浆料流以及高剪切装置中的气流混合。 在一些实施方案中，该方法还包括将来自反应器的废气的至少一部分再循环，将来自反应器或两者的至少一部分产物流循环。 本文还公开了一种用于氢化的体系。

公开(公告)号：WO2013142513A3

公开(公告)日：2013-09-26

申请号：PCT/US2013/033003

申请日：2013-03-19

Applicant: H R D CORPORATION

Inventor： HASSAN, Abbas ,  HASSAN, Aziz ,  ANTHONY, Rayford G. ,  HASSAN, Alishah

IPC: B01J19/18 ,  B01F7/16

Abstract: A system for converting a first substance into a second substance, the system including a mixing reactor configured to provide a reactant mixture comprising a first reactant, a second reactant, and a solvent; and a high shear device fluidly connected to the mixing reactor, wherein the high shear device comprises at least one rotor/stator set comprising a rotor and a complementarily-shaped stator symmetrically positioned about an axis of rotation and separated by a shear gap, wherein the shear gap is in the range of from about 10 microns to about 250 microns; and a motor configured for rotating the rotor about the axis of rotation, whereby energy can be transferred from the rotor to the reactants thereby inducing reactions between the first reactant and the second reactant to form a product.

公开(公告)号：WO2011109465A2

公开(公告)日：2011-09-09

申请号：PCT/US2011/026789

申请日：2011-03-02

Applicant: H R D CORPORATION ,  HASSAN, Abass ,  HASSAN, Aziz ,  ANTHONY, Rayford, G. ,  BORSINGER, Greg, G.

Inventor： HASSAN, Abass ,  HASSAN, Aziz ,  ANTHONY, Rayford, G. ,  BORSINGER, Greg, G.

CPC classification number: B01J19/1806 ,  B01F7/00766 ,  B01F13/1013 ,  B01F13/1027 ,  C07C17/10 ,  C07C303/06 ,  C07C19/01 ,  C07C309/62

Abstract: A method for halogenating, sulfonating, or sulfo-halogenating a feed comprising paraffin, by subjecting a mixture comprising the feed and a reagent selected from the group consisting of sulfonating agents, halogenating agents, and combinations thereof to a shear rate of at least 20,000s -1 to produce a high-shear treated product; cooling the high shear-treated product by heat exchange with a heat transfer medium, to produce a cooled product; and separating the high shear-treated product into an offgas and a liquid product comprising at least one selected from the group consisting of sulfonated paraffins, halogenated paraffins, and sulfo-halogenated paraffins. A high shear system for the production of halogenated, sulfonated, or sulfo-halogenated paraffin is also provided.

Abstract translation: 通过将包含所述原料的混合物和选自磺化剂，卤化剂及其组合的试剂的混合物的至少20,000s的剪切速率进行卤化，磺化或磺基卤化包含石蜡的进料的方法 -1以产生高剪切处理产物; 通过与传热介质的热交换来冷却高剪切处理的产品，以产生冷却的产品; 以及将所述高剪切处理的产物分离成废气和包含选自磺化链烷烃，卤化链烷烃和磺基卤代链烷烃中的至少一种的废气和液体产物。 还提供了用于生产卤化，磺化或磺基卤代石蜡的高剪切系统。

公开(公告)号：WO2011044194A2

公开(公告)日：2011-04-14

申请号：PCT/US2010/051569

申请日：2010-10-06

Applicant: H R D CORPORATION ,  HASSAN, Abbas ,  HASSAN, Aziz ,  ANTHONY, Rayford, G. ,  BORSINGER, Gregory, G.

Inventor： HASSAN, Abbas ,  HASSAN, Aziz ,  ANTHONY, Rayford, G. ,  BORSINGER, Gregory, G.

IPC: C12N1/12 ,  C12M3/02 ,  C12M1/04 ,  C12P7/06 ,  C12P5/02

CPC classification number: C12M21/12 ,  C12M21/02 ,  C12M45/02 ,  C12N1/066 ,  C12N1/12 ,  Y02E50/17

Abstract: A method for culturing algae comprising, forming an emulsion comprising a gaseous stream and a media utilizing a high shear device, wherein the emulsion comprises gas bubbles, and wherein the high shear device comprises at least one toothed rotor and at least one stator; introducing the emulsion into a bioreactor; and introducing an algae into the bioreactor for growing the algae culture. Additionally, a method for producing liquids from an algae culture, the method comprising forming an emulsion comprising a buffer and algal components, wherein the emulsion comprises algal component globules; separating algal hydrocarbons; and processing algal hydrocarbons to form liquid hydrocarbons. Additionally, a system for producing liquids from an algae culture comprising at least one high shear device.

Abstract translation: 一种用于培养藻类的方法，包括：使用高剪切装置形成包含气流的乳液和介质，其中所述乳液包括气泡，并且其中所述高剪切装置包括至少一个齿形转子和至少一个定子; 将乳液引入生物反应器; 并将藻类引入用于生长藻类培养物的生物反应器中。 另外，一种从藻类培养物生产液体的方法，所述方法包括形成包含缓冲液和藻类成分的乳液，其中所述乳液包含藻类组分球; 分离藻类碳氢化合物; 并处理藻类碳氢化合物以形成液态烃。 另外，一种用于从包含至少一个高剪切装置的藻类培养物生产液体的系统。

公开(公告)号：WO2010002534A2

公开(公告)日：2010-01-07

申请号：PCT/US2009/045967

申请日：2009-06-02

Applicant: H R D CORPORATION ,  HASSAN, Abbas ,  ANTHONY, Rayford, G. ,  BORSINGER, Gregory ,  HASSAN, Aziz ,  BAGHERZADEH, Ebrahim

Inventor： HASSAN, Abbas ,  ANTHONY, Rayford, G. ,  BORSINGER, Gregory ,  HASSAN, Aziz ,  BAGHERZADEH, Ebrahim

IPC: B01J8/04 ,  B01J8/10 ,  B01J19/28

CPC classification number: B01J19/1806 ,  B01F7/00766 ,  B01F7/00791 ,  B01F13/1013 ,  B01F13/1016 ,  B01J8/20 ,  B01J8/22 ,  B01J10/007 ,  B01J14/005 ,  B01J19/008 ,  B01J2219/00105 ,  B01J2219/1941 ,  C07C29/04 ,  C07C29/106 ,  C07C45/34 ,  C07C45/39 ,  C07C51/265 ,  C07C67/08 ,  C07C209/36 ,  C07C2601/16 ,  C12C11/02 ,  C07C31/22 ,  C07C31/225 ,  C07C35/14 ,  C07C31/202 ,  C07C31/207 ,  C07C31/205 ,  C07C47/06 ,  C07C49/04 ,  C07C49/08 ,  C07C63/06 ,  C07C69/003 ,  C07C211/46 ,  C07C211/50 ,  C07C69/14

Abstract: A reactor comprising at least one contact surface made from, coated with, or impregnated by a catalyst, wherein the contact surface comprises a sintered metal or a ceramic, and wherein the reactor is configured to subject a reactant stream to shear. A system for carrying out a heterogeneously catalyzed reaction, the system comprising a reactor as described above and a pump configured for delivering reactants to the at least one reactor. A method for carrying out a heterogeneously-catalyzed reaction by introducing reactants into a reactor comprising at least one contact surface made from, coated with, or impregnated by a catalyst under conditions which promote production of a desired product, wherein the contact surface comprises a sintered metal or a ceramic, and forming a dispersion of reactants within the reactor, wherein the dispersion comprises droplets or gas bubbles of reactant with an average diameter of less than about 5um.

Abstract translation: 一种反应器，包括由催化剂制成，涂覆或浸渍的至少一个接触表面，其中所述接触表面包括烧结金属或陶瓷，并且其中所述反应器构造成使反应物流受到剪切。 一种用于进行非均相催化反应的系统，该系统包括如上所述的反应器和构造成将反应物输送到至少一个反应器的泵。 一种通过将反应物引入反应器中进行非均相催化反应的方法，所述反应器包括在促进所需产物生产的条件下由催化剂制备，涂覆或浸渍的至少一个接触表面，其中所述接触表面包括烧结 金属或陶瓷，并且在反应器内形成反应物的分散体，其中分散体包含平均直径小于约5um的反应物的液滴或气泡。