公开(公告)号：CA2337858A1

公开(公告)日：2000-02-03

申请号：CA2337858

申请日：1999-07-02

Applicant: BASF AG

Inventor： VOIT GUIDO ,  ACHHAMMER GUNTHER ,  MERGER MARTIN ,  REHFINGER ALWIN ,  MELDER JOHANN-PETER ,  FISCHER ROLF ,  OHLBACH FRANK ,  LUYKEN HERMANN ,  ANSMANN ANDREAS ,  BASSLER PETER

IPC: C07B61/00 ,  C07C209/48 ,  C07C209/84 ,  C07C209/86 ,  C07C211/12 ,  C07C253/30 ,  C07C253/34 ,  C07C255/24

Abstract: The invention relates to a method for simultaneous production of 6- aminocapronitrile and hexamethylenediamine from adipodinitrile, comprising t he following steps: a) hydrogenating adipodinitrile in the presence of a cataly st containing an element of the VIII subgroup thereby obtaining a mixture containing 6-aminocapronitrile, hexamethylenediamine, adipodinitrile and hig h boilers; b) distillative separation of hexamethylenediamine from the mixture containing 6-aminocapronitrile, hexamethylenediamine, adipodinitrile and hig h boilers or c1) distillative separating 6-aminocapronitrile and subsequently d1) distillative separation of adipodinitrile or c2) simultaneous distillati ve separation of 6-aminocapronitrile and adipodinitrile into separate fractions . The invention is characterized in that temperatures in the bottoms of the column in steps d1) or c2) are under 185 ~C. The adipodinitrile thus obtaine d contains less impurities than for instance 1-amino-2-cyanocyclopentenes.

公开(公告)号：DE19832529A1

公开(公告)日：2000-01-27

申请号：DE19832529

申请日：1998-07-20

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  OHLBACH FRANK ,  ANSMANN ANDREAS ,  BASLER PETER ,  FISCHER ROLF ,  MELDER JOHANN-PETER ,  MERGER MARTIN ,  REHFINGER ALWIN ,  VOIT GUIDO ,  ACHHAMMER GUENTHER

IPC: C07B61/00 ,  C07C209/48 ,  C07C209/84 ,  C07C209/86 ,  C07C211/12 ,  C07C253/30 ,  C07C253/34 ,  C07C255/24 ,  C07C209/82

Abstract: A process for the simultaneous production of 6-amino-capronitrile (ACN) and hexamethylenediamine (HDA) by hydrogenation of adiponitrile (ADN) in which, after separation of HDA by distillation, the ACN and ADN are separated in succession or simultaneously (in separate fractions) with a bottom temperature below 185 deg C. A process for the simultaneous production of ACN and HDA from ADN comprises (a) hydrogenation of ADN in presence of a catalyst based on a Subgroup VIII element to give a mixture containing ACN, HDA, ADN and high-boiling products, (b) separation of HDA from the mixture by distillation, (c1) separation of ACN by distillation and then (d1) separation of ADN by distillation or (c2) simultaneous separation of ACN and ADN in separate fractions. Distillation stage (d1) or (c2) is carried out with a bottom temperature below 185 deg C.

公开(公告)号：CA2322530A1

公开(公告)日：1999-09-10

申请号：CA2322530

申请日：1999-02-23

Applicant: BASF AG

Inventor： MERGER MARTIN ,  REHFINGER ALWIN ,  FISCHER ROLF HARTMUTH ,  BASSLER PETER ,  ANSMANN ANDREAS ,  OHLBACH FRANK ,  VOIT GUIDO ,  LUYKEN HERMANN

IPC: B01J23/02 ,  B01J23/78 ,  C07B61/00 ,  C07C209/00 ,  C07C209/48 ,  C07C211/09 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: The invention relates to a method for hydrogenating aliphatic alpha-, omegadinitriles in the presence of a heterogeneous fixed-bed catalyst. The method is characterised in that the reaction mixture contains 2 .mu.mol to 30 mmol Na, K, Rb, Cs, Mg, Ca, Sr, Ba or Mn or mixtures thereof in the form of a basic salt, in relation to 10 mol of the aliphatic alpha-, omega-dinitrile used.

公开(公告)号：DE19809688A1

公开(公告)日：1999-09-09

申请号：DE19809688

申请日：1998-03-06

Applicant: BASF AG

Inventor： VOIT GUIDO ,  FISCHER ROLF HARTMUTH ,  BASLER PETER ,  ANSMANN ANDREAS ,  LUYKEN HERMANN ,  MERGER MARTIN ,  OHLBACH FRANK ,  REHFINGER ALWIN

IPC: B01J23/78 ,  B01J23/745 ,  C07B61/00 ,  C07C209/48 ,  C07C211/09 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24 ,  C07C255/04 ,  C07C253/10

Abstract: The invention relates to a method for producing aliphatic alpha-, omega-diamines by hydrogenating aliphatic alpha-, omega-dinitriles in the presence of a catalyst, characterised in that the catalyst used for the hydrogenation contains a) iron or a compound based on iron or mixtures thereof, b) 0.001 to 0.3 wt. % in relation to a) of a promoter based on 2, 3, 4 or 5 elements from the following group: aluminium, silicon, zirconium, titanium and vanadium and c) 0 to 0.3 wt. % in relation to a) of a compound based on an alkaline and/or alkaline earth metal.

公开(公告)号：BR9711729A

公开(公告)日：1999-08-24

申请号：BR9711729

申请日：1997-08-28

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  REHFINGER ALWIN ,  BASSLER PETER ,  VOIT GUIDO ,  FISCHER ROLF ,  MERGER MARTIN ,  RUST HARARLD

IPC: C07C209/86 ,  C07C211/12 ,  C07C211/36

Abstract: A process for separating 2-aminomethylcyclopentylamine from a mixture consisting of hexamethylenediamine and 2-aminomethylcyclopentylamine by distilling the mixture at a pressure from 1 to 300 mbar.

公开(公告)号：TR9900517T2

公开(公告)日：1999-07-21

申请号：TR9900517

申请日：1997-08-28

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  REHFINGER ALWIN ,  BASSLER PETER ,  VOIT GUIDO ,  FISCHER ROLF ,  MERGER MARTIN ,  RUST HARALD

IPC: C07C209/86 ,  C07C211/12 ,  C07C211/36

CPC classification number: C07C209/86 ,  C07C211/36 ,  C07C2601/08 ,  Y10S203/11 ,  C07C211/12

公开(公告)号：ID18458A

公开(公告)日：1998-04-09

申请号：ID973145

申请日：1997-09-10

Applicant: BASF AG

Inventor： EBEL KLAUS ,  FISCHER ROLF ,  FLICK KLEMENS ,  MERGER MARTIN ,  VOIT GUIDO

IPC: B01J23/78 ,  C07B61/00 ,  C07C209/48 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24 ,  C07C253/00

Abstract: A process for preparing aliphatic alpha,omega-amino nitrites by partial hydrogenation of aliphatic alpha,omega-dinitriles in the presence of a catalyst, wherein the catalyst used for the partial hydrogenation comprises(a) iron or a compound based on iron or mixtures thereof and(b) from 0.01 to 5% by weight, based on (a), of a promoter based on 2,3,4 or 5 elements selected from the group consisting of aluminum, silicon, zirconium, titanium and vanadium and(c) from 0 to 5% by weight, based on (a), of a compound based on an alkali metal or alkaline earth metal.

公开(公告)号：AU4456397A

公开(公告)日：1998-04-02

申请号：AU4456397

申请日：1997-08-28

Applicant: BASF AG

Inventor： LUYKEN HERMANN ,  REHFINGER ALWIN DR ,  BASSLER PETER ,  VOIT GUIDO ,  FISCHER ROLF ,  MERGER MARTIN ,  RUST HARALD

IPC: C07C209/86 ,  C07C211/12 ,  C07C211/36

Abstract: A process for separating 2-aminomethylcyclopentylamine from a mixture consisting of hexamethylenediamine and 2-aminomethylcyclopentylamine by distilling the mixture at a pressure from 1 to 300 mbar.

公开(公告)号：CA2342177C

公开(公告)日：2008-12-23

申请号：CA2342177

申请日：1999-08-17

Applicant: BASF AG

Inventor： BASSLER PETER ,  LUYKEN HERMANN ,  OHLBACH FRANK ,  ACHHAMMER GUNTHER ,  MELDER JOHANN-PETER ,  VOIT GUIDO ,  FISCHER ROLF ,  REHFINGER ALWIN ,  MERGER MARTIN ,  ANSMANN ANDREAS

IPC: C07C253/30 ,  C07B61/00 ,  C07C209/48 ,  C07C209/84 ,  C07C211/12 ,  C07C253/34 ,  C07C255/24

Abstract: The invention relates to a method for simultaneous preparation of 6- aminocapronitrile and hexamethylene diamine from adipodinitrile, comprising the following steps: a) hydrogenating adipodinitrile in the presence of a catalyst containing an element of the eight subgroup as catalytically active component to obtain a mixture containing 6- aminocapronitrile, hexamethylene diamine, adipodinitrile and high boilers; b) separating by distillation hexamethylene diamine from the mixture containing 6-aminocapronitrile, hexamethylene diamine, adipodinitrile and high boilers and c1) separating by distillation 6-aminocapronitrile and subsequently dl) separating by distillation adipodinitrile or c2) simultaneously separating by distillation 6-aminocapronitrile and adipodinitrile into separate fractions. The method is characterized in that the temperature of the bottom in steps d1) or c2) is below 185 .degree. C.

公开(公告)号：MY124248A

公开(公告)日：2006-06-30

申请号：MYPI9900816

申请日：1999-03-05

Applicant: BASF AG

Inventor： VOIT GUIDO ,  FISCHER ROLF ,  BASSLER PETER ,  ANSMANN ANDREAS ,  LUYKEN HERMANN ,  MERGER MARTIN ,  OHLBACH FRANK ,  ALWIN REHFINGER DR

IPC: B01J23/78 ,  C07C209/00 ,  B01J23/745 ,  C07B61/00 ,  C07C209/48 ,  C07C211/09 ,  C07C211/12 ,  C07C253/30 ,  C07C255/24

Abstract: A PROCESS FOR PREPARING ALIPHATIC ALPHA, OMEGA-DIAMINES BY HYDROGENATION OF ALIPHATIC ALPHA, OMEGA-DINITRILES IN THE PRESENCE OF A CATALYST COMPRISES USING A HYDROGENATION CATALYST COMPRISING (A) IRON OR A COMPOUND BASED ON IRON OR MIXTURES THEREOF, (B) FROM 0.001 TO 0.3% BY WEIGHT BASED ON (A) OF A PROMOTOR BASED ON 2,3,4 OR 5 ELEMENTS SELECTED FROM THE GROUP CONSISTING OF ALUMINUM, SILICON, ZIRCONIUM, TITANIUM AND VANADIUM, AND ALSO(C) FROM 0 TO 0.3% BY WEIGHT BASED ON (A) OF A COMPOUND BASED ON AN ALKAKI AND/OR ALKALINE EARTH METAL.