公开(公告)号：CA2263959A1

公开(公告)日：1998-01-29

申请号：CA2263959

申请日：1997-07-14

Applicant: EXXON CHEMICAL PATENTS INC

Inventor： GINDELBERGER DAVID EDWARD ,  ROSSI ALBERT ,  STANAT JON EDMOND ,  EMERT JACOB ISAAC ,  STOKES JAMES PETER ,  SHER JAIMES

IPC: C08F210/00 ,  C10L1/195 ,  C10L1/198 ,  C10L1/236 ,  C10L1/238 ,  C10L1/24 ,  C10L1/30 ,  C10L10/00 ,  C10M145/04 ,  C10M145/14 ,  C10M149/04 ,  C10M149/06 ,  C10M157/00 ,  C10N30/04 ,  C10N40/25 ,  C10L1/18 ,  C10L1/22 ,  C10M149/14 ,  C10M177/00

Abstract: Polar monomer-containing copolymers derived from at least one .alpha., .beta. unsaturated carbonyl compound, such as alkyl acrylates and one or more olefins, such olefins including ethylene and C3-C20 .alpha.-olefins such as propylene and 1-butene, which copolymers have (a) an average ethylene sequence length, ESL, of from about 1.0 to less than about 3.0; (b) an average of at least 5 branches per 100 carbon atoms of the copolymer chains comprising the copolymer; (c) at least about 50 % of said branches being methyl and/or ethyl branches; (d) substantially all of said incorporated polar monomer is present at the terminal position of said branches; (e) at least about 30 % of said copolymer chains terminated with a vinyl or vinylene group; (f) a number average molecular weight, Mn, of from about 300 to about 15,000 when the copolymer is intended for dispersant or wax crystal modifier uses and up to about 500,000 where intended for viscosity modifier uses; and (g) substantial solubility in hydrocarbon and/or synthetic base oil. The copolymers are produced using late-transition-metal catalyst systems and, as an olefin monomer source other than ethylene preferably inexpensive, highly dilute refinery or steam cracker feed streams that have undergone only limited cleanup steps. Fuel and lubricating oil additives, particularly dispersants, wax crystal modifiers and flow improvers, are produced. Where functionalization and derivatization of these copolymers are required for such additives it is facilitated by the olefinic structures available in the copolymer chains.

公开(公告)号：CA2251599A1

公开(公告)日：1997-11-20

申请号：CA2251599

申请日：1996-05-16

Applicant: EXXON CHEMICAL PATENTS INC

Inventor： GUTIERREZ ANTONIO ,  SONG WON R ,  WELBORN HOWARD C ,  ROSSI ALBERT ,  KLEIST ROBERT A ,  TURNER HOWARD W ,  LUNDBERG ROBERT D

IPC: C10L1/192 ,  C08F4/64 ,  C08F8/00 ,  C08F8/24 ,  C08F8/42 ,  C08F8/46 ,  C08F210/02 ,  C08F210/16 ,  C08F210/18 ,  C08F220/02 ,  C08F222/02 ,  C08L23/26 ,  C10L20060101 ,  C10L1/14 ,  C10L1/16 ,  C10L1/18 ,  C10L1/196 ,  C10L1/198 ,  C10L1/20 ,  C10L1/22 ,  C10L1/238 ,  C10L1/24 ,  C10L1/26 ,  C10L1/30 ,  C10L10/00 ,  C10L10/08 ,  C10L10/18 ,  C10M129/93 ,  C10M129/95 ,  C10M133/52 ,  C10M133/56 ,  C10M143/00 ,  C10M143/02 ,  C10M143/08 ,  C10M145/00 ,  C10M145/02 ,  C10M145/10 ,  C10M159/12 ,  C10M161/00 ,  C10M171/00 ,  C10N20/02 ,  C10N20/04 ,  C10N30/04 ,  C10N40/25

Abstract: The present invention is directed to an oil-soluble lubricating oil additive comprising at least one terminally unsaturated ethylene/alpha-olefin/diene interpolymer of 300 to 20,000 number average molecular weight substituted with mono- or dicarboxylic acid producing moieties (preferably dicarboxylic acid or anhydride moieties), wherein the terminal unsaturation comprises terminal ethenylidene unsaturation. The mono- and dicarboxylic acid or anhydride substituted interpolymers of this invention are useful per se as additives to lubricating oils, and can also be reacted with a nucleophilic reagent, such as amines, alcohols, amino alcohols and reactive metal compounds, to form products which are also useful lubricating oil additives, e.g., as dispersants.

公开(公告)号：BR9507915A

公开(公告)日：1997-08-12

申请号：BR9507915

申请日：1995-06-09

Applicant: EXXON CHEMICAL PATENTS INC

Inventor： ROSSI ALBERT ,  REA SALVATORE ,  STANAT JON EDMOND ,  WRIGHT LINDA KAY ,  KAUFMAN KENNETH LEE ,  FREDERICK JEFFREY WILLIAM ,  KOROS ROBERT MARTIN ,  MARGO HAROLD WILBUR

IPC: C08F2/06 ,  C08F4/602 ,  C08F10/00 ,  C08F10/04 ,  C08F110/08 ,  C08F210/08

公开(公告)号：AU676266B2

公开(公告)日：1997-03-06

申请号：AU5950894

申请日：1993-12-10

Applicant: EXXON CHEMICAL PATENTS INC

Inventor： ROSSI ALBERT ,  REA SALVATORE ,  STANAT JON EDMOND ,  WRIGHT LINDA KAY ,  KAUFMAN KENNETH LEE ,  MARGO HAROLD WILBUR ,  FREDERICK JEFFREY WILLIAM ,  KOROS ROBERT MARTIN

IPC: C08F2/04 ,  B01J8/38 ,  B01J19/18 ,  C08F2/06 ,  C08F4/602 ,  C08F210/16 ,  C08F210/02

Abstract: An improved process for the copolymerization of ethylene and alpha -olefins utilizing highly dilute alpha -olefin feedstreams to effect high conversions and catalyst productivities. The instant invention is particularly adaptable to copolymerizing the alpha -olefin content of commercially available refinery feedstreams such as Raffinate-2.

公开(公告)号：SG105794G

公开(公告)日：1994-10-28

申请号：SG105794

申请日：1994-07-30

Applicant: EXXON CHEMICAL PATENTS INC

Inventor： ROSSI ALBERT ,  ROSENTAL CELIO

IPC: C10M143/02 ,  C10M145/14 ,  C10M145/16 ,  C10M157/00 ,  C10N30/02

公开(公告)号：LV10297A

公开(公告)日：1994-10-20

申请号：LV920153

申请日：1992-10-14

Applicant: EXXON CHEMICAL PATENTS INC

Inventor： LEWTAS KENNETH ,  LEHMANN EDWIN WILLIAM ,  TACK ROBERT DRYDEN ,  ROSSI ALBERT

IPC: C10L1/22 ,  C07C67/00 ,  C07C211/07 ,  C07C211/08 ,  C07C301/00 ,  C07C303/32 ,  C07C309/01 ,  C07C309/20 ,  C07C309/22 ,  C07C309/25 ,  C07C309/27 ,  C07C309/28 ,  C07C309/57 ,  C07C309/58 ,  C07C309/59 ,  C07C311/00 ,  C07D327/04 ,  C10L1/14 ,  C10L1/16 ,  C10L1/18 ,  C10L1/19 ,  C10L1/192 ,  C10L1/195 ,  C10L1/222 ,  C10L1/24 ,  C10L10/14 ,  C10M133/00 ,  C10M135/00

Abstract: Distillate fuel boiling in the range 120 C to 500 DEG C containing 0.001 to 0.5 wt% of a compound of the general formula in which -Y-R is -SO3(-)(+)NR 3R , -SO3(-)(+)HNR 2R , -SO3(-)(+)H2NR R , -SO3(-)(+)H3NR , -SO2NR R or -SO3R ; -X-R is -Y-R or -CONR R , -CO2(-)(+)NR 3R , -CO2(-)(+)HNR 2R , -CO2 H2NR R , -CO2(-)(+)H3NR , -R -COOR1, -NR COR , -R OR , -R OCOR , -R R , -N(COR )R or Z(-)(+)NR 3R ; -Z(-) is SO3 or -CO2 ; R and R are alkyl, alkoxy alkyl or polyalkoxy alkyl containing at least 10 carbon atoms in the main chain; R is hydrocarbyl and each R may be the same or different and R is nothing or is C1 to C5 alkylene and in the carbon-carbon (C-C) bond is either a) ethylenically unsaturated when A and B may be alkyl, alkenyl or substituted hydrocarbyl groups or b) part of a cyclic structure which may be aromatic, polynuclear aromatic or cyclo aliphatic.

公开(公告)号：MX9307959A

公开(公告)日：1994-08-31

申请号：MX9307959

申请日：1993-12-15

Applicant: EXXON CHEMICAL PATENTS INC

Inventor： WRIGHT LINDA KAY ,  KAUFMAN KENNETH LEE ,  MARGO HAROLD WILBUR ,  FREDERICK JEFFREY WILLIAM ,  KOROS ROBERT MARTIN ,  ROSSI ALBERT ,  REA SALVATORE ,  STANAT JON EDMOND

IPC: C08F2/04 ,  B01J8/38 ,  B01J19/18 ,  C08F2/06 ,  C08F4/602 ,  C08F210/16

Abstract: An improved process for the copolymerization of ethylene and alpha -olefins utilizing highly dilute alpha -olefin feedstreams to effect high conversions and catalyst productivities. The instant invention is particularly adaptable to copolymerizing the alpha -olefin content of commercially available refinery feedstreams such as Raffinate-2.

公开(公告)号：CA1331511C

公开(公告)日：1994-08-23

申请号：CA516167

申请日：1986-08-18

Applicant: EXXON CHEMICAL PATENTS INC

Inventor： LEWTAS KENNETH ,  TACK ROBERT D ,  BLAND JACQUELINE D ,  ROSSI ALBERT

IPC: C10L1/14 ,  C10L1/18 ,  C10L1/192 ,  C10L1/195 ,  C10L1/196 ,  C10L1/22 ,  C10L10/14

Abstract: Copolymers of straight chain alpha olefins and maleic anhydride esterified with an alcohol wherein the alpha olefin is of the formula: R.CH = CH2 and the alcohol is of the formula: R1OH in which at least one of R and R1 is greater than 10 and the sum of R and R1 is from 18 to 38 and R1 is linear or contains a methyl branch at the 1 or 2 position have been found to be effective additives for improving the low temperature properties of distillate fuels.

公开(公告)号：FI90351C

公开(公告)日：1994-01-25

申请号：FI874184

申请日：1987-09-24

Applicant: EXXON CHEMICAL PATENTS INC

Inventor： LEWTAS KENNETH ,  LEHMANN EDWIN WILLIAM ,  TACK ROBERT DRYDEN ,  ROSSI ALBERT

IPC: C10L1/22 ,  C07C67/00 ,  C07C211/07 ,  C07C211/08 ,  C07C301/00 ,  C07C309/01 ,  C07C309/20 ,  C07C309/22 ,  C07C309/25 ,  C07C309/27 ,  C07C309/28 ,  C07C309/57 ,  C07C309/58 ,  C07C309/59 ,  C07C311/00 ,  C07D327/04 ,  C10L1/14 ,  C10L1/16 ,  C10L1/18 ,  C10L1/19 ,  C10L1/192 ,  C10L1/195 ,  C10L1/222 ,  C10L1/24 ,  C10L309/57

公开(公告)号：ES2045444T3

公开(公告)日：1994-01-16

申请号：ES89307567

申请日：1989-07-25

Applicant: EXXON CHEMICAL PATENTS INC

Inventor： SONG WON RYUL ,  ROSSI ALBERT ,  TURNER HOWARD WILLIAM ,  WELBORN HOWARD CURTIS ,  LUNDBERG ROBERT DEAN ,  GUTIERREZ ANTONIO ,  KLEIST ROBERT ARTHUR

IPC: C10M145/12 ,  C08F8/00 ,  C08F210/16 ,  C10L1/14 ,  C10L1/16 ,  C10L1/18 ,  C10L1/198 ,  C10L1/20 ,  C10L1/22 ,  C10L1/238 ,  C10L1/24 ,  C10L1/26 ,  C10L1/30 ,  C10L10/00 ,  C10M129/93 ,  C10M129/95 ,  C10M133/52 ,  C10M133/56 ,  C10M135/26 ,  C10M143/02 ,  C10M145/16 ,  C10M159/16 ,  C10M171/00 ,  C10N20/02 ,  C10N20/04 ,  C10N30/02 ,  C10N30/04 ,  C08F8/46