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公开(公告)号:JPH10502106A
公开(公告)日:1998-02-24
申请号:JP50244996
申请日:1995-06-14
Applicant: EXXON CHEMICAL PATENTS INC
Inventor: DANKWORTH DAVID CHARLES , EMERT JACOB ISAAC , GORDA KEITH RAYMOND , DIANA WILLIAM DANIEL , STANAT JON EDMOND , ECKSTROM WILLIAM BERNARD , CUSUMANO JOSEPH VICTOR , KOROS ROBERT MARTIN , CROSS WILLIAM HARRY , MARGO HAROLD WILBUR
IPC: C10M159/12 , B01J10/00 , B01J19/24 , C07C51/14 , C07C67/38 , C08F8/00 , C08F8/10 , C08F8/14 , C08F8/32 , C08F8/34 , C08L23/26 , C08L101/00 , C08L101/06 , C10L1/14 , C10L1/18 , C10L1/195 , C10L1/198 , C10L1/20 , C10L1/22 , C10L1/236 , C10L1/238 , C10L1/2383 , C10L1/24 , C10L1/26 , C10L1/28 , C10L1/30 , C10L10/00 , C10M129/95 , C10M133/06 , C10M133/52 , C10M133/54 , C10M133/56 , C10M143/00 , C10M145/12 , C10M149/06 , C10M159/18 , C10N20/04 , C10N30/04
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公开(公告)号:CA2257844C
公开(公告)日:2005-11-29
申请号:CA2257844
申请日:1997-06-11
Applicant: EXXON CHEMICAL PATENTS INC
Inventor: GINDELBERGER DAVID EDWARD , ROSSI ALBERT , EMERT JACOB ISAAC , SHER JAIMES , STANAT JON EDMOND , STOKES JAMES PETER
IPC: C08F8/00 , C08F10/00 , C10M143/00
Abstract: Polymers (including copolymers) derived from one or more olefins, such including ethylene and C3-C20 .alpha.-olefins such as propylene and 1-butene, which polymers have (a) an average ethylene sequence length, ESL, of from about 1.0 to less than about 3.0; (b) an average of at least 5 branches per 100 carbon atoms of the polymer chains comprising the polymer; (c) at least about 50 % of said branches being methyl and/or ethyl branches; (d) at least about 30 % of said polymer chains terminated with a vinyl or vinylene group; (e) a number average molecular weight, Mn, or from about 300 to about 15,000 when the polymer is intended for dispersant or wax crystal modifier uses and up to about 500,000 where intended for viscosity modifier uses; and (f) substantial solubility in hydrocarbon and/or synthetic base oil. The polymers are produced using late-transition-metal catalyst systems and, preferably, inexpensive, highly dilute refinery or steam cracker feed streams that have undergone only limited clean-up steps. Fuel a nd lubricating oil additives, particularly dispersants, wax crystal modifiers and flow improvers, are produced. Where functionalization and derivatization of these polymers is required for such additives it is facilitated by the olefinic structures available in the polymer chains.
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公开(公告)号:AU712427B2
公开(公告)日:1999-11-04
申请号:AU2967495
申请日:1995-07-11
Applicant: EXXON CHEMICAL PATENTS INC
Inventor: GUTIERREZ ANTONIO , EMERT JACOB ISAAC , LUNDBERG ROBERT DEAN , BANNISTER ERIC
IPC: C09K23/16 , C08F8/32 , C08F210/02 , C09K23/52 , C10L1/14 , C10L1/22 , C10L1/2383 , C10L1/24 , C10L1/26 , C10L1/30 , C10L10/00 , C10M133/52 , C10M133/54 , C10M133/56 , C10M149/02 , C10M159/12 , C10N30/04 , C10N40/25
Abstract: A succinimide dispersant, which is the reaction product of hydrocarbons or polymers functionalized by halogenation (e.g. chlorination), thermal "ene" reaction or free radical grafting and derivatized with a heavy polyamine. A heavy polyamine is a mixture of polyalkylenepolyamines comprising small amounts of lower polyamine oligomers such as tetraethylene pentamine and pentahexamine but primarily oligomers with 7 or more nitrogens, 2 or more primary amines per molecule, and more extensive branching than conventional polyamine mixtures.
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公开(公告)号:AU3485599A
公开(公告)日:1999-11-01
申请号:AU3485599
申请日:1999-04-09
Applicant: EXXON CHEMICAL PATENTS INC
Inventor: EMERT JACOB ISAAC , MACDONALD ISABEL P
IPC: C10M171/06 , C10L1/14 , C10L1/16 , C10L1/18 , C10L1/22 , C10L1/24 , C10L1/26 , C10L1/30 , C10M129/93 , C10M133/54 , C10M143/06 , C10M159/20 , C10M163/00 , C10M171/00 , C10M177/00
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公开(公告)号:DE69504668D1
公开(公告)日:1998-10-15
申请号:DE69504668
申请日:1995-06-14
Applicant: EXXON CHEMICAL PATENTS INC
Inventor: DANKWORTH DAVID CHARLES , EMERT JACOB ISAAC , GORDA KEITH RAYMOND , DIANA WILLIAM DANIEL , STANAT JON EDMOND , ECKSTROM WILLIAM BERNARD , CUSUMANO JOSEPH VICTOR , KOROS ROBERT MARTIN , CROSS WILLIAM HARRY , MARGO HAROLD WILBUR
IPC: C10M159/12 , B01J10/00 , B01J19/24 , C07C51/14 , C07C67/38 , C08F8/00 , C08F8/10 , C08F8/14 , C08F8/32 , C08F8/34 , C08L23/26 , C08L101/00 , C08L101/06 , C10L1/14 , C10L1/18 , C10L1/195 , C10L1/198 , C10L1/20 , C10L1/22 , C10L1/236 , C10L1/238 , C10L1/2383 , C10L1/24 , C10L1/26 , C10L1/28 , C10L1/30 , C10L10/00 , C10M129/95 , C10M133/06 , C10M133/52 , C10M133/54 , C10M133/56 , C10M143/00 , C10M145/12 , C10M149/06 , C10M159/18 , C10N20/04 , C10N30/04
Abstract: A process for reacting a liquid with a gas in a gas-liquid pipe reactor which is operated in laminar flow with a Reynolds number less than 10 and which contains a static mixer to disperse the gas into the liquid for reaction.
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公开(公告)号:MX9700294A
公开(公告)日:1998-03-31
申请号:MX9700294
申请日:1995-07-11
Applicant: EXXON CHEMICAL PATENTS INC
Inventor: GUTIERREZ ANTONIO , EMERT JACOB ISAAC , LUNDBERG ROBERT DEAN , BANNISTER ERIC
IPC: C08F8/32 , C08F210/02 , C09K23/16 , C09K23/52 , C10L1/14 , C10L1/22 , C10L1/2383 , C10L1/24 , C10L1/26 , C10L1/30 , C10L10/00 , C10M133/52 , C10M133/54 , C10M133/56 , C10M149/02 , C10M159/12 , C10N30/04 , C10N40/25 , C08F08/32
Abstract: Un dispersante de succinimida, el cual es el producto de reaccion de hidrocarburos o polímeros funcionalizados por halogenacion (por ejemplo, cloracion), reaccion "eno" térmica o injerto de radicales libres, y derivados con una poliamina pesada. Una poliamina pesada es una mezcla de polialquilenopoliaminas que comprende pequeñas cantidades de oligomeros de poliamina inferior tales como tetraetileno pentamina y pentahexamina sin oligomeros primarios con 7 o más nitrogenos, 2 o más aminas primarias por molécula, y ramificacion más extensa que las mezclas convencionales de poliamina.
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公开(公告)号:AU2944395A
公开(公告)日:1996-01-15
申请号:AU2944395
申请日:1995-06-14
Applicant: EXXON CHEMICAL PATENTS INC
Inventor: DANKWORTH DAVID CHARLES , EMERT JACOB ISAAC , GORDA KEITH RAYMOND , DIANA WILLIAM DANIEL , STANAT JON EDMOND , ECKSTROM WILLIAM BERNARD , CUSUMANO JOSEPH VICTOR , KOROS ROBERT MARTIN , CROSS WILLIAM HARRY , MARGO HAROLD WILBUR
IPC: C10M159/12 , B01J10/00 , B01J19/24 , C07C51/14 , C07C67/38 , C08F8/00 , C08F8/10 , C08F8/14 , C08F8/32 , C08F8/34 , C08L23/26 , C08L101/00 , C08L101/06 , C10L1/14 , C10L1/18 , C10L1/195 , C10L1/198 , C10L1/20 , C10L1/22 , C10L1/236 , C10L1/238 , C10L1/2383 , C10L1/24 , C10L1/26 , C10L1/28 , C10L1/30 , C10L10/00 , C10M129/95 , C10M133/06 , C10M133/52 , C10M133/54 , C10M133/56 , C10M143/00 , C10M145/12 , C10M149/06 , C10M159/18 , C10N20/04 , C10N30/04
Abstract: A process for reacting a liquid with a gas in a gas-liquid pipe reactor which is operated in laminar flow with a Reynolds number less than 10 and which contains a static mixer to disperse the gas into the liquid for reaction.
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公开(公告)号:CA2189072A1
公开(公告)日:1995-12-28
申请号:CA2189072
申请日:1995-06-16
Applicant: EXXON CHEMICAL PATENTS INC
Inventor: THALER WARREN ALAN , ZUSHMA STEPHEN , DANKWORTH DAVID CHARLES , GUTIERREZ ANTONIO , EMERT JACOB ISAAC , GORDA KEITH RAYMOND , DIANA WILLIAM DANIEL , ECKSTROM WILLIAM BERNARD , CUSUMANO JOSEPH VICTOR
IPC: C08F8/32 , C10L1/236 , C10L1/238 , C10L1/2387 , C10L10/00 , C10M133/56
Abstract: The present invention is directed to a process for preparing a polymeric amide which comprises the steps of: (A) reacting a mixture of (i) functionalized hydrocarbon polymer containing ester functional groups comprising at least one member selected from the group consisting of substituted alkyl ester functional groups, the substituted alkyl moiety containing at least one electron withdrawing substituent group, and aryl ester functional groups, the hydrocarbon polymer having a number average molecular weight of at least about 500 prior to functionalization, and (ii) an amine having at least one reactive -NH2 moiety, for a time and under conditions sufficient to form amide groups; and (B) removing from the mixture during step (A) hydroxyl compound released from the ester functional groups in forming the amide groups. The polymeric amides so produced are useful as fuel additives (e.g., detergents) and lubricating oil additives (e.g., dispersants).
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公开(公告)号:CA2327836A1
公开(公告)日:1999-10-21
申请号:CA2327836
申请日:1999-04-09
Applicant: EXXON CHEMICAL PATENTS INC
Inventor: MACDONALD ISABEL P , VAN DRIESEN KARL J , RITCHIE ANDREW J D , STOKES JAMES P , REA SALVATORE , EMERT JACOB ISAAC , HIGTON GARY , WILKINSON ROBERT A
IPC: C10M171/06 , C10M163/00 , C10M169/04 , C10N60/14 , C10M129/04 , C10M129/76 , C10M133/08 , C10M133/54 , C10M133/56 , C10M159/20 , C10M159/22 , C10M159/24
Abstract: Concentrates for lubricating oil compositions are prepared by mixing at elevated temperature: (i) at least one high molecular weight ashless dispersant; (ii) at least one oil-soluble overbased metal detergent; and (iii) at least one surface-active agent comprising a low molecular weight hydroxyl or amine group.
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公开(公告)号:BR9508269A
公开(公告)日:1999-06-01
申请号:BR9508269
申请日:1995-07-11
Applicant: EXXON CHEMICAL PATENTS INC
Inventor: GUTIERREZ ANTONIO , EMERT JACOB ISAAC , LUNDBERG ROBERT DEAN , BANNISTER ERIC
IPC: C09K23/16 , C08F8/32 , C08F210/02 , C09K23/52 , C10L1/14 , C10L1/22 , C10L1/2383 , C10L1/24 , C10L1/26 , C10L1/30 , C10L10/00 , C10M133/52 , C10M133/54 , C10M133/56 , C10M149/02 , C10M159/12 , C10N30/04 , C10N40/25
Abstract: A succinimide dispersant, which is the reaction product of hydrocarbons or polymers functionalized by halogenation (e.g. chlorination), thermal "ene" reaction or free radical grafting and derivatized with a heavy polyamine. A heavy polyamine is a mixture of polyalkylenepolyamines comprising small amounts of lower polyamine oligomers such as tetraethylene pentamine and pentahexamine but primarily oligomers with 7 or more nitrogens, 2 or more primary amines per molecule, and more extensive branching than conventional polyamine mixtures.
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