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    81.
    发明专利
    未知

    公开(公告)号：ES2116644T3

    公开(公告)日：1998-07-16

    申请号：ES95106087

    申请日：1995-04-24

    Applicant: HOECHST AG

    Inventor： EPPLE ULRICH ,  KUBILLUS UWE ,  SCHMIDT HOLGER

    IPC: C08F2/00 ,  C08F8/30 ,  C08F20/26 ,  C08F220/04 ,  C08F220/10 ,  C08F220/28 ,  C08F220/32 ,  C08F222/02 ,  C08F222/20 ,  C09D5/03 ,  C09D5/46 ,  C09D133/00 ,  C09D133/04 ,  C09D133/14 ,  C09D135/02 ,  C09D175/04

    Abstract: Low-viscosity copolymers with OH and COOH gps. (I) are obtd. by reacting (A) 3 - 50 wt.% glycidyl ester(s) of satd. aliphatic carboxylic acids with a tert. or quat. alpha -C atom and (B) 97 - 50 wt.% of at least 2 unsatd. comonomers, at least one of which contains at least one COOH gp. and at least one of which is sterically hindered, in the presence of radical initiators, and with an excess of COOH gps. in (B) wrt. epoxide gps. in (A) such that the prod. has an acid no. of at least 15 mg KOH/g. Also claimed is the above process for the prodn. of (I). Also claimed are 1-component paints with (I) as binder and formaldehyde/amino-resin reaction prods. (opt. etherated with 1 - 8 C aliphatic alcohol) as hardeners, and 2-component paints with (I) as binder and polyisocyanates or urethane-forming polyisocyanate derivs. as hardeners.

    Aliphatic expoxide-amine adducts with substantial side-chain branching, process for their preparation, and their use.
    83.
    发明专利
    Aliphatic expoxide-amine adducts with substantial side-chain branching, process for their preparation, and their use. 未知

    公开(公告)号：ZA963464B

    公开(公告)日：1997-11-03

    申请号：ZA963464

    申请日：1996-05-02

    Applicant: HOECHST AG

    Inventor： EPPLE ULRICH ,  MARTEN MANFRED ,  KUBILLUS UWE ,  OSWALD HARALD

    IPC: C08G59/02 ,  C08G18/32 ,  C08G18/64 ,  C08G59/00 ,  C08G59/14 ,  C08G59/18 ,  C08G59/40 ,  C08G59/64 ,  C08L63/00 ,  C09D133/00 ,  C09D133/04 ,  C09D133/06 ,  C09D133/08 ,  C09D163/00 ,  C09D167/00 ,  C09J163/00 ,  C09K3/10 ,  C08G ,  C09D ,  C09K ,  C08L

    Abstract: Epoxide-amine adducts (I) are claimed, contg. at least 20 wt% aliphatic epoxide and/or amine units with at least one tert. or quat. carbon atom. Also claimed are: (i) binders for coatings, contg. adduct(s) (I); (ii) mixts. of 0.1-99.9 wt% OH gp.-contg. copolymers and 99.9-0.1 wt% (I); (iii) binders for coatings, contg. mixts. (ii); (iv) coating materials contg. these binders, together with hardeners such as amino resins, capped or uncapped polyisocyanates and cpds. with acid and/or anhydride gps.. Pref. (I) are obtd.: (A) by reacting (a) 7-33C (cyclo)aliphatic mono-epoxides (a1), at least 20 wt% of which comprises monoepoxides with a tert. or quat. C atom with (b) 2-30C amines with at least 2 prim. or sec. amino gps. not attached directly to an aromatic ring; or (B) by reacting (a) 8-50C (cyclo)aliphatic diepoxides (a2) with (b) 4-30C prim. or sec. mono-amines with amino gps. not directly attached to aromatic rings, of which at least 20 wt% comprises mono-amines with at least one tert. or quat. C atom; or (C) by reacting (a1) with (b), the corresp. proportions of mono-amine and mono-epoxide with tert. or quat. C atoms being a% and b% respectively, where a + b = 20 and both a and b are greater than zero. The functionality of (I) is reduced by partial or complete reaction of the functional OH and amino gps., pref. by blocking with temporary protecting gps., esp. oxazolidine gps..

    85.
    发明专利
    未知

    公开(公告)号：TR199600350A2

    公开(公告)日：1996-11-21

    申请号：TR9600350

    申请日：1996-04-26

    Applicant: HOECHST AG

    Inventor： EPPLE ULRICH ,  KUBILLUS UWE ,  OSWALD HARALD

    IPC: C08F220/32 ,  C08F20/32 ,  C08F220/04 ,  C08F222/02 ,  C08F222/16 ,  C08G18/62 ,  C09D133/02 ,  C09D133/04 ,  C09D133/14 ,  C09D135/00 ,  C09J133/02 ,  C09J133/04 ,  C09J133/14 ,  C09J135/00 ,  C09K3/10

    Abstract: Low-mol. wt. copolymers (I) with a wt.-average mol. wt. (Mw) of less than 3500 contain at least 20 wt.% of components with branched side chains, obtd. by the reaction of (aa) glycidyl ester(s) of satd. aliphatic monocarboxylic acids with a tert. or quat. alpha -C atom; and (ab) at least two unsatd. comonomers, at least one of which contains at least one COOH gp., under radical copolymerisation conditions. Also claimed are (i) prepn. of (I) by heating component (aa) to 210-260 degrees C and reacting with component (ab) (which contains at least 2.0 wt.% of a COOH gp.-contg. monomer) in the presence of radical initiator(s), to a degree of conversion of at least 95 (pref. at least 97.5) %; (ii) polymer mixts. contg. (I), obtd. by reaction of (aa) and (ab) as above in at least two time intervals with a constant temp. in each interval, using at least two different reaction temps., at least one of which is in the range 210-260 degrees C; (iii) polymer mixts. contg. (I) and other polymers etc.; (iv) binders for coating materials contg. (I) or the above polymer mixts.; (v) coating materials contg. binders as above and hardeners such as amino resins, capped or uncapped polyisocyanates or organic cpds. with acid and/or anhydride gps.

    LOW-MOLECULAR HYDROXYFUNCTIONAL COPOLYMERS WITH HIGH BRANCHING OF SIDE CHAINS, PROCESS OF THEIR PREPARATION AND USE
    87.
    发明专利
    LOW-MOLECULAR HYDROXYFUNCTIONAL COPOLYMERS WITH HIGH BRANCHING OF SIDE CHAINS, PROCESS OF THEIR PREPARATION AND USE 未知

    公开(公告)号：CZ128496A3

    公开(公告)日：1996-11-13

    申请号：CZ128496

    申请日：1996-05-02

    Applicant: HOECHST AG

    Inventor： EPPLE ULRICH ,  KUBILLUS UWE ,  OSWALD HARALD

    IPC: C08F220/32 ,  C08F20/32 ,  C08F220/04 ,  C08F222/02 ,  C08F222/16 ,  C08G18/62 ,  C09D133/02 ,  C09D133/04 ,  C09D133/14 ,  C09D135/00 ,  C09J133/02 ,  C09J133/04 ,  C09J133/14 ,  C09J135/00 ,  C09K3/10

    Abstract: Low-mol. wt. copolymers (I) with a wt.-average mol. wt. (Mw) of less than 3500 contain at least 20 wt.% of components with branched side chains, obtd. by the reaction of (aa) glycidyl ester(s) of satd. aliphatic monocarboxylic acids with a tert. or quat. alpha -C atom; and (ab) at least two unsatd. comonomers, at least one of which contains at least one COOH gp., under radical copolymerisation conditions. Also claimed are (i) prepn. of (I) by heating component (aa) to 210-260 degrees C and reacting with component (ab) (which contains at least 2.0 wt.% of a COOH gp.-contg. monomer) in the presence of radical initiator(s), to a degree of conversion of at least 95 (pref. at least 97.5) %; (ii) polymer mixts. contg. (I), obtd. by reaction of (aa) and (ab) as above in at least two time intervals with a constant temp. in each interval, using at least two different reaction temps., at least one of which is in the range 210-260 degrees C; (iii) polymer mixts. contg. (I) and other polymers etc.; (iv) binders for coating materials contg. (I) or the above polymer mixts.; (v) coating materials contg. binders as above and hardeners such as amino resins, capped or uncapped polyisocyanates or organic cpds. with acid and/or anhydride gps.

    88.
    发明专利
    未知

    公开(公告)号：DE59303811D1

    公开(公告)日：1996-10-24

    申请号：DE59303811

    申请日：1993-04-15

    Applicant: HOECHST AG

    Inventor： EPPLE ULRICH ,  BREKNER MICHAEL-JOACHIM

    IPC: C08F232/00 ,  C08F297/08 ,  C08G81/02 ,  C08L45/00 ,  C08L23/00 ,  C08L53/00 ,  C08L65/00

    Abstract: A polymer alloy contains at least one cycloolefin polymer and/or at least one polyolefin and a block copolymer as phase promoter, which has different contents of monomers (norbornene derivatives and cycloolefins and/or acyclic olefins) in the individual blocks. To prepare the alloy, the individual polymers are combined and processed at elevated temperature under the action of shear forces.

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