公开(公告)号：JPH10306126A

公开(公告)日：1998-11-17

申请号：JP26827897

申请日：1997-10-01

Applicant: HOECHST AG ,  HNA HOLDINGS INC

Inventor： ASLAM MOHAMMAD ,  VICARI RICHARD ,  DAMMEL RALPH ,  LINGNAU JUERGEN ,  DOESSEL KARL-FRIEDRICH

IPC: B01J27/02 ,  B01J27/06 ,  B01J27/24 ,  C07B61/00 ,  C07C45/54 ,  C07C45/63 ,  C07C67/297 ,  C07C69/157 ,  C08F8/12 ,  C08F12/00 ,  C08F12/14 ,  C08F112/14

Abstract: PROBLEM TO BE SOLVED: To obtain a poly(halogen-substituted-4-hydroxystyrene) by reacting 4-hydroxyacetophenone with a halogenated reagent to give a corresponding 3-mono or 3,5-dihalogen-substituted derivative, esterifying the derivative, reducing the ester to give an ethanol compound, dehydrating the ethanol compound to give a styrene compound, subjecting the styrene compound to radical polymerization to give a polymer, and hydrolyzing the polymer. SOLUTION: 4-Hydroxyacetophenone represented by the formula (wherein R1 is H or a 1-10C alkyl; and R2 and R3 are each H, alkyl, alkoxy or halogeno) is reacted with a halogenated reagent to give a corresponding 3-mono or 3,5- dihalogen-substituted-4-hydroxyacetophenone, which is esterified to form 4- acetoxyacetophenone. This ester is reduced with a sufficient amount of a reducing agent to give acetoxyphenyl ethanol, which is dehydrated to give 4- acetoxystyrene. The 4-acetoxystyrene is subjected to free-radical polymerization to give a polymer having a molecular weight of 1,000 to 800,000, and this polymer is hydrolyzed to give an objective material.

公开(公告)号：TR9501216A2

公开(公告)日：1996-06-21

申请号：TR9501216

申请日：1995-10-05

Applicant: HOECHST AG

Inventor： EPPLE ULRICH ,  SCHMIDT HOLGER ,  BRINDOEPKE GERHARD ,  DOESSEL KARL-FRIEDRICH

IPC: C08F220/16 ,  C08F2/02 ,  C08F4/04 ,  C08F4/32 ,  C08F20/10 ,  C08F220/18 ,  C08F220/26 ,  C08G18/62 ,  C09D5/02 ,  C09D5/03 ,  C09D133/04 ,  C09D133/06 ,  C09D135/00 ,  C09J133/04

CPC classification number: C08G18/6237 ,  C08F220/18 ,  C08G18/622 ,  C08G2150/20 ,  C09D133/06 ,  C08L2666/14

公开(公告)号：FI900721A0

公开(公告)日：1990-02-14

申请号：FI900721

申请日：1990-02-14

Applicant: HOECHST AG

Inventor： DOESSEL KARL-FRIEDRICH ,  FISCHER BERND ,  SCHLOSSER ERNST-GUENTER ,  SCHMIDT GUENTER

IPC: G11B11/10 ,  G11B11/105 ,  H01F10/08 ,  H01F10/12 ,  H01F10/13 ,  H01F10/32 ,  H01F41/18 ,  G11B

公开(公告)号：BR9504332A

公开(公告)日：1996-10-08

申请号：BR9504332

申请日：1995-10-09

Applicant: HOECHST AG

Inventor： EPPLE ULRICH ,  SCHMIDT HOLGER ,  BRINDOEPKE GERHARD ,  DOESSEL KARL-FRIEDRICH

IPC: C08F220/16 ,  C08F2/02 ,  C08F4/04 ,  C08F4/32 ,  C08F20/10 ,  C08F220/18 ,  C08F220/26 ,  C08G18/62 ,  C09D5/02 ,  C09D5/03 ,  C09D133/04 ,  C09D133/06 ,  C09D135/00 ,  C09J133/04 ,  C09J133/06

Abstract: Copolymers (I) of olefinic monomer(s) comprise an isomeric mixt. of esters of isobornyl alcohol with an alpha , beta -unsatd. acid. The isomeric alcohol mixt. contains: (a) not more than 92% isoborneol, (b) at least 3.5% iso-fenchyl alcohol, and (c) at least 1% pseudo-bornyl alcohol. Also claimed are: (i) a process for the prodn. of (I) by bulk polymerisation in the presence of aliphatic azo cpds., diacyl peroxide, alkyl per-esters, alkyl hydroperoxide, dialkyl peroxide or peroxy-di-carbonate as radical initiators; and (ii) a process for the prodn. of water-dilutable polyacrylate dispersions by: (A) dissolution of (I) in a water-dilutable organic solvent, followed by: (B) partial or complete neutralisation, and (C) dilution by adding water or stirring the soln. into water.

公开(公告)号：CZ9401761A3

公开(公告)日：1995-02-15

申请号：CZ176194

申请日：1994-07-22

Applicant: HOECHST AG

Inventor： EPPLE ULRICH ,  KUBILLUS UWE ,  BRINDOEPKE GERHARD ,  DOESSEL KARL-FRIEDRICH

IPC: C08F4/28 ,  C08F4/34 ,  C08F20/10 ,  C08F20/26 ,  C08F212/08 ,  C08F220/04 ,  C08F220/12 ,  C08F220/18 ,  C08F220/26 ,  C08F220/28 ,  C08F220/32 ,  C09D5/00 ,  C09D5/03 ,  C09D133/00 ,  C09D133/02 ,  C09D133/04 ,  C09D133/06 ,  C09D133/14 ,  C09D175/04

CPC classification number: C08F220/12 ,  C08F220/04

公开(公告)号：AU630664B2

公开(公告)日：1992-11-05

申请号：AU4978490

申请日：1990-02-14

Applicant: HOECHST AG

Inventor： DOESSEL KARL-FRIEDRICH ,  FISCHER BERND ,  SCHLOSSER ERNST-GUENTER ,  SCHMIDT GUENTHER

IPC: G11B11/10 ,  G11B11/105 ,  H01F10/08 ,  H01F10/12 ,  H01F10/13 ,  H01F10/32 ,  H01F41/18 ,  C23C14/35 ,  C22C45/02 ,  G11B11/12 ,  G11B13/04

公开(公告)号：FI893071A

公开(公告)日：1989-12-26

申请号：FI893071

申请日：1989-06-22

Applicant: HOECHST AG

Inventor： DAMMEL RALPH ,  DOESSEL KARL-FRIEDRICH ,  LINGNAU JUERGEN ,  THEIS JUERGEN

IPC: G03F7/004 ,  G03F7/029 ,  G03F7/038 ,  H01L21/027 ,  H01L21/30 ,  G03F

Abstract: A radiation-curable composition which comprises a compound that forms an acid under the action of high-energy radiation and an acid-hardening substance, wherein the compound forming an acid contains aromatically linked chlorine or bromine and has a pKa value below 12. The composition and the recording material prepared therefrom display increased sensitivity, improved resolution and a high etch resistance after development.

公开(公告)号：FI893071A0

公开(公告)日：1989-06-22

申请号：FI893071

申请日：1989-06-22

Applicant: HOECHST AG

Inventor： DAMMEL RALPH ,  DOESSEL KARL-FRIEDRICH ,  LINGNAU JUERGEN ,  THEIS JUERGEN

IPC: G03F7/004 ,  G03F7/029 ,  G03F7/038 ,  H01L21/027 ,  H01L21/30 ,  G03F

Abstract: A radiation-curable composition which comprises a compound that forms an acid under the action of high-energy radiation and an acid-hardening substance, wherein the compound forming an acid contains aromatically linked chlorine or bromine and has a pKa value below 12. The composition and the recording material prepared therefrom display increased sensitivity, improved resolution and a high etch resistance after development.

公开(公告)号：TR199501216A2

公开(公告)日：1996-06-21

申请号：TR9501216

申请日：1995-10-05

Applicant: HOECHST AG

Inventor： EPPLE ULRICH ,  SCHMIDT HOLGER ,  BRINDOEPKE GERHARD ,  DOESSEL KARL-FRIEDRICH

IPC: C08F220/16 ,  C08F2/02 ,  C08F4/04 ,  C08F4/32 ,  C08F20/10 ,  C08F220/18 ,  C08F220/26 ,  C08G18/62 ,  C09D5/02 ,  C09D5/03 ,  C09D133/04 ,  C09D133/06 ,  C09D135/00 ,  C09J133/04 ,  C09J133/06

Abstract: Copolymers (I) of olefinic monomer(s) comprise an isomeric mixt. of esters of isobornyl alcohol with an alpha , beta -unsatd. acid. The isomeric alcohol mixt. contains: (a) not more than 92% isoborneol, (b) at least 3.5% iso-fenchyl alcohol, and (c) at least 1% pseudo-bornyl alcohol. Also claimed are: (i) a process for the prodn. of (I) by bulk polymerisation in the presence of aliphatic azo cpds., diacyl peroxide, alkyl per-esters, alkyl hydroperoxide, dialkyl peroxide or peroxy-di-carbonate as radical initiators; and (ii) a process for the prodn. of water-dilutable polyacrylate dispersions by: (A) dissolution of (I) in a water-dilutable organic solvent, followed by: (B) partial or complete neutralisation, and (C) dilution by adding water or stirring the soln. into water.

公开(公告)号：AU3308895A

公开(公告)日：1996-04-18

申请号：AU3308895

申请日：1995-10-05

Applicant: HOECHST AG

Inventor： EPPLE ULRICH ,  SCHMIDT HOLGER ,  BRINDOEPKE GERHARD ,  DOESSEL KARL-FRIEDRICH

IPC: C08F220/16 ,  C08F2/02 ,  C08F4/04 ,  C08F4/32 ,  C08F20/10 ,  C08F220/18 ,  C08F220/26 ,  C08G18/62 ,  C09D5/02 ,  C09D5/03 ,  C09D133/04 ,  C09D133/06 ,  C09D135/00 ,  C09J133/04 ,  C09J133/06 ,  C08F212/08 ,  C09D125/14 ,  C09J125/14

Abstract: Copolymers (I) of olefinic monomer(s) comprise an isomeric mixt. of esters of isobornyl alcohol with an alpha , beta -unsatd. acid. The isomeric alcohol mixt. contains: (a) not more than 92% isoborneol, (b) at least 3.5% iso-fenchyl alcohol, and (c) at least 1% pseudo-bornyl alcohol. Also claimed are: (i) a process for the prodn. of (I) by bulk polymerisation in the presence of aliphatic azo cpds., diacyl peroxide, alkyl per-esters, alkyl hydroperoxide, dialkyl peroxide or peroxy-di-carbonate as radical initiators; and (ii) a process for the prodn. of water-dilutable polyacrylate dispersions by: (A) dissolution of (I) in a water-dilutable organic solvent, followed by: (B) partial or complete neutralisation, and (C) dilution by adding water or stirring the soln. into water.