81.
    发明专利
    未知

    公开(公告)号:DE3784403D1

    公开(公告)日:1993-04-08

    申请号:DE3784403

    申请日:1987-07-29

    Abstract: Thermoplastic aromatic polyether-pyridines are composed of repeating structural units each containing one or more pyridine rings. These polymers are prepared by a polycondensation reaction between a 2,6-dihalogenopyridine and one or two dihydroxy compounds, or between a bis(6-chloro-2-pyridyloxy) compound and a dihydroxy compound, the reactions being performed substantially in the absence of water. The degree of polymerization may be 10 or greater. The polymers have an excellent combination of heat resistance, moldability and other properties, and hence are useful in a wide variety of applications.

    BIS(3-AMINOPHENOXY) AROMATICS AND METHOD OF PREPARING THE SAME

    公开(公告)号:CA1256451A

    公开(公告)日:1989-06-27

    申请号:CA502460

    申请日:1986-02-21

    Abstract: BIS (3-AMINOPIIENOXY) AROMATICS AND METHOD OF PREPARING THE SAME Bis(3-nitrophenoxy) derivatives of aromatic or bridged aromatic hydrocarbons are derived from m-dinitrobenzene and dihydroxy derivatives of said hydrocarbons by a condensation reaction in dipolar aprotic solvents in the presence of bases. The bis(3-nitro-phenoxy) derivatives obtained are successively reduced to afford bis (3-aminophenoxy)derivatives. This is a new method for reacting the dihydroxy-derivatives with m-dinitrobenzene, and hence can prepare novel bis(3-aminophenoxy) derivatives such as 4,4'-bis(3-amino-phenoxy)biphenyl, 1-¢4-(3-aminophenoxy)phenyl!-1,3,3-trimethyl-6- (3-aminophenoxy)indan, 6,6'-bis(3-aminophenoxy)-3,3,3',3'-tetra-methyl-1,1'spirobiindan, and methyl substituted 2,2'-bis¢4-(3-amino-pllenoxy)phenyl!propane.

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