公开(公告)号：DE2332880A1

公开(公告)日：1974-01-31

申请号：DE2332880

申请日：1973-06-28

Applicant: STANDARD OIL CO OHIO

Inventor： CALLAHAN JAMES LOUIS ,  MILLER ARTHUR FRANCIS ,  SHAW WILFRID GARSIDE

IPC: B01J2/02 ,  B01J37/00

Abstract: 1444572 Hollow particles STANDARD OIL CO 13 July 1973 [13 July 1972] 7199/76 Divided out of 1444571 Heading C1A [Also in Division B5] An aggregate, Fig. 1, of solid particles having a rounded shape, a void centre and a single cavity in the external surface communicating with the void centre is produced by the process described in the parent Specification 1,444,571 modified by feeding the droplets of the slurry containing the solid particles on to a static particle bed so that the total droplet is not immersed in the bed and is allowed to dry in the bed without agitation. Specified materials include clay, ammonium nitrate and metal oxides.

公开(公告)号：DE2229358A1

公开(公告)日：1973-01-18

申请号：DE2229358

申请日：1972-06-16

Applicant: STANDARD OIL CO OHIO

Inventor： MILLER ARTHUR FRANCIS ,  SHAW WILFRID GARSIDE ,  BLYTHE HUGH MICHAEL

IPC: B01J23/28 ,  B01J23/88 ,  B01J27/19 ,  B01J11/32

Abstract: 1397119 Making fluidizable, supported molybdenum oxide-containing catalysts STANDARD OIL CO 22 June 1972 [28 June 1971] 29325/72 Heading B1E Catalysts are made by adding incrementally a sol containing SiO 2 , Al 2 O 3 , TiO 2 and/or ZrO 2 to an aqueous suspension and/or solution of a heptamolybdate or a dimolybdate and optionally an alkali metal hydroxide or nitrate at a temperature below 150‹F, spray drying the resulting slurry at a temperature below 1000‹F, collecting the dried spherical particles and calcining them. Optionally to the slurry an acid of P, As or B may be added below (150‹F) after the sol. As a further option a nitrate, carbonate, oxalate and/or acetate of an alkali metal, Mg, Ca, Zn, Cd, a rare earth metal, Sn, Nb, Ta, Sb, Bi, Te, Mn, Fe, Co and/or Ni may be added in solution to the slurry (below 150‹F) but after the acid if that is also used. Further sol may be added with the nitrate, carbonate, oxalate and/or acetate and/ or with the acid.