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    MASS SPECTROMETRY METHOD AND DEVICES
    84.
    发明公开
    MASS SPECTROMETRY METHOD AND DEVICES 审中-公开
    MASSENSPEKTROMETRIEVERFAHREN UND -VORRICHTUNG

    公开(公告)号：EP2958133A1

    公开(公告)日：2015-12-23

    申请号：EP13875207.6

    申请日：2013-03-13

    Applicant: Saparqaliyev, Aldan Asanovich

    Inventor： Saparqaliyev, Aldan Asanovich

    IPC: H01J49/40 ,  G01N30/72

    CPC classification number: G01N30/72 ,  H01J49/009 ,  H01J49/405 ,  H01J49/406

    Abstract: This invention relates to the analytical electronics used to identify compositions and structures of substances, in particular, to the analyzers comprising at least one mass-spectrometer (MS) and may be applied in such fields as medicine, biology, gas and oil industry, metallurgy, energy, geochemistry, hydrology, ecology.
    Technical result provides the increase in MS resolution capacity, gain in sensitivity, precision and measurement rates of substances compositions and structures concurrently with enhancement of analyzer functional capabilities, downsizing and mass reduction.
    A multipath method of mass-spectrometry and a three-dimensional reflecting (-reflecting) method of mass-spectrometry requiring to use a three-dimensional reflecting IO sub-system (- reflector) are developed. A new type of electric field distribution such as transversely discontinuous conic field distribution, including its type of three-dimensional distribution in area of reflection, is proposed to implementing said methods.
    Versions of devices to implement the claimed method are developed.
    Proposed schematic ion optical diagrams allow to developing different MS types.

    Abstract translation: 本发明涉及用于识别物质的组成和结构的分析电子装置，特别涉及包含至少一种质谱仪（MS）的分析仪，并且可以应用于诸如医药，生物学，燃气和石油工业，冶金学 ，能源，地球化学，水文学，生态学。 技术结果提高了分析能力，提高了分析仪功能，缩小尺寸和减少质量的同时，提高了MS分辨率，灵敏度，精度和物质成分和结构测量速率。 开发了质谱法的多路径法和需要使用三维反射IO子系统（ - 反射器）的质谱法的三维反射（ - 反射）方法。 提出了一种新型的电场分布，如横向不连续圆锥场分布，包括其反射区域的三维分布类型，用于实现所述方法。 开发了实现所要求保护的方法的设备的版本。 拟议的示意图光学图允许开发不同的MS类型。

    Ion trap
    85.
    发明公开
    Ion trap 审中-公开
    离子阱

    公开(公告)号：EP2276056A2

    公开(公告)日：2011-01-19

    申请号：EP10176305.0

    申请日：2002-06-17

    Applicant: Yeda Research And Development Company Ltd.

    Inventor： Zajfman, Daniel ,  Heber, Oded ,  Pedersen, Henrik B. ,  Rudich, Yinon ,  Sagi, Irit ,  Rappaport, Michael

    IPC: H01J49/40

    CPC classification number: H01J3/40 ,  H01J49/027 ,  H01J49/406 ,  H01J49/4245

    Abstract: A charged particle trap for trapping of a plurality of charged particles, and a method of operating said trap. The trap includes first and second electrode mirrors (2,3) having a common optical axis (4), the mirrors being arranged in alignment at two extremities thereof. The mirrors are capable, when voltage is applied thereto, of creating respective electric fields defined by key field parameters. The electric fields are configured to reflect charged particles causing their oscillation between the mirrors. The method includes introducing into the trap, along the optical axis, the plurality of charged particles as a beam (10) having pre-determined key beam parameters. The method further includes choosing the key field parameters for at least one of the mirrors such as to induce bunching among charged particles in the beam.

    Abstract translation: 用于捕获多个带电粒子的带电粒子捕获器以及操作所述捕获器的方法。 该陷阱包括具有公共光轴（4）的第一和第二电极镜（2,3），这些镜在其两个末端排列成对齐。 当施加电压时，反射镜能够产生由关键场参数定义的相应电场。 电场被配置为反射带电粒子，引起它们在镜子之间的振荡。 该方法包括沿着光轴将多个带电粒子作为具有预定关键射束参数的射束（10）引入陷阱。 该方法还包括选择用于至少一个反射镜的关键场参数，以便诱导射束中带电粒子之间的聚束。

    MULTIREFLECTION TIME-OF-FLIGHT MASS SPECTROMETER
    86.
    发明公开
    MULTIREFLECTION TIME-OF-FLIGHT MASS SPECTROMETER 有权
    多重反射时间质谱仪

    公开(公告)号：EP2232525A2

    公开(公告)日：2010-09-29

    申请号：EP08865251.6

    申请日：2008-12-22

    Applicant: Thermo Fisher Scientific (Bremen) GmbH

    Inventor： MAKAROV, Alexander ,  GRINFELD, Dmitry, E. ,  MONASTYRSKIY, Mikhail, A.

    IPC: H01J49/40

    CPC classification number: H01J49/406 ,  H01J49/061 ,  H01J49/405

    Abstract: The present invention provides a method of reflecting ions in a multireflection time of flight mass spectrometer comprising providing an ion mirror having a plurality of electrodes, the ion mirror having a cross section with a first, minor axis (Y) and a second, major axis (X) each perpendicular to a longitudinal axis (Z) of the ion mirror which lies generally in the direction of time of flight separation of the ions in the mirror; guiding ions towards the ion mirror; applying a voltage to the electrodes so as to create an electric field which: (a) causes the mean trajectory of the ions to intersect a plane of symmetry of the ion mirror which contains the longitudinal (Z) and major axes (X) of the mirror; (b) causes the ions to reflect in the ion mirror; and (c) causes the ions to exit the ion mirror in a direction such that the mean trajectory of ions passing through the ion mirror has a component of movement in a direction (Y) perpendicular to and diverging from the said plane of symmetry thereof. Apparatus for carrying out the method is also disclosed.

    MULTI-REFLECTING TIME-OF-FLIGHT MASS ANALYSER AND A TIME-OF-FLIGHT MASS SPECTROMETER INCLUDING THE MASS ANALYSER
    88.
    发明公开
    MULTI-REFLECTING TIME-OF-FLIGHT MASS ANALYSER AND A TIME-OF-FLIGHT MASS SPECTROMETER INCLUDING THE MASS ANALYSER 有权
    多思考时间和持续时间质谱仪质谱仪，其质量分析器

    公开(公告)号：EP2078305A2

    公开(公告)日：2009-07-15

    申请号：EP07830134.8

    申请日：2007-10-12

    Applicant: Shimadzu Corporation

    Inventor： SUDAKOV, Michael

    IPC: H01J49/40

    CPC classification number: H01J49/406

    Abstract: A multi-reflecting TOF mass analyser has two parallel, gridless ion mirrors each having an elongated structure in a drift direction (Z). These ion mirrors provide a folded ion path formed by multiple reflections of ions in a flight direction (X), orthogonal to the drift direction (Z). The analyser also has a further gridless ion mirror for reflecting ions in the drift direction (Z). In operation ions are spatially separated according to mass-to-charge ratio due to their different flight times along the folded ion path and ions having substantially the same mass-to-charge ratio are subjected to energy focusing with respect to the flight and drift directions.

    IMPROVEMENTS IN AN ELECTROSTATIC TRAP
    89.
    发明公开
    IMPROVEMENTS IN AN ELECTROSTATIC TRAP 有权
    VERBESSERUNGEN A EINER ELEKTROSTATISCHEN FALLE

    公开(公告)号：EP1900002A2

    公开(公告)日：2008-03-19

    申请号：EP06744082.6

    申请日：2006-06-05

    Applicant: THERMO FINNIGAN LLC

    Inventor： MAKAROV, Alexander ,  DENISOV, Eduard, V. ,  JUNG, Gerhard ,  BALSCHUN, Wilko, c/o Thermo Electron (Bremen) GmbH ,  HORNING, Stevan, Roy

    IPC: H01J49/42

    CPC classification number: H01J49/4245 ,  H01J49/0027 ,  H01J49/02 ,  H01J49/282 ,  H01J49/406 ,  H01J49/425

    Abstract: An electrostatic trap such as an orbitrap is disclosed, with an electrode structure. An electrostatic trapping field of the form U'(r,φ,z) is generated to trap ions within the trap so that they undergo isochronous oscillations. The trapping field U'(r, φ,z) is the result of a perturbation W to an ideal field U(r, φ,z) which, for example, is hyperlogarithmic in the case of an orbitrap. The perturbation W may be introduced in various ways, such as by distorting the geometry of the trap so that it no longer follows an equipotential of the ideal field U(r, φ,z), or by adding a distortion field (either electric or magnetic). The magnitude of the perturbation is such that at least some of the trapped ions have an absolute phase spread of more than zero but less than about 2 π radians over an ion detection period Tm.

    Abstract translation: 公开了诸如轨道捕获器的静电捕获器，具有电极结构。 产生形式U'（r，＆phgr; z）的静电捕获场，以捕获陷阱内的离子，使得它们经历同步振荡。 捕获场U'（r，＆phgr; z）是对于理想场U（r，＆phgr; z）的扰动W的结果，其在轨道捕获的情况下例如是超对数的。 扰动W可以以各种方式引入，例如通过使陷波器的几何形状变形，使得其不再遵循理想场U（r，＆phgr; z）的等电位，或者通过添加失真场（电 或磁性）。 扰动的幅度使得至少一些捕获的离子具有大于零但小于2的绝对相位扩散; 弧度超过离子检测周期Tm。

    TANDEM TIME-OF-FLIGHT MASS SPECTROMETER
    90.
    发明授权
    TANDEM TIME-OF-FLIGHT MASS SPECTROMETER 失效
    串联飞行时间质谱仪

    公开(公告)号：EP0584262B1

    公开(公告)日：1997-07-16

    申请号：EP92913066.4

    申请日：1992-05-15

    Applicant: THE JOHNS HOPKINS UNIVERSITY

    Inventor： COTTER, Robert, J. ,  CORNISH, Timothy, J.

    IPC: H01J49/40

    CPC classification number: H01J49/004 ,  H01J49/406

    Abstract: A tandem time-of-flight mass spectrometer comprises a grounded vacuum housing (7), two reflecting-type mass analyzers (1, 2) coupled via a collision chamber (15) and flight channels (3, 4) electrically floated with respect to the grounded vacuum housing (7). The first reflecting-type mass analyzer (1) receives ionized molecules (ions). These ions pass through the flight channel (3) of the first reflecting-type mass analyzer (1) and are fragmented in the collision chamber (15). The fragmented ions pass through the flight channel (4) of the second reflecting-type mass analyzer (2). Detectors (03, 04) disposed in the collision chamber (15) and in the second reflecting-type mass analyzer (2) detect the spectrum of the first reflecting-type mass analyzer (1) and the spectra of the tandem time-of-flight mass analyzer (100) respectively.

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