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    COATING MATERIALS AND METHODS FOR ENHANCED RELIABILITY
    1.
    发明申请
    COATING MATERIALS AND METHODS FOR ENHANCED RELIABILITY 审中-公开
    涂层材料和增强可靠性的方法

    公开(公告)号：WO2016011041A1

    公开(公告)日：2016-01-21

    申请号：PCT/US2015/040393

    申请日：2015-07-14

    Applicant: ENKI TECHNOLOGY, INC.

    Inventor： BROPHY, Brenor, L. ,  MAGHSOODI, Sina ,  KOPCZYNSKI, Kevin

    IPC: H01L31/0216 ,  H01L31/042 ,  H01L31/18

    CPC classification number: H01L31/048 ,  C03C17/30 ,  C03C2217/425 ,  C03C2217/73 ,  C09D183/04 ,  C09D183/08 ,  G02B1/113 ,  G02B27/0006 ,  G02B2207/109 ,  H01L31/0488 ,  Y02E10/50

    Abstract: Glass coating materials and methods are disclosed for the coating of glass substrates used in the manufacturer of photovoltaic solar modules such that the coating enhances the reliability of the module by reducing its susceptibility to potential induced degradation (PID). Coating materials are disclosed that reduce soiling on the front surface of the glass; that increase the surface resistivity of the glass and that repel moisture and that seal the surface from the ingress of moisture. Further electrically conductive coatings are disclosed that reduce the electric field between the front and back surfaces of the glass and hence reduce ion mobility within the glass and transport from the interior glass surface to the solar cell. There are additional configuration choices for fine tuning associated with separately optimizing the exterior and interior glass coating. Finally, coating processes and methods are disclosed for coating glass substrates with the disclosed materials.

    Abstract translation: 公开了用于光伏太阳能模块制造商中使用的玻璃基板的涂覆的玻璃涂层材料和方法，使得涂层通过降低其对潜在的诱导退化（PID）的敏感性来增强模块的可靠性。 公开了减少玻璃前表面污染的涂料; 这增加了玻璃的表面电阻率并且排斥了水分，并且使表面与水分的进入密封。 公开了另外的导电涂层，其减少玻璃的前表面和后表面之间的电场，并因此降低玻璃内的离子迁移率并从内部玻璃表面传输到太阳能电池。 还有另外的配置选择，用于与外部和内部玻璃涂层分开优化相关的微调。 最后，公开了用所公开的材料涂覆玻璃基板的涂布方法和方法。

    TUNING THE ANTI-REFLECTIVE, ABRASION RESISTANCE, ANTI-SOILING AND SELF-CLEANING PROPERTIES OF TRANSPARENT COATINGS FOR DIFFERENT GLASS SUBSTRATES AND SOLAR CELLS
    2.
    发明申请
    TUNING THE ANTI-REFLECTIVE, ABRASION RESISTANCE, ANTI-SOILING AND SELF-CLEANING PROPERTIES OF TRANSPARENT COATINGS FOR DIFFERENT GLASS SUBSTRATES AND SOLAR CELLS 审中-公开
    调整不同玻璃基板和太阳能电池透明涂层的抗反射，耐磨性，防污染和自清洁性能

    公开(公告)号：WO2014193513A3

    公开(公告)日：2015-02-19

    申请号：PCT/US2014022857

    申请日：2014-03-10

    Applicant: ENKI TECHNOLOGY INC

    Inventor： NAIR VINOD ,  BROPHY BRENOR L

    IPC: C03C17/00 ,  G02B1/10

    CPC classification number: C03C17/30 ,  C03C17/002 ,  C03C2217/732 ,  C03C2217/76 ,  C03C2218/36 ,  G02B1/11 ,  H01L31/048 ,  Y02E10/50 ,  Y10T428/265 ,  Y10T428/315 ,  Y10T428/31612

    Abstract: Functionalized coatings preferentially coated on the tin-side of float glass used in solar and other applications are disclosed. Coating compositions include silane-based precursors that are used to form coatings through a sol-gel process including hydrolyzed alkoxysilane-based sols. The coatings are characterized by anti-reflective, abrasion resistant, and anti-soiling properties and the tunability of those properties with respect to different applications. The coatings formed from the compositions described herein have wide application, including, for example, use as abrasion resistant coatings on the outer glass of solar modules, wherein the coating adheres through siloxane linkages. In some embodiments, when applied to glass and cured at a temperature of less than 300°C, the dried sol gel has abrasion resistance sufficient to pass standard EN-1096-2 with a loss of transmission of no more than 0.5% and enables a post-test light transmission gain of greater than 1% as compared to uncoated glass.

    Abstract translation: 公开了在太阳能和其他应用中使用的浮法玻璃的锡侧上优先涂覆的功能化涂层。 涂料组合物包括硅烷基前体，其用于通过包括水解的烷氧基硅烷基溶胶的溶胶 - 凝胶法形成涂层。 涂层的特征在于抗反射性，耐磨性和防污性以及这些性质相对于不同应用的可调性。 由本文描述的组合物形成的涂层具有广泛的应用，包括例如用作太阳能模块外玻璃上的耐磨涂层，其中涂层粘附通过硅氧烷键。 在一些实施方案中，当应用于玻璃并在小于300℃的温度下固化时，干燥的溶胶凝胶具有足以通过标准EN-1096-2的耐磨性，其传输损失不超过0.5％ 与未涂覆玻璃相比，后测光透射增益大于1％。

    GLASS COATING SPECIFICATION LIBRARY
    4.
    发明申请
    GLASS COATING SPECIFICATION LIBRARY 审中-公开
    玻璃涂料规范图书馆

    公开(公告)号：WO2016043969A1

    公开(公告)日：2016-03-24

    申请号：PCT/US2015/047979

    申请日：2015-09-01

    Applicant: ENKI TECHNOLOGY, INC.

    Inventor： BROPHY, Brenor L. ,  KOPCZYNSKI, Kevin

    IPC: C03C17/00

    CPC classification number: G06F19/702 ,  G01N33/386 ,  G01W1/00

    Abstract: Disclosed herein are methods for characterizing environmental factors that affect glass substrates and then based on those factors, determining the optimal coatings to be applied to glass substrates used in solar energy modules and the like to enhance efficiency, general performance and to reduce operational and maintenance costs. Also disclosed are methods and apparatus for applying coatings to flat substrates including substrate pre-treatment processes, coating processes including flow coating and roll coating; coating curing processes including skin-curing using hot-air knives. Also disclosed are coating compositions and formulations for highly tunable, durable, highly abrasion resistant functionalized anti-reflective coatings.

    Abstract translation: 本文公开了用于表征影响玻璃基板的环境因素的方法，然后基于这些因素，确定应用于太阳能模块等中使用的玻璃基板的最佳涂层以提高效率，一般性能并降低操作和维护成本 。 还公开了用于将涂层施加到平坦基底的方法和装置，包括基底预处理工艺，包括流动涂覆和辊涂在内的涂覆工艺; 涂层固化过程包括使用热风刀进行皮肤固化。 还公开了用于高度可调，耐用，高耐磨功能的抗反射涂层的涂料组合物和配方。

    HIGH GAIN DURABLE ANTI-REFLECTIVE COATING
    5.
    发明申请
    HIGH GAIN DURABLE ANTI-REFLECTIVE COATING 审中-公开
    高增益耐反射涂层

    公开(公告)号：WO2016011071A2

    公开(公告)日：2016-01-21

    申请号：PCT/US2015040440

    申请日：2015-07-14

    Applicant: ENKI TECHNOLOGY INC

    Inventor： MAGHSOODI SINA ,  BROPHY BRENOR L ,  COLSON THOMAS E ,  GONSALVES PETER R ,  ABRAMS ZE EV R ,  MOVASSAT MEISAM ,  VARADARAJAN ARAVAMUTHAN

    IPC: C08G77/04 ,  C08J3/07 ,  C08L83/04 ,  C09D183/04

    CPC classification number: C09D183/04 ,  C03C17/30 ,  C03C2217/425 ,  C03C2217/73 ,  C09D183/08 ,  Y02P20/582

    Abstract: Disclosed herein are polysilsesquioxane-based anti-reflective coating (ARC) compositions, methods of preparation, and methods of deposition on a substrate. In one embodiment, the polysilsesquioxane of this disclosure is prepared in a two-step process of acid catalyzed hydrolysis of organoalkoxysilane followed by addition of tetralkoxysilane that generates silicone polymers with >40 mol% silanol based on Si- NMR. These high silanol siloxane polymers are stable and have a long shelf-life in polar organic solvents at room temperature. Also disclosed are low refractive index ARC made from these compositions with and without additives such as porogens, templates, thermal radical initiator, photo radical initiators, crosslinkers, Si-OH condensation catalyst and nano-fillers. Also disclosed are methods and apparatus for applying coatings to flat substrates including substrate pre-treatment processes, coating processes and coating curing processes including skin-curing using hot-air knives. Also disclosed are coating compositions and formulations for highly tunable, durable, highly abrasion-resistant functionalized anti-reflective coatings.

    Abstract translation: 本文公开了基于聚倍半硅氧烷的抗反射涂层（ARC）组合物，制备方法和沉积在基材上的方法。 在一个实施方案中，本公开的聚倍半硅氧烷是以有机烷氧基硅烷的酸催化水解的两步法制备的，然后加入基于Si-NMR产生具有> 40mol％硅烷醇的硅氧烷聚合物的四氢化硅烷。 这些高硅烷醇硅氧烷聚合物是稳定的，并且在室温下在极性有机溶剂中具有长的保质期。 还公开了由具有和不具有添加剂的这些组合物制成的低折射率ARC，例如致孔剂，模板，热自由基引发剂，光自由基引发剂，交联剂，Si-OH缩合催化剂和纳米填料。 还公开了用于将涂层施加到平面基板上的方法和装置，包括基板预处理工艺，涂覆工艺和涂层固化工艺，包括使用热风刀的皮肤固化。 还公开了用于高度可调，耐用，高耐磨性的功能化抗反射涂层的涂料组合物和制剂。

    TUNING THE ANTI-REFLECTIVE, ABRASION RESISTANCE, ANTI-SOILING AND SELF-CLEANING PROPERTIES OF TRANSPARENT COATINGS FOR DIFFERENT GLASS SUBSTRATES AND SOLAR CELLS
    6.
    发明申请
    TUNING THE ANTI-REFLECTIVE, ABRASION RESISTANCE, ANTI-SOILING AND SELF-CLEANING PROPERTIES OF TRANSPARENT COATINGS FOR DIFFERENT GLASS SUBSTRATES AND SOLAR CELLS 审中-公开
    调整不同玻璃基板和太阳能电池的透明涂层的抗反射，耐磨性，防污染和自清洁性能

    公开(公告)号：WO2014193513A2

    公开(公告)日：2014-12-04

    申请号：PCT/US2014/022857

    申请日：2014-03-10

    Applicant: ENKI TECHNOLOGY, INC.

    Inventor： NAIR, Vinod ,  BROPHY, Brenor L.

    IPC: C03C17/00 ,  G02B1/10

    CPC classification number: C03C17/30 ,  C03C17/002 ,  C03C2217/732 ,  C03C2217/76 ,  C03C2218/36 ,  G02B1/11 ,  H01L31/048 ,  Y02E10/50 ,  Y10T428/265 ,  Y10T428/315 ,  Y10T428/31612

    Abstract: Functionalized coatings preferentially coated on the tin-side of float glass used in solar and other applications are disclosed. Coating compositions include silane-based precursors that are used to form coatings through a sol-gel process including hydrolyzed alkoxysilane-based sols. The coatings are characterized by anti-reflective, abrasion resistant, and anti-soiling properties and the tunability of those properties with respect to different applications. The coatings formed from the compositions described herein have wide application, including, for example, use as abrasion resistant coatings on the outer glass of solar modules, wherein the coating adheres through siloxane linkages. In some embodiments, when applied to glass and cured at a temperature of less than 300°C, the dried sol gel has abrasion resistance sufficient to pass standard EN-1096-2 with a loss of transmission of no more than 0.5% and enables a post-test light transmission gain of greater than 1% as compared to uncoated glass.

    Abstract translation: 公开了在太阳能和其他应用中使用的浮法玻璃的锡侧上优先涂覆的功能化涂层。 涂料组合物包括硅烷基前体，其用于通过包括水解的烷氧基硅烷基溶胶的溶胶 - 凝胶法形成涂层。 涂层的特征在于抗反射性，耐磨性和抗污染性以及这些性质相对于不同应用的可调性。 由本文描述的组合物形成的涂层具有广泛的应用，包括例如用作太阳能模块外玻璃上的耐磨涂层，其中涂层粘附通过硅氧烷键。 在一些实施方案中，当应用于玻璃并在低于300℃的温度下固化时，干燥的溶胶凝胶具有足以通过标准EN-1096-2的耐磨性，其传输损失不超过0.5％ 与未涂覆玻璃相比，后测光透射增益大于1％。

    MULTI-LAYER COATINGS
    7.
    发明申请
    MULTI-LAYER COATINGS 审中-公开
    多层涂料

    公开(公告)号：WO2016064494A3

    公开(公告)日：2016-08-04

    申请号：PCT/US2015050561

    申请日：2015-09-17

    Applicant: ENKI TECHNOLOGY INC

    Inventor： MAGHSOODI SINA ,  BROPHY BRENOR L ,  ABRAMS ZE EV R ,  GONSALVES PETER R

    IPC: B05D5/06 ,  B05D7/00 ,  B05D7/24

    CPC classification number: C03C17/3417 ,  C03C17/34 ,  C03C2217/734 ,  C03C2217/76 ,  C03C2217/78 ,  C03C2218/113

    Abstract: Disclosed herein are coating materials and methods for applying a top-layer coating that is durable, abrasion resistant, highly transparent, hydrophobic, low-friction, moisture-sealing, anti-soiling, and self-cleaning to an existing conventional high temperature anti-reflective coating. The top coat imparts superior durability performance and new properties to the under-laying conventional high temperature anti-reflective coating without reducing the anti-reflectiveness of the coating. Methods and data for optimizing the relative thickness of the under-layer high temperature anti-reflective coating and the top-layer thickness for optimizing optical performance are also disclosed.

    Abstract translation: 本文公开了用于将耐用，耐磨，高度透明，疏水，低摩擦，湿气密封，防污染和自清洁的顶层涂层施加到现有常规高温抗蚀剂的涂料和方法， 反光涂层。 顶层涂层赋予了低成本的常规高温抗反射涂层优异的耐久性能和新特性，而不会降低涂层的抗反射性。 还公开了用于优化底层高温抗反射涂层的相对厚度和优化光学性能的顶层厚度的方法和数据。

    MULTI-LAYER COATINGS
    8.
    发明申请
    MULTI-LAYER COATINGS 审中-公开
    多层涂层

    公开(公告)号：WO2016064494A2

    公开(公告)日：2016-04-28

    申请号：PCT/US2015/050561

    申请日：2015-09-17

    Applicant: ENKI TECHNOLOGY, INC.

    Inventor： MAGHSOODI, Sina ,  BROPHY, Brenor L. ,  ABRAMS, Ze'ev R. ,  GONSALVES, Peter R.

    IPC: B05D5/06 ,  B05D7/24 ,  B05D7/00

    CPC classification number: C03C17/3417 ,  C03C17/34 ,  C03C2217/734 ,  C03C2217/76 ,  C03C2217/78 ,  C03C2218/113

    Abstract: Disclosed herein are coating materials and methods for applying a top-layer coating that is durable, abrasion resistant, highly transparent, hydrophobic, low-friction, moisture-sealing, anti-soiling, and self-cleaning to an existing conventional high temperature anti-reflective coating. The top coat imparts superior durability performance and new properties to the under-laying conventional high temperature anti-reflective coating without reducing the anti-reflectiveness of the coating. Methods and data for optimizing the relative thickness of the under-layer high temperature anti-reflective coating and the top-layer thickness for optimizing optical performance are also disclosed.

    Abstract translation: 这里公开了用于施加耐用，耐磨，高度透明，疏水，低摩擦，防潮，防污和自清洁的顶层涂层的涂层材料和方法 到现有的常规高温抗反射涂层。 顶层涂层赋予底铺常规高温抗反射涂层优越的耐久性能和新的性能，而不会降低涂层的抗反射性。 还公开了用于优化底层高温抗反射涂层的相对厚度和用于优化光学性能的顶层厚度的方法和数据。

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