PYRIDINE-2,3-DICARBOXIMIDES, THEIR PREPARATION AND THEIR USE FOR CONTROLLING UNDESIRED PLANT GROWTH

    公开(公告)号:CA2138756A1

    公开(公告)日:1995-06-23

    申请号:CA2138756

    申请日:1994-12-21

    Abstract: Pyridine-2,3-dicarboximides of the general formula I I where R1 is hydrogen, alkoxy or unsubstituted or substituted alkyl (excluding C1-C4-dialkylaminoalkyl if one of the radicals R2, R3 or R4 = NH2 or OH), cycloalkyl, alkenyl or alkynyl, at least one radical R2, R3 or R4 is nitro, an OR5 or NR6R7 group, and the remaining radicals R2, R3 and R4 are identical or different and are hydrogen, halogen, cyano, unsubstituted or substituted alkyl, benzyl, cycloalkyl, alkenyl, alkynyl, alkoxy, phenoxy or phenylthio, a 5- or 6-membered heterocyclic radical having one or two heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen, or unsubstituted or substituted phenyl; R5 is hydrogen, C1-C4-alkylcarbonyl, C1-C4-haloalkylcarbonyl, C1-C4-alkoxycarbonyl, C1-C4-alkoxy-C2-C4-alkoxycarbonyl, C1-C4-alkylcarbamoyl, C1-C4-dialkylcarbamoyl, C1-C4-alkylsulfonyl, C1-C4-haloalkylsulfonyl, sulfamoyl, C1-C4-alkylaminosulfonyl, C1-C4-dialkylaminosulfonyl, phenylsulfonyl, which can be substituted one to three times by C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, halogen, cyano or nitro; R6 is hydrogen, C1-C4-alkyl, C1-C4-alkoxy or together with R7 C=S and R7 is hydrogen, C1-C4-alkyl, C1-C4-alkylcarbonyl, C1-C4-halo-alkylcarbonyl, C1-C4-alkoxycarbonyl, C1-C4-alkoxy-C2-C4-alkoxycar-bonyl, C1-C4-alkylcarbamoyl, C1-C4-dialkylcarbamoyl, C1-C4-alkyl-sulfonyl, C1-C4-haloalkylsulfonyl, sulfamoyl, C1-C4-alkylamino-sulfonyl, C1-C4-dialkylaminosulfonyl, phenylsulfonyl, which can be substituted one to three times by C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, halogen, cyano or nitro; excluding 6-amino-5-cyano-5-phenyl-2,3-pyridinecarboximide; and their agriculturally utilizable salts are described.

    ACYLAMINO-SUBSTITUTED ISOXAZOLE OR ISOTHIAZOLE DERIVATIVES, THEIR PREPARATION AND THEIR USE

    公开(公告)号:CA2130620A1

    公开(公告)日:1995-02-25

    申请号:CA2130620

    申请日:1994-08-22

    Abstract: Acylamino-substituted isoxazole or isothiazole derivatives, their preparation and their use Acylamino-substituted isoxazole or isothiazole derivatives of the formula I I where X is oxygen or sulfur; R1 is unsubstituted or substituted alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl or phenyl; R2 is CN, CONH2, CSNH2, SCN or haloalkyl; R3 is hydrogen or unsubstituted or substituted alkyl or cycloalkyl; R4 is alkoxy, unsubstituted or substituted alkyl, cycloalkenyl, cycloalkyl, alkenyl or alkynyl, an unsubstituted or substituted 5-membered or 6-membered heterocyclic radical or unsubstituted or substituted phenyl; haloalkyl, alkoxy, haloalkoxy, alkylthio and/or haloalkylthio, and agriculturally useful salts of the isoxazole or isothiazole derivatives I, with the exception of 3-methyl-4-thiocyanato-5-trifluoroacetylaminoisoxazole, 3-methyl-4-thiocyanato-5-benzoylaminoisoxazole, 3-methyl-4-cyano-5-fur-2-ylcarbonylaminoisoxazole, 3-ethyl-4-cyano-5-fur-2-ylcarbonylaminoisoxazole, 3-methyl-4-cyano-5-benzoylaminoisothiazole, 3-methyl-4-carboxamido-5-acetylaminoisothiazole, 3-methyl-4-carboxamido-5-(4-chlorobenzoyl)-aminoisothiazole, 3-methyl-4-carboxamido-5-(2-chlorobenzoyl)-aminoisothiazole, 3-methyl-4-carboxamido-5-benzoylaminoisothiazole, 3-phenyl-4-cyano-5-benzoylaminoisoxazole, 3-phenyl-4-cyano-5-(4-chlorobenzoyl)-aminoisoxazole, 3-phenyl-4-cyano-5-(4-methylbenzoyl)-aminoisosazole and 3-phenyl-4-cyano-5-propionylaminoisoxazole, agent containing the compounds I and their use as herbicides.

    SUBSTITUTED PYRIMIDINE DERIVATIVES AND THEIR USE FOR CONTROLLING UNDESIRABLE PLANT GROWTH

    公开(公告)号:CA2073883A1

    公开(公告)日:1993-01-17

    申请号:CA2073883

    申请日:1992-07-15

    Abstract: O.Z. 0050/42552 Pyrimidine derivatives of the formula I I where the substituents have the following meanings: R1 is hydrogen or alkyl; A is a substituted or unsubstituted bi- or tricyclic carbo- or heterocyclic radical which may contain one or several double bonds; CR2R3R4, where R2 and R3 are hydrogen or substituted or unsubstituted alkyl and R4 is substituted or unsubstituted naphthyl with the exception of 1-naphthyl, substituted or unsubstituted cycloalkyl, R4 may also, if Y is NH2 and X is not trifluoromethyl, be cyclopropyl, R4 may also be substituted or unsubstituted bicycloalkyl or mono- or bicyclic heterocyclyl having 1 to 3 heteroatoms selected from the group consisting of oxygen, sulfur and nitrogen, with the exception of 2-furyl, 2-thienyl, 2-pyrrolyl, 2-N-methylpyrrolyl, 2,3-pyridyl, 2-thiolanyl, 2-perhydropyrrolyl and 2-perhydro-N-methylpyrrolyl, and if R2 and R3 are each hydrogen, further, R4 may also, if R2 and/or R3 are substituted by methoxy or methylthio, be phenyl which may carry the following groups: alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio, halogen, nitro or cyano; X is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio or halo- alkylthio; Y is halogen, alkyl, haloalkyl, alkylthio, Y may also, if A is thienyl ethyl, furylethyl or a bicyclic radical with the exception of naphthyl, quinolyl and isoquinolyl or R2 is trifluoromethyl, R3 is hydrogen and R4 is phenyl substituted as mentioned above, be alkoxy, C1-C3-alkoxy-C2-C3-alkoxy, or C1-C3-alkylthio-C2-C3-alkoxy, O.Z. 0050/42552 and Y may also be NR5R6, where R5 is hydrogen, alkyl, haloalkyl, alkoxy, alkoxyalkyl or cycloalkyl and R6 is hydrogen, except when R5 is methoxy and R4 is phenyl, or alkyl; and addition salts thereof with organic or inorganic acids.

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