公开(公告)号：ID20265A

公开(公告)日：1998-11-12

申请号：ID980350

申请日：1998-03-10

Applicant: DAICEL CHAEMICAL IND LTD ,  ISHII YASUTAKA

Inventor： NAKANO TATSUYA ,  ISHII YASUTAKA

IPC: B01J31/02 ,  B01J31/04 ,  C07B41/02 ,  C07B41/06 ,  C07B61/00 ,  C07C27/12 ,  C07C29/50 ,  C07C31/12 ,  C07C45/28 ,  C07C45/33 ,  C07C49/08 ,  C07C31/02

Abstract: A non-cyclic branched aliphatic hydrocarbon (e.g., isobutane) is oxidized with oxygen in the presence of an oxidation catalyst comprising an imide compound of the following formula (1) (e.g., N-hydroxyphthalimide) or an oxidation catalyst comprising the imide compound and a co-catalyst (e.g., a transition metal compound of selected from Group 3A, 4A, 5A, 6A, 7A, 8 and 1B elements of the Periodic Table of elements), for the formation of an oxide (e.g., t-butanol, acetone): wherein R and R represent a substituent such as a hydrogen atom or a halogen atom, or R and R may together form a double bond or an aromatic or nonaromatic 5- to 12-membered ring, X is O or OH, and n is 1 to 3.

公开(公告)号：EP0878458A1

公开(公告)日：1998-11-18

申请号：EP98108533.5

申请日：1998-05-11

Applicant: Daicel Chemical Industries, Ltd. ,  Ishii, Yasutaka

Inventor： Ishii, Yasutaka ,  Nakano, Tatsuya

IPC: C07C51/23 ,  C07C55/02 ,  C07C67/39 ,  C07C69/00 ,  C07D309/30

CPC classification number: C07D315/00 ,  B01J31/006 ,  B01J31/0247 ,  B01J31/2208 ,  B01J2231/70 ,  B01J2531/845 ,  C07C51/23 ,  C07C51/54 ,  C07C67/39 ,  C07D201/08 ,  C07D309/30 ,  C07D311/86 ,  C07C55/02 ,  C07C63/16

Abstract: An ether is oxidized with oxygen under an oxidation catalyst comprising an imide compound (such as N-hydroxyphthalimide) or the imide compound and a co-catalyst to produce the corresponding chain or cyclic ester or anhydride. The co-catalyst may be a transition metal compound. The above process provides a process for oxidizing an ether by oxygen efficiently to produce the corresponding oxide (such as an ester, an hydride) with high conversion and selectivity.

Abstract translation: 在包含酰亚胺化合物（如N-羟基邻苯二甲酰亚胺）或酰亚胺化合物的氧化催化剂和助催化剂下，用氧氧化醚，生成相应的链或环状酯或酸酐。 助催化剂可以是过渡金属化合物。 上述方法提供了一种通过氧气有效氧化醚的方法，以高转化率和选择性产生相应的氧化物（如酯，氢化物）。

公开(公告)号：EP0897747A1

公开(公告)日：1999-02-24

申请号：EP98900216.7

申请日：1998-01-13

Applicant: Daicel Chemical Industries, Ltd. ,  Ishii, Yasutaka

Inventor： ISHII, Yasutaka ,  NAKANO, Tatsuya ,  SAKAGUCHI, Satoshi

IPC: B01J31/02 ,  B01J31/26 ,  C07C201/08 ,  C07C51/10 ,  C07C61/28 ,  C07C211/35 ,  C07C265/10 ,  C07C205/55 ,  C07C62/06 ,  C07C271/24 ,  C07B43/02 ,  C07B41/08

CPC classification number: C07C45/36 ,  B01J31/006 ,  B01J31/0247 ,  B01J31/2208 ,  B01J2231/70 ,  B01J2531/16 ,  B01J2531/72 ,  B01J2531/842 ,  B01J2531/845 ,  C07B41/08 ,  C07B43/02 ,  C07C51/10 ,  C07C67/12 ,  C07C69/757 ,  C07C205/04 ,  C07C205/05 ,  C07C205/06 ,  C07C205/18 ,  C07C205/55 ,  C07C211/35 ,  C07C211/37 ,  C07C215/42 ,  C07C229/50 ,  C07C233/10 ,  C07C233/14 ,  C07C233/23 ,  C07C233/41 ,  C07C233/52 ,  C07C233/58 ,  C07C233/62 ,  C07C235/40 ,  C07C235/82 ,  C07C237/24 ,  C07C265/10 ,  C07C271/24 ,  C07C2603/74 ,  C07C49/78 ,  C07C61/29 ,  C07C61/135

Abstract: In the presence of an imide compound (e.g., N-hydroxyphthalimide) shown by the following formula (1):
   wherein R 1 and R 2 represent a hydrogen atom, a halogen atom, an alkyl group, an aryl group and a cycloalkyl group, and R 1 and R 2 may bond together to form a double bond, or an aromatic or non-aromatic ring, and Y is an O or OH, and n denotes 1 to 3;
a substrate is allowed to contact with at least one reactant selected from (i) a nitrogen oxide and (ii) a mixture of carbon monoxide and oxygen to be introduced with at least one functional group selected from a nitro group and a carboxyl group. The nitrogen oxide includes, for example, a compound represented by the formula N x O y (e.g., N 2 O 3 , NO 2 ). The substrate includes, for example, a compound having a methine carbon atom (e.g., adamantane), a compound having a methyl group or a methylene group at an adjacent moiety of an aromatic ring. According to such reaction, the substrate can be efficiently nitrated or carboxylated even in a mild or moderate condition.

Abstract translation: 在下式（1）所示的酰亚胺化合物（例如N-羟基邻苯二甲酰亚胺）存在下，其中R 1和R 2表示氢原子，卤素原子，烷基， 芳基和环烷基，R 1和R 2可以键合在一起形成双键，或芳族或非芳香环，Y是O或OH，n表示1至3; 允许底物与选自（i）氮氧化物和（ii）一氧化碳和氧气的混合物中的至少一种反应物接触，以将至少一种选自硝基和羧基的官能团引入。 氮氧化物包括例如由式N x O y表示的化合物（例如，N 2 O 3，NO 2）。 底物包括例如具有次甲基碳原子的化合物（例如金刚烷），在芳环的相邻部分具有甲基或亚甲基的化合物。 根据这种反应，即使在温和或中等条件下，底物也能被有效地硝化或羧化。

公开(公告)号：EP0990631A1

公开(公告)日：2000-04-05

申请号：EP99909321.4

申请日：1999-03-23

Applicant: Daicel Chemical Industries, Ltd. ,  Ishii, Yasutaka

Inventor： ISHII, Yasutaka ,  NAKANO, Tatsuya

IPC: C07B41/00 ,  C07B33/00 ,  C07D301/06 ,  C07D303/04 ,  C07D303/14 ,  C07D303/16 ,  B01J31/02

CPC classification number: C07B41/12 ,  B01J31/006 ,  B01J31/0231 ,  B01J31/0247 ,  B01J31/0271 ,  B01J31/20 ,  B01J31/2208 ,  B01J2231/70 ,  B01J2231/72 ,  B01J2531/64 ,  B01J2531/845 ,  C07D315/00

Abstract: According to the inventive co-oxidation process of organic compounds, (A) a compound selected from (A1) a compound having a non-aromatic ethylenic bond and (A2) a ketone or an alcohol corresponding to the ketone is oxidized by molecular oxygen in the presence of N-hydroxyphthalimide or another imide compound and in the coexistence of (B) a compound oxidizable by the imide compound and oxygen and different from the compound (A). As the compound (B), (a) primary or secondary alcohols (e.g., benzhydrol, cyclohexanol), (b) compounds each having a carbon-hydrogen bond at the adjacent position to an unsaturated bond (e.g., tetralin, ethylbenzene) and the like can be used. According to this process, a corresponding epoxy compound from the compound (A1) having a non-aromatic ethylenic bond, and a corresponding ester or lactone from the ketone or its corresponding alcohol (A2) can be obtained in satisfactory yields.

Abstract translation: 根据本发明的有机化合物的共氧化方法，（A）选自（A1）具有非芳香族烯键的化合物和（A2）酮或与酮相应的醇的化合物被分子氧氧化 存在N-羟基邻苯二甲酰亚胺或其它酰亚胺化合物，并且（B）可由酰亚胺化合物氧化并且不同于化合物（A）的化合物共存。 作为化合物（B），（a）伯或仲醇（例如二苯基甲醇，环己醇），（b）在与不饱和键相邻的位置上具有碳 - 氢键的化合物（例如，四氢化萘，乙苯）和 喜欢可以使用。 根据该方法，可以以令人满意的产率获得来自具有非芳香族烯键的化合物（A1）和来自酮或其相应的醇（A2）的相应的酯或内酯的相应的环氧化合物。

公开(公告)号：EP0850915A1

公开(公告)日：1998-07-01

申请号：EP97122787.1

申请日：1997-12-23

Applicant: DAICEL CHEMICAL INDUSTRIES, LTD. ,  Ishii, Yasutaka

Inventor： Nakano, Tatsuya ,  Sakaguchi, Satoshi ,  Ishii, Yasutaka

IPC: C07C201/08 ,  C07C205/04 ,  C07C205/06 ,  C07C205/05

CPC classification number: C07B43/02 ,  C07C201/08 ,  C07C2603/74 ,  C07C205/04 ,  C07C205/05

Abstract: The method provides nitro compounds at a high conversion and selectivity by nitrating substrates under comparatively mild conditions in the absence of catalysts. Organic substrates are nitrated using no catalysts or ozone, but using (1) at least one nitrogen compound selected from N 2 O or NO and oxygen. It is advantageous for the nitration reaction to employ a nitrogen compound obtained by a reaction of the nitrogen compound with oxygen, particularly a nitrogen oxide comprising N 2 O 3 as a main component. Additionally, organic substrates are nitrated using (2) NO 2 . The substrates include a compound having a methine-carbon atom, and a compound having a methyl group or methylene group in an adjacent position to an aromatic ring.

公开(公告)号：EP0927711A1

公开(公告)日：1999-07-07

申请号：EP98905769.0

申请日：1998-03-05

Applicant: Daicel Chemical Industries, Ltd. ,  Ishii, Yasutaka

Inventor： ISHII, Yasutaka ,  NAKANO, Tatsuya ,  HIRAI, Naruhisa

IPC: C07C35/37 ,  C07C29/48 ,  C07C233/23 ,  C07C233/32 ,  C07C62/06 ,  C07C62/22 ,  C07C69/757 ,  C07C69/16 ,  C07C69/753 ,  C07C69/96 ,  C07C65/10 ,  C07C205/18 ,  C07C205/45 ,  C07C205/41 ,  C07C205/55 ,  C07C233/74 ,  C07C235/14 ,  C07C219/24 ,  C07C271/34 ,  C07B41/00

CPC classification number: C07C29/50 ,  C07C35/37 ,  C07C62/06 ,  C07C62/24 ,  C07C67/05 ,  C07C67/08 ,  C07C67/29 ,  C07C67/31 ,  C07C68/02 ,  C07C69/757 ,  C07C69/96 ,  C07C205/18 ,  C07C205/41 ,  C07C205/55 ,  C07C219/24 ,  C07C233/23 ,  C07C233/32 ,  C07C233/74 ,  C07C235/40 ,  C07C265/10 ,  C07C271/34 ,  C07C2603/74 ,  C07C69/753 ,  C07C69/157

Abstract: In the presence of an imide compound (e.g., N-hydroxyphthalimide) shown by the formula (2):
   wherein R 1 and R 2 independently represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, a cycloalkyl group; or R 1 and R 2 may bond together to form a double bond or an aromatic or non-aromatic ring; Y is O or OH and n = 1 to 3;
or the imide compound and a co-catalyst (e.g., a transition metal compound), an adamantane derivative having a functional group such as a nitro group, an amino group, a hydroxyl group, a carboxyl group, a hydroxymethyl group and an isocyanato group is oxidized with oxygen. According to the above method, an adamantane derivative having a hydroxyl group together with a functional group such as a nitro group, an amino group, a hydroxyl group, a carboxyl group, a hydroxymethyl group and an isocyanato group is efficiently obtained.

Abstract translation: 在式（2）所示的酰亚胺化合物（例如，N-羟基邻苯二甲酰亚胺）存在下，其中R 1和R 2独立地表示氢原子，卤素原子，烷基， 芳基，环烷基; 或R 1和R 2可以键合在一起形成双键或芳族或非芳族环; Y为O或OH且n = 1至3; 或酰亚胺化合物和助催化剂（例如过渡金属化合物），具有硝基，氨基，羟基，羧基，羟甲基和异氰酸基的官能团的金刚烷衍生物 被氧气氧化。 根据上述方法，有效地获得具有羟基的金刚烷衍生物与硝基，氨基，羟基，羧基，羟甲基和异氰酸基等官能团。

公开(公告)号：EP0878234A3

公开(公告)日：1999-01-07

申请号：EP98108532.7

申请日：1998-05-11

Applicant: Daicel Chemical Industries, Ltd. ,  Ishii, Yasutaka

Inventor： Ishii, Yasutaka ,  Nakano, Tatsuya

IPC: B01J31/02

CPC classification number: B01J31/34 ,  B01J31/006 ,  B01J31/0247 ,  B01J31/2208 ,  B01J31/36 ,  B01J2231/70 ,  B01J2531/56 ,  C07C29/50 ,  C07C45/33 ,  C07C45/34 ,  C07C45/36 ,  C07C49/453 ,  C07C2603/74 ,  C07C35/37

Abstract: A substrate is contacted with oxygen in the presence of the imide compound shown by the following formula (1) (N-hydroxyphthalimide) and a strong acid, or the imide compound, the strong acid and a co-catalyst (e.g., a transition metal compound) to oxygenate the substrate with high conversion and selectivity:
   wherein R 1 and R 2 represent a substituent such as a hydrogen atom or a halogen atom, an alkyl group, an aryl group or a cycloalkyl group, or R 1 and R 2 may bond together to form a double bond or an aromatic or nonaromatic ring, X is O or OH, and n is 1 to 3. The substrate comprises, for example, at least one compound selected from (a) a compound having a methyl group or a methylene group at an adjacent site of an unsaturated bond, (b) a homo- or hetero cyclic compound having a methylene group, (c) a compound having a methine carbon atom, (d) a compound having a methyl group or a methylene group at an adjacent site of an aromatic ring and (e) a compound having a methyl group or a methylene group at an adjacent site of a carbonyl group.

公开(公告)号：EP0864555A1

公开(公告)日：1998-09-16

申请号：EP98103834.2

申请日：1998-03-04

Applicant: Daicel Chemical Industries, Ltd. ,  Ishii, Yasutaka

Inventor： Nakano,Tatsuya ,  Ishii,Yasutaka

IPC: C07C27/12 ,  C07C31/02 ,  C07C49/04

CPC classification number: C07C45/33 ,  C07C29/50 ,  C07C31/12

Abstract: A non-cyclic branched aliphatic hydrocarbon (e.g., isobutane) is oxidized with oxygen in the presence of an oxidation catalyst comprising an imide compound of the following formula (1) (e.g., N-hydroxyphthalimide) or an oxidation catalyst comprising the imide compound and a co-catalyst (e.g., a transition metal compound of selected from Group 3A, 4A, 5A, 6A, 7A, 8 and 1B elements of the Periodic Table of elements), for the formation of an oxide (e.g., t-butanol, acetone):
   wherein R 1 and R 2 represent a substituent such as a hydrogen atom or a halogen atom, or R 1 and R 2 may together form a double bond or an aromatic or nonaromatic 5- to 12-membered ring, X is O or OH, and n is 1 to 3.

Abstract translation: 非环状支化脂族烃（例如，异丁烷）被氧化的氧在氧化催化剂的包含下式的二酰亚胺化合物的存在（1）（例如，N-羟基）或氧化催化剂，其包含二酰亚胺化合物和 助催化剂（例如，选自3A，4A，5A，6A，7A，8和元素周期表的1B族元素的过渡金属化合物），对于氧化物的形成（例如，叔丁醇， 丙酮）： worin - [R <1>和R <2>代表的取代基：例如，氢原子或卤原子，或R <1>和R <2>可一起形成一个双键，或芳香或非芳香 5-至12-元环，X为O或OH，并且n为1至3中

公开(公告)号：EP0990631A4

公开(公告)日：2004-09-01

申请号：EP99909321

申请日：1999-03-23

Applicant: DAICEL CHEM ,  ISHII YASUTAKA

Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA

IPC: B01J31/02 ,  B01J31/20 ,  B01J31/22 ,  C07B41/12 ,  C07D315/00 ,  C07B41/00 ,  C07B33/00 ,  C07D301/06 ,  C07D303/04 ,  C07D303/14 ,  C07D303/16

CPC classification number: C07B41/12 ,  B01J31/006 ,  B01J31/0231 ,  B01J31/0247 ,  B01J31/0271 ,  B01J31/20 ,  B01J31/2208 ,  B01J2231/70 ,  B01J2231/72 ,  B01J2531/64 ,  B01J2531/845 ,  C07D315/00

Abstract: A process for cooxidizing organic compounds which comprises, in the presence of an imide compound such as N-hydroxyphthalimide, oxidizing with molecular oxygen a compound (A) which is selected from among (A1) compounds having nonaromatic ethylenic linkage and (A2) ketones or alcohols corresponding to the ketones and a compound (B) which can be oxidized by the above imide compound with oxygen and is different from the above compound (A). As the compound (B), use can be made of (a) primary or secondary alcohols (benzhydrol, cyclohexanol, etc.), and (b) compounds having a carbon-hydrogen bond adjacent to an unsaturated bond (tetralin, ethylbenzene, etc.). Use of this process makes it possible to obtain the corresponding epoxy compounds from (A1) compounds having nonaromatic ethylenic linkage, and the corresponding esters or lactones from (A2) ketones or alcohols corresponding to the ketones, each at a high yield.

公开(公告)号：EP0915077A4

公开(公告)日：2000-08-09

申请号：EP98919559

申请日：1998-05-12

Applicant: DAICEL CHEM ,  ISHII YASUTAKA

Inventor： ISHII YASUTAKA ,  NAKANO TATSUYA ,  HIRAI NARUHISA

IPC: C07C67/08 ,  C07C69/00 ,  B01J27/10 ,  B01J31/22 ,  C07C69/54 ,  C07C69/732 ,  C07C201/12 ,  C07C205/05 ,  C07C231/02 ,  C07C233/25 ,  C08F16/14 ,  C08F20/10

CPC classification number: C07C67/03 ,  C07C2603/74 ,  C07C69/54

Abstract: High yields of polymerizable adamantane derivatives each having at least one polymerizable unsaturated group are produced by the esterification or amidation of a compound of general formula (1a) and a polymerizable unsaturated compound (e.g. an alcohol, a carboxylic acid or an amine) in the presence of a catalyst comprising a compound of a Group 3 element of the periodic table, such as a samarium compound. In said formula, R?1a to R4a¿ represent each a substituent selected from among inert atoms, inert groups, hydroxyl, carboxyl and amino, provided at least two groups of R?1a to R4a¿ are hydroxyl, carboxyl or amino.