DEPOSITION OF UNIFORM LAYER OF PARTICULATE MATERIAL
    4.
    发明申请
    DEPOSITION OF UNIFORM LAYER OF PARTICULATE MATERIAL 审中-公开
    沉积物质的均匀层

    公开(公告)号:WO2005095005A1

    公开(公告)日:2005-10-13

    申请号:PCT/US2005/010634

    申请日:2005-03-31

    CPC classification number: B05D1/12 B05D1/025 B05D2401/90

    Abstract: Deposition of particulate material of a substance on a surface includes: (i) charging a vessel with a compressed fluid; (ii) introducing into the vessel a first feed stream comprising a solvent and the substance and a second feed stream comprising the compressed fluid, wherein the substance is less soluble in the compressed fluid relative to its solubility in the solvent and the solvent is soluble in the compressed fluid, and wherein the first feed stream is dispersed in the compressed fluid, allowing extraction of the solvent into the compressed fluid and precipitation of particles of the substance; (iii) exhausting components from the vessel at a rate substantially equal to the rate of addition of such components to the vessel in step (ii) through a restrictive passage whereby a flow of particles of the substance is formed; and (iv) exposing a receiver surface to the exhausted flow of particles.

    Abstract translation: 将物质颗粒物质沉积在表面上包括:(i)向容器中加入压缩流体; (ii)向容器中引入包含溶剂和物质的第一进料流和包含压缩流体的第二进料流,其中该物质相对于其在溶剂中的溶解度较不溶于压缩流体,溶剂可溶于 压缩流体,并且其中第一进料流分散在压缩流体中,允许将溶剂萃取到压缩流体中并沉淀物质颗粒; (iii)通过限制性通道以基本​​上等于这种组分向容器加入速率的速率从容器排出组分,由此形成物质的颗粒流; 和(iv)将接收器表面暴露于排出的颗粒流。

    SELF ASSEMBLED ORGANIC NANOCRYSTAL SUPERLATTICES
    5.
    发明申请
    SELF ASSEMBLED ORGANIC NANOCRYSTAL SUPERLATTICES 审中-公开
    自组装有机纳米晶体超导

    公开(公告)号:WO2005090652A1

    公开(公告)日:2005-09-29

    申请号:PCT/US2004/043689

    申请日:2004-12-21

    Abstract: A process for the preparation of a self assembled superlattice thin film comprising: (i) combining one or more functional organic material and one or more surface active material in a compressed CO 2 phase, where they interact to form an aggregated system having a continuous compressed CO 2 phase and a plurality of aggregates comprising surfactant and functional material molecules of average diameter less than 50 nanometers dispersed therein; (ii) rapidly depressurizing the compressed phase thereby precipitating the dispersed materials in the form of composite organic nanocrystals of average diameter less than 50 nanometers, and (iii) depositing the organic nanocrystals on a substrate surface, wherein the organic nanocrystals form a thin film having an ionic content of less than 0.001 M in equivalent sodium chloride concentration, and the thin film exhibits a long range periodicity in the arrangement of the organic nanocrystals in a self assembled superlattice structure.

    Abstract translation: 一种用于制备自组装超晶格薄膜的方法,包括:(i)将一种或多种功能性有机材料和一种或多种表面活性材料在压缩的CO 2相中组合,其中它们相互作用以形成具有连续压缩CO 2的聚集体系 相和包含分散在其中的表面活性剂和平均直径小于50纳米的功能材料分子的多个聚集体; (ii)使压缩相快速减压,从而以平均直径小于50纳米的复合有机纳米晶体的形式沉淀分散的材料,和(iii)将有机纳米晶体沉积在基材表面上,其中有机纳米晶体形成具有 当量氯化钠浓度的离子含量小于0.001M,并且薄膜在自组装超晶格结构中的有机纳米晶体的布置中表现出长程周期性。

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