公开(公告)号：US07572879B2

公开(公告)日：2009-08-11

申请号：US11418317

申请日：2006-05-05

Applicant: Steffen Zahn ,  Gauri Sankar Lal ,  William Franklin Burgoyne, Jr. ,  Kristen Elaine Minnich ,  Andrew Francis Nordquist ,  Lloyd Mahlon Robeson ,  Francis Joseph Waller

Inventor： Steffen Zahn ,  Gauri Sankar Lal ,  William Franklin Burgoyne, Jr. ,  Kristen Elaine Minnich ,  Andrew Francis Nordquist ,  Lloyd Mahlon Robeson ,  Francis Joseph Waller

IPC: C08G73/24 ,  C08G75/00 ,  C08F4/80

CPC classification number: C07D495/04 ,  C08G61/126 ,  C08G2261/146 ,  C08G2261/3243 ,  C08L25/12 ,  C08L25/18 ,  C08L27/12 ,  C08L33/02 ,  C08L35/00 ,  C08L65/00 ,  H01B1/127 ,  H01G11/48 ,  H01L51/0036 ,  Y02E60/13 ,  C08L2666/06 ,  C08L2666/04

Abstract: Partially and fully fluorinated alkyl substituted thienothiophene monomers (and polymers thereof) wherein the monomers are represented by the formula: wherein R is a partially or fully fluorinated primary, secondary or tertiary alkyl having from 1 to 8 carbon atoms; and X and X′ are independently selected from the group consisting of H, F, Cl, Br, I, MgCl,  —COR″, —C≡CH, and a polymerizable cyclic pi-conjugated carbon-ring structure optionally comprising S, N or O heteroatoms; wherein R′ is a primary, secondary or tertiary alkyl having from 1 to 6 carbon atoms, and R″ is H or a primary, or tertiary alkyl having from 1 to 6 carbon atoms.

Abstract translation: 部分和完全氟化的烷基取代的噻吩并噻吩单体（及其聚合物），其中单体由下式表示：其中R是具有1至8个碳原子的部分或完全氟化的伯，仲或叔烷基; 并且X和X'独立地选自H，F，Cl，Br，I，MgCl，-COR“，-C≡CH，以及任选地包含S的可聚合环状π-共轭碳环结构， N或O杂原子; 其中R'是具有1至6个碳原子的伯，仲或叔烷基，R“是H或具有1至6个碳原子的伯或叔烷基。

公开(公告)号：US07332223B2

公开(公告)日：2008-02-19

申请号：US11394906

申请日：2006-03-31

Applicant: Gregory A. Sotzing ,  Francis Joseph Waller ,  Lloyd Mahlon Robeson

Inventor： Gregory A. Sotzing ,  Francis Joseph Waller ,  Lloyd Mahlon Robeson

IPC: B32B27/06 ,  C08G75/00

CPC classification number: C08G61/123 ,  C08G61/126 ,  H01G11/48 ,  H01G11/56 ,  Y02E60/13 ,  Y10T428/31533

Abstract: This invention presents polymers and copolymers comprising repeating units of thieno[3,4-b]thiophene. Water-borne dispersions of such polymers and copolymers can be cast by conventional methods to provide uniform, thin films which possess utility in numerous electroactive applications including electrochromic displays, optically transparent electrodes and antistatic coatings. The compositions of this invention can be doped with conventional p-dopants or n-dopants. The invention also presents an aqueous process for preparing such compositions of matter.

Abstract translation: 本发明提供了包含噻吩并[3,4-b]噻吩重复单元的聚合物和共聚物。 这种聚合物和共聚物的水分散体可以通过常规方法浇铸以提供均匀的薄膜，其在许多电活性应用中具有实用性，包括电致变色显示器，光学透明电极和抗静电涂层。 本发明的组合物可掺杂常规的p-掺杂剂或n-掺杂剂。 本发明还提供了用于制备这种物质组合物的水性方法。

公开(公告)号：US07285504B2

公开(公告)日：2007-10-23

申请号：US10830558

申请日：2004-04-23

Applicant: Ronald Bernal Jones ,  Blaine Richard Hobar ,  Joel Erwin Goldstein ,  Lloyd Mahlon Robeson

Inventor： Ronald Bernal Jones ,  Blaine Richard Hobar ,  Joel Erwin Goldstein ,  Lloyd Mahlon Robeson

IPC: B32B27/04 ,  B32B5/02 ,  B32B27/30

CPC classification number: D04H1/64 ,  D04H1/587 ,  Y10T428/24124 ,  Y10T428/249947 ,  Y10T428/249952 ,  Y10T428/249962 ,  Y10T442/2738 ,  Y10T442/2779 ,  Y10T442/2787 ,  Y10T442/60

Abstract: The present invention is directed to an improvement in the wet tensile of a nonwoven web, whether the web is for a pre-moistened nonwoven wet wipe that is both safe to use and also flushes, disperses and finally biodegrades in appropriate environments or for a nonwoven web which requires high tensile strength when in contact with liquids. An improvement in the wet tensile of the nonwoven webs is achieved by incorporating a finite amount of poly(acrylic acid) into a polymeric binder system that is applied to the web.

Abstract translation: 本发明涉及非织造纤维网的湿拉伸性能的改进，无论纤维网是用于预先润湿的非织造湿织物，其既可安全使用又可在合适的环境中进行冲洗，分散和最终生物降解，或用于非织造布 在与液体接触时需要高拉伸强度的网。 通过将有限量的聚（丙烯酸）掺入到施加到纤维网上的聚合物粘合剂体系中来实现非织造纤维网的湿拉伸的改善。

公开(公告)号：US6133415A

公开(公告)日：2000-10-17

申请号：US337054

申请日：1999-06-21

Applicant: Thomas John Markley ,  Lloyd Mahlon Robeson

Inventor： Thomas John Markley ,  Lloyd Mahlon Robeson

IPC: C08G18/08 ,  C08G18/10 ,  C08G18/48

CPC classification number: C08G18/08 ,  C08G18/10 ,  C08G18/4854 ,  Y02P20/582

Abstract: Polyurethane prepolymer which can be converted into a final product by reaction with a curative or chain extending agent is made by reacting polyisocyanate with polyol in the presence of an amount of an aliphatic hydrocarbon which is a solvent for the polyisocyanate but a non-solvent for the prepolymer. In order to minimize the formation of unwanted oligomers the polyisocyanate is present in stoichiometric excess with respect to the polyol and the amount of hydrocarbon solvent present in the reaction mixture is limited so that a single liquid phase is present in the mixture during most of the synthesis. Solvent containing dissolved isocyanate is then removed from the prepolymer by liquid phase separation. A portion of the solvent can be distilled from this isocyanate solution for use in liquid--liquid extraction of residual isocyanate from the prepolymer, and the remaining solution of isocyanate in hydrocarbon solvent can be used in prepolymer synthesis. A preferred method of liquid--liquid extraction of unreacted polyisocyanate from prepolymer is by counter-current flow of the prepolymer and hydrocarbon solvent through a vertically elongated contact column. This technique can be used independently or in combination with the use of hydrocarbon solvent in the prepolymer synthesis.

Abstract translation: 通过与固化剂或扩链剂反应可以转化成最终产物的聚氨酯预聚物是通过使多异氰酸酯与多元醇在一定量的脂肪烃存在下反应而制备的，脂族烃是多异氰酸酯的溶剂，但是用于 预聚物。 为了最小化不想要的低聚物的形成，多异氰酸酯以相对于多元醇的化学计量过量存在并且反应混合物中存在的烃溶剂的量受到限制，使得在大部分合成期间混合物中存在单一液相 。 然后通过液相分离从预聚物中除去含有溶解的异氰酸酯的溶剂。 可以从该异氰酸酯溶液中蒸馏出一部分溶剂，用于从预聚物中液 - 液萃取残余异氰酸酯，并将剩余的异氰酸酯溶液在烃溶剂中用于预聚物合成。 从预聚物中液 - 液萃取未反应的多异氰酸酯的优选方法是通过垂直伸长的接触柱逆流预聚物和烃溶剂。 该技术可以单独使用或与在预聚物合成中使用烃溶剂组合使用。

公开(公告)号：US5874516A

公开(公告)日：1999-02-23

申请号：US502508

申请日：1995-07-13

Applicant: William Franklin Burgoyne, Jr. ,  Lloyd Mahlon Robeson ,  Raymond Nicholas Vrtis

Inventor： William Franklin Burgoyne, Jr. ,  Lloyd Mahlon Robeson ,  Raymond Nicholas Vrtis

IPC: C08G65/34 ,  C08G65/40 ,  C08G65/48 ,  H01L23/498 ,  H01L23/532 ,  H05K3/46 ,  B32B27/04 ,  B32B27/28 ,  C08G65/00

CPC classification number: C08G65/40 ,  H01L23/49894 ,  H01L23/5329 ,  C08L2203/20 ,  H01L2924/0002 ,  H01L2924/09701

Abstract: The present invention is directed to novel poly(arylene ethers), their synthesis and use in electronics applications as low dielectric insulating layers such as spin-on materials in integrated circuits. The polymers have repeating units of the structure: ##STR1## wherein m=0.2 to 1.0; and n=1.0-m; and Ar.sub.1, Ar.sub.2 and Ar.sub.3 are individually divalent arylene radicals selected from the group consisting of; ##STR2##

Abstract translation: 本发明涉及新颖的聚（亚芳基醚），它们在电子应用中的合成和应用，作为低介电绝缘层，例如集成电路中的旋涂材料。 聚合物具有以下结构的重复单元：其中m = 0.2至1.0; 并且n = 1.0-m; Ar 1，Ar 2和Ar 3分别是选自以下的二价亚芳基：

公开(公告)号：US06239250B1

公开(公告)日：2001-05-29

申请号：US09293002

申请日：1999-04-16

Applicant: John Guinn Hefner ,  Lloyd Mahlon Robeson

Inventor： John Guinn Hefner ,  Lloyd Mahlon Robeson

IPC: C08G6700

CPC classification number: C09J173/00 ,  Y10T428/31688 ,  Y10T428/31692 ,  Y10T428/31938 ,  Y10T428/31942

Abstract: Olefin/CO linear alternating copolymers which are useful in hot melt adhesive applications are disclosed. The linear alternating copolymers have melting points ranging from 50 to 165° C. and exhibit a combination of properties which are desired for hot melt adhesives. Single olefins or combinations of olefins ranging from ethylene to C12 olefins can be used to form the linear alternating copolymer.

Abstract translation: 公开了可用于热熔粘合剂应用的烯烃/ CO线性交替共聚物。 线性交替共聚物的熔点范围为50至165℃，并表现出热熔粘合剂所需的性能组合。 单烯烃或从乙烯到C12烯烃的烯烃组合可用于形成线性交替共聚物。

公开(公告)号：US5789505A

公开(公告)日：1998-08-04

申请号：US911416

申请日：1997-08-14

Applicant: Steven Paul Wilkinson ,  Frank Kenneth Schweighardt ,  Lloyd Mahlon Robeson

Inventor： Steven Paul Wilkinson ,  Frank Kenneth Schweighardt ,  Lloyd Mahlon Robeson

IPC: C01B32/50 ,  C08F2/04 ,  C08F2/44 ,  D06L1/00 ,  B05D1/02

CPC classification number: C01B31/20 ,  C08F2/04 ,  Y02P20/544

Abstract: Acetylenic alcohols and diols have been found which are soluble in liquid/supercritical CO.sub.2 and exhibit surface active properties. These alcohols and diols act as surfactants by lowering the surface tension between CO.sub.2 and mobile CO.sub.2 -phobic substances which are contacted with the CO.sub.2.

Abstract translation: 已经发现可溶于液体/超临界二氧化碳的乙炔醇和二醇具有表面活性。 这些醇和二醇通过降低与CO 2接触的CO 2和可移动的CO 2 - 恐怕物质之间的表面张力作为表面活性剂。

公开(公告)号：US5688870A

公开(公告)日：1997-11-18

申请号：US630396

申请日：1996-04-10

Applicant: Steven Paul Wilkinson ,  Lloyd Mahlon Robeson

Inventor： Steven Paul Wilkinson ,  Lloyd Mahlon Robeson

IPC: C08F2/00 ,  C08F265/04 ,  C08F291/00 ,  C08F26/08

CPC classification number: C08F291/00 ,  C08F265/04 ,  Y02P20/544

Abstract: Water dispersible polymeric powders are prepared in liquid/supercritical CO.sub.2 by the sequential polymerization of a water soluble polymer after the polymerization of a non-water soluble polymer using core-shell polymerization technology.

Abstract translation: 通过在使用核 - 壳聚合技术聚合非水溶性聚合物之后通过水溶性聚合物的顺序聚合，在液体/超临界CO 2中制备水分散性聚合物粉末。

公开(公告)号：US07432340B2

公开(公告)日：2008-10-07

申请号：US11128538

申请日：2005-05-13

Applicant: Steffen Zahn ,  Gauri Sankar Lal ,  William Franklin Burgoyne, Jr. ,  Kristen Elaine Minnich ,  Andrew Francis Nordquist ,  Lloyd Mahlon Robeson ,  Francis Joseph Waller

Inventor： Steffen Zahn ,  Gauri Sankar Lal ,  William Franklin Burgoyne, Jr. ,  Kristen Elaine Minnich ,  Andrew Francis Nordquist ,  Lloyd Mahlon Robeson ,  Francis Joseph Waller

IPC: C08G73/24 ,  C08F4/80 ,  C08G75/00

CPC classification number: C08G61/123 ,  C08G61/126

Abstract: Partially and fully fluorinated alkyl substituted thienothiophene monomers (and polymers thereof) wherein the monomers are represented by the formula: wherein R is a partially or fully fluorinated primary, secondary or tertiary alkyl having from 1 to 8 carbon atoms; and X and X′ are independently selected from the group consisting of H, F, Cl, Br, I, MgCl, MgBr, Mgl, Sn(R′)3, CH═CHR″, —OR″, —COOR″, —S—COR″, —B(OR″)2, —COR″, —C≡CH, and a polymerizable cyclic pi-conjugated carbon-ring structure optionally comprising S, N or O heteroatoms; wherein R′ is a primary, secondary or tertiary alkyl having from 1 to 6 carbon atoms, and R″ is H or a primary, secondary or tertiary alkyl having from 1 to 6 carbon atoms.

Abstract translation: 部分和完全氟化的烷基取代的噻吩并噻吩单体（及其聚合物），其中单体由下式表示：其中R是具有1至8个碳原子的部分或完全氟化的伯，仲或叔烷基; 并且X和X'独立地选自H，F，Cl，Br，I，MgCl，MgBr，MgI，Sn（R'）3，CH-CHR“， - OR“，-COOR”，-S-COR“，-B（OR”）2，-COR“，-C≡CH和可聚合的环状π-共轭碳 任选地包含S，N或O杂原子的环结构; 其中R'是具有1至6个碳原子的伯，仲或叔烷基，R“是H或具有1至6个碳原子的伯，仲或叔烷基。

公开(公告)号：US06235811B1

公开(公告)日：2001-05-22

申请号：US09327731

申请日：1999-06-08

Applicant: Lloyd Mahlon Robeson ,  David Alan Dubowik

Inventor： Lloyd Mahlon Robeson ,  David Alan Dubowik

IPC: C08K320

CPC classification number: C08L31/04 ,  C08G59/50 ,  C08L63/00 ,  C08L2201/52 ,  C08L2666/14 ,  C08L2666/04

Abstract: Hybrid polymeric compositions of epoxy resin and vinyl acetate polymer are combined in an aqueous emulsion also containing an emulsifying agent and isophoronediamine as a hardener for the epoxy resin. The emulsion is stable for long periods of time but can be cast and cured at room temperature, providing a one-pot system for the preparation of protective coatings, laminating adhesives, and the like. The vinyl acetate polymer must be emulsion polymerized independently of the epoxy resin and is preferably a copolymer of vinyl acetate with ethylene or n-butyl acrylate. The pot life of these hybrid polymer emulsions containing the epoxy hardening agent is at least one month and frequently as long as a year.

Abstract translation: 将环氧树脂和乙酸乙烯酯聚合物的混合聚合物组合物也含有乳化剂和异佛尔酮二胺作为环氧树脂的硬化剂的水性乳液中。 该乳液长时间稳定，但可以在室温下浇铸和固化，为制备保护涂层，层压粘合剂等提供一锅系统。 乙酸乙烯酯聚合物必须独立于环氧树脂乳液聚合，并且优选为乙酸乙烯酯与乙烯或丙烯酸正丁酯的共聚物。 含有环氧硬化剂的这些杂化聚合物乳液的适用期至少为一个月，经常长达一年。