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    PREPARATION OF AMINES
    1.
    发明专利
    PREPARATION OF AMINES 未知

    公开(公告)号：CA2155171A1

    公开(公告)日：1996-02-09

    申请号：CA2155171

    申请日：1995-08-01

    Applicant: REIF WOLFGANG ,  FRANZ LOTHAR ,  STOPS PETER ,  MENGER VOLKMAR ,  BECKER RAINER ,  KUMMER RUDOLF ,  WINDERL SIEGFRIED

    Inventor： REIF WOLFGANG ,  FRANZ LOTHAR ,  STOPS PETER ,  MENGER VOLKMAR ,  BECKER RAINER ,  KUMMER RUDOLF ,  WINDERL SIEGFRIED

    IPC: B01J23/88 ,  B01J21/06 ,  B01J23/885 ,  B01J37/03 ,  C07C209/08 ,  C07C209/16 ,  C07C209/18 ,  C07C211/03 ,  C07C213/02 ,  C07C211/02 ,  C07D295/027 ,  C07C217/08 ,  C08G65/38

    Abstract: A process for the preparation of amines from primary or secondary alcohols and nitrogen compounds selected from the group consisting of ammonia and primary and secondary amines, at temperatures of from 80.degree. to 250.degree.C and pressures of from 1 to 400 bar using hydrogen in the presence of a zirconium/copper/nickel catalyst, wherein the catalytically active material contains from 20 to 85wt% ofoxygen-containing zirconium compounds, calculated as ZrO2, from 1 to 30wt% of oxygen-containing compounds of copper, calculated as cuO, from 30 to 70 wt% of oxygen-containing compounds of nickel, calculated as NiO, from 0.1 to 5wt% of oxygen-containing compounds of molybdenum, calculated as MoO3 and from 0 to 10 wt% the oxygen-containing compounds of aluminum and/or manganese, calculated as AI203 or MnO2 respectively. It is preferred to prepare amines of the general formula I ( 1), in which R1 and R2 denote hydrogen, C1-C20alkyl, C3-C12cycloalkyl, aryl, C7-C20 aralkyl und C7-C20 alkylaryl or together form (CH2)1-X-(CH2)m' R3 and R4 denote hydrogen, C1-C200 alkyl, C3-C12 cycloalkyl, C1-C20 hydr oxyalkyl, C1-C20alkyl substituted by amino and/or hydroxy, C2-c30 alkoxyalkyl, R5-(OCR?R7CR8R9)"-(OCR6R7), aryl, C7-C20 aralkyl, C7-C20 alkylaryl, (R5)2N-(CH2)q and Y-(CH2)m-NR5-(CH2)q or together form (CH2)?-x-(CH2)m or R2 and R4 together form (CH2)l-x-(CH2)m, R5 denotes hydrogen, C1-C4 alkyl, or C12-C40 alkylphenyl, R6, R7, R8, and R9 denote hydrogen, methyl, or ethyl, R10 denotes hydrogen or C1-C4 alkyl, ____________________________________________________________________________ 23 X denotes CH2, oxygen, or N-R6, Y denotes N(R5)2, hydroxy, C2-C20 alkylaminoalkyl or C3-C20 dialkylaminoalkyl, n is an integer from 1 to 30, ? is an integer from 2 to 4, m and q are integers from 1 to 4, from primary or secondary alcohols of the general formula II R4 CHR3-OH (II), and nitrogen compounds of the general formula III (III), in which R1, R2, and R3 and R4 have the aforementioned meanings. ________________________________________________________________________ 24

    METHOD OF PREPARING AMINES FROM OLEFINS OVER BORON 'beta'-ZEOLITES
    3.
    发明申请
    METHOD OF PREPARING AMINES FROM OLEFINS OVER BORON 'beta'-ZEOLITES 审中-公开
    用于生产AMINES由烯烃欠压引起β沸石

    公开(公告)号：WO1997007088A1

    公开(公告)日：1997-02-27

    申请号：PCT/EP1996003634

    申请日：1996-08-19

    Applicant: BASF AKTIENGESELLSCHAFT ,  DINGERDISSEN, Uwe ,  KUMMER, Rudolf ,  STOPS, Peter ,  MÜLLER, Ulrich ,  HERRMANN, Jürgen ,  ELLER, Karsten

    Inventor： BASF AKTIENGESELLSCHAFT

    IPC: C07C209/60

    CPC classification number: C07C209/60

    Abstract: Disclosed is a method of preparing amines of general formula (I), in which R , R , R , R , R and R are hydrogen, C1-C20 alkyl, C2-C20 alkenyl, C2-C20 alkinyl, C3-C20 cycloalkyl, C4-C20 alkylcycloalkyl, C4-C20 cycloalkylalkyl, aryl, C7-C20 alkylaryl or C7-C20 aralkyl, R and R together form a saturated or unsaturated C3-C9 alkylene di-chain and R or R is C21-C200 alkyl or C21-C200 alkenyl or R and R together form a C2-C12 alkylene di-chain, by reacting olefins of general formula (II), in which R , R , R and R are as defined above, with ammonia or primary or secondary amines of general formula (III), in which R and R are as defined above, at temperatures of 200 to 350 DEG C and pressures of 100 to 300 bar in the presence of a zeolite catalyst, a boron beta -zeolite being used as the catalyst.

    Abstract translation: 一种用于制备通式（I）中R <1>，R <2>，R <3>，R <4>，R <5> - [R <6>为氢，C1至C20的胺的方法 烷基，C2至C20烯基，C2至C20炔基，C3至C20环烷基，C4至C20烷基 - 环烷基，C4〜C20环烷基 - 烷基，芳基，C7-C20烷芳基或 C7至C20芳烷基，R <1>和R <2>一起形成饱和或不饱和的C3-C9-Alkylendikette和R <3>或R <5> C21至C200烷基，C21至C200烯基 或者一起表示C2至C12 Alkylendikette，通过使通式（II）的烯烃，其中R <3>，R <4>，R <5>和R <6>上面所提到的含义，与 氨或通式（III）的伯或仲胺，具有在R <1>和R <2>如在沸石催化剂的存在如上所定义的，在温度为200至350℃和100至300巴的压力 通过采用作为沸石催化剂硼BETA-沸石。

    PREPARATION OF AMINES
    5.
    发明专利
    PREPARATION OF AMINES 未知

    公开(公告)号：CA2155171C

    公开(公告)日：2006-03-14

    申请号：CA2155171

    申请日：1995-08-01

    Applicant: REIF WOLFGANG ,  FRANZ LOTHAR ,  STOPS PETER ,  MENGER VOLKMAR ,  BECKER RAINER ,  KUMMER RUDOLF ,  WINDERL SIEGFRIED

    Inventor： REIF WOLFGANG ,  FRANZ LOTHAR ,  STOPS PETER ,  MENGER VOLKMAR ,  BECKER RAINER ,  KUMMER RUDOLF ,  WINDERL SIEGFRIED

    IPC: B01J23/88 ,  C07C213/02 ,  B01J21/06 ,  B01J23/885 ,  B01J37/03 ,  C07C209/08 ,  C07C209/16 ,  C07C209/18 ,  C07C211/02 ,  C07C211/03 ,  C07C217/08 ,  C07D295/027 ,  C08G65/38

    Abstract: A process for the preparation of amines from primary or secondary alcohols a nd nitrogen compounds selected from the group consisting of ammonia and primary and secondary amines, at temperatures of from 80.degree. to 250.degree.C and pressures of from 1 to 400 bar using hydrogen in the presence of a zirconium/copper/nicke l catalyst, wherein the catalytically active material contains from 20 to 85 w t% of oxygen-containing zirconium compounds. calculated as ZrO2, from 1 to 30 wt% of oxygen-containing compounds of copper, calculated as CuO, from 30 to 70 wt% of oxygen-containing compounds of nickel, calculated as NiO, from 0.1 to 5 wt% of oxygen-containing compounds of molybdenum, calculated as MoO3 and from 0 to wt% the oxygen-containing compounds of aluminum and/or manganese, calculated as Al2O3 or MnO2 respectively. It is preferred to prepare amines of the general formula I (see formula I) in which R1 and R2 denote hydrogen, C1-C20 alkyl, C3-C12 cycloalkyl, aryl, C7-C2 0 aralkyl and C7-C20 alkylaryl or together form (CH2)l-X-(CH2)m, R3 and R4 denote hydrogen, C1-C200 alkyl, C3-C12 cycloalkyl, C1-C20 hydroxyalkyl, C1-C20 alkyl substituted by amino and/or hydroxy, C2-C30 alkoxyalkyl, R5-(OCR6R7CR8R9)n-(OCR6R7), aryl, C7-C20 aralkyl, C7-C20 alkylaryl, (R5)2N-(CH2)q and Y-(CH2)m-NR5-(CH2)q ortogether form (CH2)l-X-(CH2)m or R2 and R4 together form (CH2)l-X-(CH2)m, R5 denotes hydrogen, C1-C4 alkyl, or C12-C40 alkylphenyl, R6, R7, R8, and R9 denote hydrogen, methyl, or ethyl, R10 denotes hydrogen or C1-C4 alkyl, X denotes CH2, oxygen, or N-R6, Y denotes N(R5)2, hydroxy, C2-C20 alkylaminoalkyl or C3-C20 dialkylaminoalkyl, n is an integer from 1 to 30, l is an integer from 2 to 4, m and q are integers from 1 to 4, from primary or secondary alcohols of the general formula II R4 - CHR3 - OH (II), and nitrogen compounds of the general formula III (see formula III) in which R1, R2, and R3 and R4 have the aforementioned meanings.

    PROCESS FOR PRODUCING AMINES FROM OLEFINS ON ZEOLITHS OF TYPES SSZ-26, SSZ-33, CIT-1 OR MIXTURES THEREOF
    7.
    发明申请
    PROCESS FOR PRODUCING AMINES FROM OLEFINS ON ZEOLITHS OF TYPES SSZ-26, SSZ-33, CIT-1 OR MIXTURES THEREOF 审中-公开
    用于生产AMINES FROM AN烯烃型沸石SSZ-26，SSZ-33，CIT-1或它们的混合物

    公开(公告)号：WO1997021661A1

    公开(公告)日：1997-06-19

    申请号：PCT/EP1996005406

    申请日：1996-12-04

    Applicant: BASF AKTIENGESELLSCHAFT ,  ELLER, Karsten ,  KUMMER, Rudolf ,  STOPS, Peter

    Inventor： BASF AKTIENGESELLSCHAFT

    IPC: C07C209/60

    CPC classification number: C07C209/60

    Abstract: A process is disclosed for producing amines of general formula (I) in which: R , R , R , R , R , R stand for hydrogen, C1-C20-alkyl, C2-C20-alkenyl, C2-C20-alkinyl, C3-C20-cycloalkyl, C4-C20-alkyl-cycloalkyl, C4-C20-cycloalkyl-alkyl, aryl, C7-C20 alkylaryl or C7-C20-aralkyl; R and R together represent a saturated or unsaturated C3-C9 alkylene di-chain; and R or R stand for C21-C200-alkyl, C21-C200-alkenyl or together stand for a C2-C12 alkylene di-chain. The process involves reacting the olefins of general formula (II), in which R , R , R , R have the above meanings, with ammonia or primary or secondary amines of general formula (III), in which R and R have the above meanings, at temperatures of 200-350 DEG C and pressures of 100-300 bar in the presence of a heterogenous catalyst in the form of zeoliths of type SSZ-26, SSZ-33, CIT-1 or mixtures thereof.

    Abstract translation: 一种用于制备通式（I）中R <1>，R <2>，R <3>，R <4>，R <5> - [R <6>为氢，C1至C20的胺的方法 烷基，C2至C20烯基，C2至C20炔基，C3至C20环烷基，C4至C20烷基 - 环烷基，C4〜C20环烷基 - 烷基，芳基，C7-C20烷芳基或 C7至C20芳烷基，R <1>和R <2>一起形成饱和或不饱和的C3-C9-Alkylendikette和R <3>或R <5> C21至C200烷基，C21至C200烯基 或者一起表示C2至C12 Alkylendikette，通过使通式（II）的烯烃，其中R <3>，R <4>，R <5>和R <6>上面所提到的含义，与 通式（III）的氨或伯胺或仲胺具有上述含义，其中R <1>和R <2>在200温度下，以350℃，100至300巴的压力在非均相催化剂的存在下， 通过使用如非均相催化剂的类型SSZ-26，SSZ-33，CIT-1或其mixe的沸石 他使用。

    PROCESS AND CATALYST FOR THE SELECTIVE HYDROGENATION OF BUTINE DIOL TO BUTENE DIOL
    8.
    发明申请
    PROCESS AND CATALYST FOR THE SELECTIVE HYDROGENATION OF BUTINE DIOL TO BUTENE DIOL 审中-公开
    工艺及催化剂的丁炔二醇的选择性加氢丁烯

    公开(公告)号：WO1996001242A1

    公开(公告)日：1996-01-18

    申请号：PCT/EP1995002592

    申请日：1995-07-04

    Applicant: BASF AKTIENGESELLSCHAFT ,  IRGANG, Matthias ,  MENGER, Volkmar ,  MIESEN, Ernest ,  STOPS, Peter ,  GRAF, Fritz

    Inventor： BASF AKTIENGESELLSCHAFT

    IPC: C07C29/17

    CPC classification number: C07C33/035 ,  B01J23/60 ,  B01J23/66 ,  B01J23/8953 ,  C07C29/17

    Abstract: A process is disclosed for the selective hydrogenation of butine-2-diol(1,4) to butene-2-diol(1,4) using a palladium catalyst to which copper and zinc or silver and zinc are added as doping agents. In the preferred embodiment, it has been possible, by optimizing the composition of the catalyst, to improve the activity and selectivity of the catalysts in question while also eliminating the need to handle toxic substances during the catalyst manufacturing process.

    Abstract translation: 本发明描述了一种用于丁炔-1,2-二醇（1,4），以丁烯-1,2-二醇（1.4）与掺杂了铜和锌或银和锌钯催化剂的帮助下，选择性氢化的方法。 在优选的实施方案中，可以通过将催化剂组合物中，活性和选择性的催化剂的优化和在同一时间，以增加，以避免在催化剂制备和使用有毒材料的处理。

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