公开(公告)号：KR1020120043191A

公开(公告)日：2012-05-04

申请号：KR1020100104367

申请日：2010-10-26

Applicant: 강원대학교산학협력단

Inventor： 이필호 ,  김성각 ,  김선대 ,  박애리 ,  신두섭 ,  최수빈 ,  박영철

IPC: C07F9/12 ,  C07F9/113 ,  B01J27/14 ,  B01J27/10

CPC classification number: C07F9/12 ,  B01J31/2404 ,  B01J2531/18 ,  B01J2531/90

Abstract: PURPOSE: An enol phosphate derivative and a method for preparing the same are provided to enable synthesis of natural products and physiologically active materials. CONSTITUTION: An enol phosphate derivative is denoted by chemical formula 1. A method for preparing enol phosphate derivative comprises: a step of reacting alkane derivative of chemical formula 2 with a phosphate derivative of chemical formula 4 under the presence of a gold catalyst to prepare kinetic enol phosphate derivative of chemical formula A. The gold catalyst includes AuCl, AuCl_3, AuBr_3, PPh_3AuCl, (C_6F_5)_3PAuCl, (IPr)AuCl, or (IMes)AuCl.

Abstract translation: 目的：提供烯醇磷酸酯衍生物及其制备方法，以使天然产物和生理活性物质合成。 烯烃磷酸酯衍生物由化学式1表示。一种制备烯醇磷酸酯衍生物的方法包括：在金催化剂存在下使化学式2的烷烃衍生物与化学式4的磷酸酯衍生物反应以制备动力学的步骤 金催化剂包括AuCl，AuCl_3，AuBr_3，PPh_3AuCl，（C_6F_5）_3PAuCl，（IPr）AuCl或（IMes）AuCl。

公开(公告)号：KR101210428B1

公开(公告)日：2012-12-10

申请号：KR1020100104367

申请日：2010-10-26

Applicant: 강원대학교산학협력단

Inventor： 이필호 ,  김성각 ,  김선대 ,  박애리 ,  신두섭 ,  최수빈 ,  박영철

IPC: C07F9/12 ,  C07F9/113 ,  B01J27/14 ,  B01J27/10

Abstract: 본발명은하기화학식 1로표시되는엔올포스페이트유도체및 이의제조방법에관한것이다. 보다상세하게는, 서로다른금 촉매계를이용하여알카인유도체를포스페이트유도체와의첨가반응을통하여하기화학식 A로표시되는카이네틱(kinetic) 엔올포스페이트유도체와하기화학식 B로표시되는써모다이나믹(thermodynamic) 엔올포스페이트유도체를각각선택적으로제조하는방법에관한것이다. [화학식 1][화학식 A][화학식 B]상기화학식 1, 화학식 A 및화학식 B에서 R, R, R및 R는각각발명의상세한설명에서정의한바와같다.