公开(公告)号：KR101184428B1

公开(公告)日：2012-09-20

申请号：KR1020110021387

申请日：2011-03-10

Applicant: 단국대학교 산학협력단

Inventor： 이용걸 ,  서혜련 ,  김기덕

IPC: B01J27/051 ,  B01J35/06 ,  B01J37/20 ,  C10G3/00

CPC classification number: Y02P20/52 ,  Y02P30/20

Abstract: PURPOSE: A nano-wire shaped molybdenum disulfide catalyst and a method for producing bio-fuel using the same are provided to convert biomass with oxygen-containing compounds into biofuel under hydrodeoxygenation. CONSTITUTION: A nano-wire shaped molybdenum disulfide(MoS_2) catalyst is used as the activating component of hydrodeoxygenation. The hydrodeoxygenation converts biomass into biofuel. The catalyst is prepared based on a ligand stabilizing method. The average particle size of the catalyst is in a range between 1 and 1,000nm. The catalyst is dispersed phase. A method for preparing the catalyst includes the following: a molybdenum complex compound is prepared by reacting a molybdenum precursor and a phosphine oxide-based compound based on the ligand stabilizing method; and sulfur is reacted with the molybdenum complex compound. [Reference numerals] (AA) Benzene products; (BB) Comparative example 3; (CC) Comparative example 4; (DD) Example 3; (EE) Reaction time (h)

Abstract translation: 目的：提供纳米线状二硫化钼催化剂和使用其制备生物燃料的方法，用于在含氧化合物的生物燃料加氢脱氧下转化为生物燃料。 构成：使用纳米线状二硫化钼（MoS_2）催化剂作为加氢脱氧活化成分。 加氢脱氧将生物质转化为生物燃料。 基于配体稳定化方法制备催化剂。 催化剂的平均粒径在1〜1000nm的范围内。 催化剂是分散相。 制备催化剂的方法包括以下：通过基于配体稳定化方法使钼前体和基于氧化膦的化合物反应制备钼络合物; 硫与钼络合物反应。 （标号）（AA）苯产品; （BB）比较例3; （CC）比较例4; （DD）实施例3; （EE）反应时间（h）

公开(公告)号：KR1020120103235A

公开(公告)日：2012-09-19

申请号：KR1020110021387

申请日：2011-03-10

Applicant: 단국대학교 산학협력단

Inventor： 이용걸 ,  서혜련 ,  김기덕

IPC: B01J27/051 ,  B01J35/06 ,  B01J37/20 ,  C10G3/00

CPC classification number: Y02P20/52 ,  Y02P30/20 ,  B01J27/051 ,  B01J35/023 ,  B01J35/06 ,  B01J37/20 ,  C10G3/44 ,  Y02E50/10

Abstract: 본발명은바이오매스를바이오연료로전환시키는수첨탈산소반응의활성성분으로사용하기위한나노와이어형상의이황화몰리브데늄(MoS) 촉매에관한것으로서, 슬러리반응기에서사용될수 있고, 산소를함유하는화합물을포함하는바이오매스를바이오연료로전환하는수첨탈산소반응에서우수한활성을보이는분산상촉매로서나노와이어형상의이황화몰리브데늄촉매를제공할수 있다.