公开(公告)号：KR1020020006979A

公开(公告)日：2002-01-26

申请号：KR1020000040610

申请日：2000-07-14

Applicant: 대한민국(충남대학교)

Inventor： 최호석 ,  김재우

IPC: C08J3/24

Abstract: PURPOSE: A method for cross-linking a high density polyethylene by using the plasma reaction and a latent heat regenerating material prepared by using the method are provided, to obtain a high density polyethylene with a low surface charge which stores heat by the form of slurry. CONSTITUTION: The method comprises the steps of charging a high density polyethylene with flowing a carrier gas into a plasma reactor; fluidizing the high density polyethylene slurry by stirring it with a Teflon-coated magnetic bar to cross-link the high density polyethylene; and introducing fluorine from Teflon to modify the surface. Preferably the cross-linking process is carried out in the condition of an RF power of 30-300 W, a pressure of 0-350 mTorr, a treatment time of 30 sec to 120 min, and a rotation velocity of a magnetic bar of 50-1,000 rpm. The carrier gas is preferably argon. The plasma electron energy of a reactor is 0.1-10 and the electron density is 10¬9-10¬12 cm¬-3.

Abstract translation: 目的：提供通过使用等离子体反应交联高密度聚乙烯的方法和通过使用该方法制备的潜热再生材料，以获得具有低表面电荷的高密度聚乙烯，其通过浆料形式储存热量 。 构成：该方法包括以下步骤：将载气流入等离子体反应器中的高密度聚乙烯; 通过用聚四氟乙烯涂覆的磁棒搅拌它来使高密度聚乙烯浆料流化，以交联高密度聚乙烯; 并从特氟隆引入氟改性表面。 优选地，交联过程在30-300W的RF功率，0-350mTorr的压力，30秒至120分钟的处理时间和50巴的旋转速度的条件下进行 -1000转。 载气优选为氩。 反应器的等离子体电子能量为0.1-10，电子密度为10〜10〜12cm-3。

公开(公告)号：KR100367235B1

公开(公告)日：2003-01-10

申请号：KR1020000040610

申请日：2000-07-14

Applicant: 대한민국(충남대학교)

Inventor： 최호석 ,  김재우

IPC: C08J3/24

Abstract: PURPOSE: A method for cross-linking a high density polyethylene by using the plasma reaction and a latent heat regenerating material prepared by using the method are provided, to obtain a high density polyethylene with a low surface charge which stores heat by the form of slurry. CONSTITUTION: The method comprises the steps of charging a high density polyethylene with flowing a carrier gas into a plasma reactor; fluidizing the high density polyethylene slurry by stirring it with a Teflon-coated magnetic bar to cross-link the high density polyethylene; and introducing fluorine from Teflon to modify the surface. Preferably the cross-linking process is carried out in the condition of an RF power of 30-300 W, a pressure of 0-350 mTorr, a treatment time of 30 sec to 120 min, and a rotation velocity of a magnetic bar of 50-1,000 rpm. The carrier gas is preferably argon. The plasma electron energy of a reactor is 0.1-10 and the electron density is 10¬9-10¬12 cm¬-3.

Abstract translation: 目的：提供一种通过使用等离子体反应交联高密度聚乙烯的方法和通过使用该方法制备的潜热再生材料，以获得具有低表面电荷的高密度聚乙烯，其通过浆料形式储存热量 。 构成：该方法包括以下步骤：使载气流入等离子体反应器中，填充高密度聚乙烯; 通过用聚四氟乙烯涂覆的磁棒搅拌高密度聚乙烯淤浆来流化高密度聚乙烯淤浆以交联高密度聚乙烯; 并引入聚四氟乙烯氟改性表面。 交联处理优选在30〜300W的RF功率，0〜350mTorr的压力，30秒〜120分钟的处理时间，50的磁棒的旋转速度的条件下进行 -1,000rpm。 载气优选为氩气。 反应器的等离子体电子能量为0.1-10，电子密度为10-900而不是12-12厘米。