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公开(公告)号:KR1020120019167A
公开(公告)日:2012-03-06
申请号:KR1020100082395
申请日:2010-08-25
Applicant: 도레이첨단소재 주식회사
Abstract: PURPOSE: VOC(Volatile Organic Compounds)s treatment method and facility are provided to treat VOCs stably and effectively by a direct burning mode without a processing facility or an additional energy source. CONSTITUTION: A VOC(Volatile Organic Compounds)s treatment facility comprises a demister(201), a fan, gas sensors(101,102), a heater(203), a flame arrestor(103), and a shut-off valve(104). The demister separates and collects moisture and mist from VOC gas. The fan sucks and moves VOC. For LEL(Lowest Explosive Limit) to be maintained, the gas sensors measure the concentration of the VOC sucked and control the amount of external air. The heater keeps the temperature of the sucked VOC constant and prevents the VOC from having a temperature lower than a boiling point.
Abstract translation: 目的:提供VOC(挥发性有机化合物)的处理方法和设施,通过直接燃烧模式稳定有效地处理VOC,无需加工设备或附加能源。 构成:VOC(挥发性有机化合物)处理设备包括除雾器(201),风扇,气体传感器(101,102),加热器(203),阻焰器(103)和截止阀(104) 。 除雾器从VOC气体分离并收集水分和雾气。 风扇吸入并移动VOC。 对于要保持的LEL(最低爆炸极限),气体传感器测量吸入的VOC的浓度并控制外部空气的量。 加热器保持吸入的VOC的温度恒定,并防止VOC的温度低于沸点。
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公开(公告)号:KR1020130051699A
公开(公告)日:2013-05-21
申请号:KR1020110117002
申请日:2011-11-10
Applicant: 도레이첨단소재 주식회사
IPC: C08G63/78 , C08G63/183 , C08F2/01 , B01J19/00
CPC classification number: Y02P20/124
Abstract: PURPOSE: A heat exchange system is provided to reduce a large amount of energy used for a polyester process and to increase reaction time by preheating raw materials before the materials are put into a reaction pipe. CONSTITUTION: A heat exchange system for a polymerization reactor consists of a slurry preparing tank(1), a slurry supply line(2), an ester reaction pipe, a first heat exchanger, an end heat exchanger(5), a heat exchanger inlet line(6), and a storage tank(7). Ethylene glycol and water generated in the reaction pipe is transferred to the first heat exchanger through the heat exchanger inlet line, ethylene glycol is collected into the storage tank, residual steam is transferred to the end heat exchanger and condensed into liquid phase, coolant of the end heat exchanger collects heat using slurry flowing in through the slurry supply line.
Abstract translation: 目的:提供一种热交换系统,以减少用于聚酯工艺的大量能量,并通过在将材料投入反应管之前预热原料来增加反应时间。 构成:用于聚合反应器的热交换系统包括浆料制备罐(1),浆料供应管线(2),酯反应管,第一热交换器,端部热交换器(5),热交换器入口 管线(6)和储罐(7)。 在反应管中生成的乙二醇和水通过热交换器入口管路转移到第一热交换器,将乙二醇收集到储罐中,将残余蒸汽转移到末端换热器并冷凝成液相,冷却液 末端热交换器使用通过浆料供应管线流入的浆料来收集热量。
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公开(公告)号:KR101753005B1
公开(公告)日:2017-06-30
申请号:KR1020160073906
申请日:2016-06-14
Applicant: 도레이첨단소재 주식회사
CPC classification number: C08J11/02 , C08G63/90 , C08G85/00 , Y02P20/582
Abstract: 본발명의일 실시예에따르면, 폴리에스테르를중합하기위한폴리에스테르중합장치, 및상기폴리에스테르중합장치로부터회수된불순물을포함하는에틸렌글리콜을정제하기위한에틸렌글리콜정제장치를포함하며, 상기에틸렌글리콜정제장치는필터및 원심분리기를포함하는에틸렌글리콜회수장치를제공한다.
Abstract translation: 根据本发明的一个实施方式,提供用于聚合聚酯的聚酯聚合设备和用于精制包含从聚酯聚合设备回收的杂质的乙二醇的乙二醇精炼设备,其中乙二醇 该净化装置提供了一种包括过滤器和离心机的乙二醇回收装置。
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公开(公告)号:KR1020110053643A
公开(公告)日:2011-05-24
申请号:KR1020090110260
申请日:2009-11-16
Applicant: 도레이첨단소재 주식회사
IPC: C08G63/78 , C08G63/183 , C08G63/42 , C08G63/89
Abstract: PURPOSE: A method for manufacturing a polyester resin is provided to easily and economically prepare a polyester resin with excellent yellowness by removing causes causing yellowness. CONSTITUTION: A method for manufacturing a polyester resin with excellent yellowness comprises a step of mixing ethylene glycol with terephthalic acid in a molar ratio of 1.0-3.0 to prepare slurry and then performing a polymerization reaction, wherein an excess of ethylene glycol is collected in the polymerization reaction and in purified through two-stage purification steps and the purified ethylene glycol is reused in the process for manufacturing a polyester resin.
Abstract translation: 目的:提供一种聚酯树脂的制造方法,通过除去引起黄色的原因容易且经济地制备具有优异黄色性的聚酯树脂。 构成:具有黄色优异的聚酯树脂的制造方法包括将乙二醇与摩尔比为1.0〜3.0的对苯二甲酸混合以制备浆料,然后进行聚合反应的步骤,其中将过量的乙二醇收集在 聚合反应和通过两步纯化步骤纯化,并且纯化的乙二醇在制备聚酯树脂的方法中被重复使用。
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公开(公告)号:KR1020140046626A
公开(公告)日:2014-04-21
申请号:KR1020120111753
申请日:2012-10-09
Applicant: 도레이첨단소재 주식회사
IPC: C08G63/78 , C08G63/183 , C08L67/03
Abstract: The present invention relates to a method of preparing a polyester resin having high yellowness index, of which yellowness index may be improved to less than a predetermined degree by excluding a chemical material such as a tinter and controlling inorganic materials through improvemet of processes only, and a polyester resin having high yellowness index prepared by the method. According to the method of preparing the polyester resin having high yellowness index, in which ethylene glycol and terephthalic acid react to prepare the polyester resin, ethylene glycol and terephthalic acid are mixed at a molar ratio of 1.0 to 3.0 and stirred to prepare a slurry, and a polymerization reaction is conducted to recycle for the use in a preparation process of a polyester resin. According to the polyester resin having high yellowness index and the method of preparing the same, the inorganic materials included in ethylene glycol and terephthalic acid as impurities may be controlled. Thus, contaminating problems by heavy metals due to the use of the tinter such as cobalt acetate for managing the yellowness index which is important physical properties in an existing method of preparing common polyester are not generated. The increase of the yellowness index of the polyester may be simply restrained, and the devaluation of a product due to the deterioration of transparency may be prevented. [Reference numerals] (AA) Terephthalic acid ethylene glycol; (P) Phosphoric acid
Abstract translation: 本发明涉及一种黄色指数高的聚酯树脂的制备方法,其黄色指数可通过除去化学物质如调色剂而改善至小于预定程度,并且通过改进方法控制无机材料,以及 通过该方法制备的具有高黄度指数的聚酯树脂。 根据黄变度高的聚酯树脂的制造方法,其中乙二醇和对苯二甲酸反应制备聚酯树脂,将乙二醇和对苯二甲酸以1.0至3.0的摩尔比混合并搅拌以制备浆料, 并进行聚合反应以再循环用于聚酯树脂的制备过程中。 根据具有高黄度指数的聚酯树脂及其制备方法,可以控制包含在乙二醇和对苯二甲酸中作为杂质的无机材料。 因此,不会产生由于使用诸如乙酸钴的色调剂引起的重金属污染问题来控制在现有的制备普通聚酯的方法中重要的物理性质的黄度指数。 可以简单地抑制聚酯的黄度指数的增加,并且可以防止由于透明性的劣化导致的产品的贬值。 (标号)(AA)对苯二甲酸乙二醇; (P)磷酸
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公开(公告)号:KR101274339B1
公开(公告)日:2013-06-13
申请号:KR1020110117002
申请日:2011-11-10
Applicant: 도레이첨단소재 주식회사
IPC: C08G63/78 , C08G63/183 , C08F2/01 , B01J19/00
CPC classification number: Y02P20/124
Abstract: 본 발명은 폴리에스테르 제조공정에서 에너지원의 70% 이상을 소비하는 에스테르 공정에서 원료인 슬러리를 예열함으로써 반응률을 높여주며 발생하는 물을 효과적이고 에너지 절약형으로 제거하여 에너지회수율이 높고 반응율을 높일 수 있는, 에너지 효율이 높은 중합 반응기의 열교환 시스템 및 그 장치에 관한 것으로, 상기한 본 발명의 에너지 효율이 높은 중합 반응기의 열교환 시스템은 에스테르 공정에서 사용되는 중합반응 시스템에 있어서, 상기 시스템은 슬러리 준비탱크, 슬러리 공급라인, 에스테르 반응관, 1단 열교환기, 말단 열교환기, 열교환기 유입라인 및 저장 탱크로 구성되어 지고, 상기 반응관에서 발생한 에틸렌글리콜(EG)과 물은 열교환기 유입라인을 통해 1단 열교환기로 이송되고, EG가 저장 탱크로 회수된 후 잔여 수분 증기는 말단 열교환기로 이송되어 액상으로 응축되며, 여기서 말단 열교환기의 냉매는 슬러리 공급라인으로 통해 유입되는 슬러리를 사용하여 열을 회수하는 것을 특징으로 한다.
상기와 같이 구성되는 본 발명의 에너지 효율이 높은 중합 반응기의 열교환 시스템은 폴리에스테르공정에서 사용되는 많은 양의 에너지를 줄 일 수 있고 원료를 반응관 투입 전에 가열을 하여 반응률을 올리며 반응시간을 단축할 뿐만 아니라 설비를 단순화하여 공간 활용도를 높이는 방법을 제공한다.
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