公开(公告)号：KR1020140108204A

公开(公告)日：2014-09-05

申请号：KR1020140101865

申请日：2014-08-07

Applicant: 서울대학교산학협력단

Inventor： 박수영 ,  황동렬 ,  유승찬

IPC: C07F15/00 ,  C01B3/10

CPC classification number: Y02E60/36 ,  C07F19/00 ,  C01B3/042

Abstract: Disclosed are an organometallic complex and a method for generating hydrogen using the same. According to an embodiment of the present invention, the an organometallic complex is presented by Chemical Formula 1-1 or 1-2. In Chemical Formula 1-1 or 1-2, A is a substituted or unsubstituted, in other words capable of having a substituent, aromatic or heteroaromatic ring; B is a substituted or unsubstituted, in other words capable of having a substituent, aromatic or heteroaromatic ring including nitrogen atoms. A and B is covalently bonded by Z. Z may be bonded a single bond, -O-, -S-, -CO-, -(CR′R′′)a-, -(SiR′R′′)a-, or -NR′-.

Abstract translation: 公开了一种有机金属络合物和使用其制造氢的方法。 根据本发明的一个实施方案，有机金属络合物由化学式1-1或1-2表示。 在化学式1-1或1-2中，A是取代或未取代的，换句话说，可以具有取代基，芳族或杂芳族环; B是取代或未取代的，换句话说能够具有取代基，包括氮原子的芳族或杂芳族环。 A和B通过Z共价键合，Z可以键合单键，-O - ， - S - ， - CO-， - （CR'R“）a - ， - （SiR'R” ，或-NR'-。

公开(公告)号：KR1020140049233A

公开(公告)日：2014-04-25

申请号：KR1020120115213

申请日：2012-10-17

Applicant: 서울대학교산학협력단

Inventor： 박수영 ,  황동렬 ,  유승찬

IPC: C07F15/00 ,  C07F15/02 ,  C01B3/02

CPC classification number: C07F15/0033 ,  C01B3/068 ,  C07F19/00

Abstract: The present invention relates to an organometallic complex and a method of manufacturing hydrogen using the same. The organometallic complex according to the present invention is an organometallic complex represented by chemical formula 1. In the chemical formula 1, A is an aromatic ring or a hetero aromatic ring capable of having a substituent, and B is an aromatic ring or a hetero aromatic ring containing a nitrogen atom capable of having a substituent. The A and B are combined by a covalent bond through Z. The Z is one among a single bond -O-, -S-, -CO-, -(CR′R′′)a-, -(SiR′R′′)a- and -NR′-. (R′ and R′′ may be hydrogen, a substituted or non-substituted aromatic ring, a hetero aromatic ring, or an alkyl group) (Chemical formula 1) M may be one among iridium, ruthenium, rhenium, platinum, osmium, iron, cobalt or copper. n1 is an integer. R1 through R8 respectively hydrogen, a substituted or non-substituted alkyl group, a substituted or non-substituted alkoxy group, a substituted or non-substituted aryloxy group, a substituted or non-substituted alkenyl group, a substituted or non-substituted arylamino group, a substituted or non-substituted alkylamino group, a halogen atom, a cyano group or a nitro group.

Abstract translation: 本发明涉及一种有机金属配合物及其制造方法。 根据本发明的有机金属络合物是由化学式1表示的有机金属络合物。在化学式1中，A是能够具有取代基的芳香环或杂芳香环，B是芳香环或杂芳族 环，其含有能够具有取代基的氮原子。 A和B通过Z的共价键组合。Z是单键-O - ， - S - ， - CO - ， - （CR'R“）a - ， - （SiR'R' '）a-和-NR'-。 （R'和R“可以是氢，取代或未取代的芳环，杂芳环或烷基）（化学式1）M可以是铱，钌，铼，铂，锇， 铁，钴或铜。 n1是整数。 取代或未取代的烷氧基，取代或未取代的芳氧基，取代或未取代的烯基，取代或未取代的芳基氨基 取代或未取代的烷基氨基，卤素原子，氰基或硝基。